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US4645844A Expired / Lapsed US ⏱️ 0.0 years remaining

Functionally substituted phenoxyalkyl alkoxysilanes and method for preparing same

Assignee: Arkema Inc
•
Filing: 1983-07-20
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Granted: 1987-02-24
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Expires: 2003-07-20
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Abstract

Abstract Novel and known functionally substituted phenoxyalkyl-, thiophenoxyalkyl- and pyridyloxyalkylsilanes are prepared by reacting substantially equimolar amounts of an alkali- or alkaline earth metal phenoxide, thiophenoxide or pyridyloxide with a haloalkylsilane under anhydrous conditions using a dipolar, aprotic solvent in combination with a liquid hydrocarbon.

Inventors

  • 👤 Abe Berger
  • 👤 Irwin B. Silverstein

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 15:53
CPC Classifications
C; C07; C07F; C07F7/00; C07F7/02; C07F7/08; C07F7/18; C07F7/1804

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 236 words
A silane represented by the general formula ##STR18## where R 1 is --NH 2 , --NR 8 H, --NR 2 8 , ##STR19## --CHO, --CN, --COR 8 , --COOR 8 , Cl, Br, I, alkenyl which contains from 2 to 10 carbon atoms, and --NO 2 ; R 2 is alkyl, alkoxy or thioalkoxy and contains from 1 to 12 carbon atoms; R 5 is methylene or alkylene containing from 3 to 12 carbon atoms; R 6 and R 7 are individually selected from the group consisting of alkyl, cyanoalkyl, alkenyl, cycloalkyl, aryl, alkaryl and aralkyl, wherein any alkyl group present as all or part of R 6 and R 7 contains from 1 to 12 carbon atoms; R 8 is selected from the group consisting of alkyl, cycloalkyl, aryl, alkaryl and aralkyl wherein any alkyl group contains from 1 to 12 carbon atoms; R 9 is ##STR20## wherein R 11 and R 12 are individually selected from the group consisting of hydrogen, chlorine, bromine, iodine and alkyl containing from 1 to 12 carbon atoms; R 12 and R 14 are individually selected from the group consisting of hydrogen and alkyl containing from 1 to 12 carbon atoms; m is an integer equal to 1; n is 0, 1 or 2; p is 2 or 3; with the proviso that if R 1 is --NH 2 or --NO 2 , then n is 1 or 2.
Claim 2
Dependent Claim 236 words
A silane represented by the general formula ##STR18## where R 1 is --NH 2 , --NR 8 H, --NR 2 8 , ##STR19## --CHO, --CN, --COR 8 , --COOR 8 , Cl, Br, I, alkenyl which contains from 2 to 10 carbon atoms, and --NO 2 ; R 2 is alkyl, alkoxy or thioalkoxy and contains from 1 to 12 carbon atoms; R 5 is methylene or alkylene containing from 3 to 12 carbon atoms; R 6 and R 7 are individually selected from the group consisting of alkyl, cyanoalkyl, alkenyl, cycloalkyl, aryl, alkaryl and aralkyl, wherein any alkyl group present as all or part of R 6 and R 7 contains from 1 to 12 carbon atoms; R 8 is selected from the group consisting of alkyl, cycloalkyl, aryl, alkaryl and aralkyl wherein any alkyl group contains from 1 to 12 carbon atoms; R 9 is ##STR20## wherein R 11 and R 12 are individually selected from the group consisting of hydrogen, chlorine, bromine, iodine and alkyl containing from 1 to 12 carbon atoms; R 12 and R 14 are individually selected from the group consisting of hydrogen and alkyl containing from 1 to 12 carbon atoms; m is an integer equal to 1; n is 0, 1 or 2; p is 2 or 3; with the proviso that if R 1 is --NH 2 or --NO 2 , then n is 1 or 2.
Claim 3
Dependent Claim 18 words
A silane according to claim 1 wherein R 1 is --NH 2 , --NR 2 8 or --CHO.
Claim 4
Dependent Claim 11 words
A silane according to claim 1 wherein R 5 is propylene.
Claim 5
Dependent Claim 22 words
A silane according to claim 1 wherein R 6 and R 7 are alkyl and contain from 1 to 4 carbon atoms.
Claim 6
Dependent Claim 14 words
A silane according to claim 4 wherein R 6 and R 7 are methyl.
Claim 7
Dependent Claim 12 words
A silane according to claim 1 wherein n is 0 or 1.
Claim 8
Dependent Claim 15 words
A silane according to claim 1 wherein n is 1 and R 2 is methyl.
Claim 9
Dependent Claim 10 words
A silane according to claim 1 which is 3(p-formylphenoxy)propyl trimethoxysilane.
Claim 10
Dependent Claim 10 words
A silane according to claim 1 which is 3(m-diethylaminophenoxy)propyl trimethoxysilane.
Claim 11
Dependent Claim 10 words
A silane according to claim 1 which is 3(3-pyridyloxy)propyl trimethoxysilane.
Claim 12
Dependent Claim 11 words
A silane according to claim 1 which is 3,5 bis-(carbomethoxy)phenoxypropyl trimethoxysilane.
Claim 13
Dependent Claim 10 words
A silane according to claim 1 which is 3[o-propenyl)phenoxy]propyl trimethoxysilane.
Claim 14
Dependent Claim 10 words
A silane according to claim 1 which is p-carbomethoxyphenoxypropyl methyldimethoxysilane.
Claim 15
Dependent Claim 10 words
A silane according to claim 1 which is m-succinimidophenoxypropyl trimethoxysilane.
Claim 16
Dependent Claim 20 words
A silane according to claim 1 in which R 1 is alkenyl which contains from 2 to 10 carbon atoms.
Claim 17
Dependent Claim 17 words
A silane according to claim 1 wherein R 1 is CH 3 COO--, and n is 0.
Claim 18
Dependent Claim 15 words
A silane according to claim 1 wherein R 2 is alkyl and n is 2.

References Cited (Backward Citations)

US4049691A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-02-23 1990-08-25 1991-02-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-02-23 1994-08-25 1995-02-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-02-23 1998-08-25 1999-02-24 $7700.00 Window Closed / Lapsed

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