Blends of cyclic vinyl ether containing compounds and expoxides

Claim 2

A composition suitable for photocopolymerization comprising: (a) from about 5 to 95 parts by weight of a cyclic vinyl ether compound, said cyclic vinyl ether compound being a member selected from the group consisting of dihydropyranyl compounds, di-(dihydropyranyl) compounds, and mixtures of these; (b) from about 95 to 5 parts by weight of cycloaliphatic epoxide resins, said cycloaliphatic epoxide resins being a mixture of (i) 3,4-epoxy-cyclohexylmethyl-3,4-epoxycyclohexane carboxylate, (ii) bis(3,4-epoxycyclohexylmethyl)adipate, and (iii) 2-(3,4-epoxycyclohexyl)-5,5-spiro-3,4-epoxy)cyclohexane-meta-dioxane; (c) a vinyl cycloaliphatic monoepoxide, said vinyl cycloaliphatic monoepoxide being a member selected from the group consisting of the formulas: ##STR42## and mixtures of these; and (d) an amount of a photoinitiator effective to cure said composition.

Claim 3

A composition as defined in claim 1 wherein the cyclic vinyl ether compound is selected from the following: ##STR43## the Z's each represents hydrogen or an alkyl group having from 1 to 10 carbon atoms; X and X' are members of the class consisting of a bivalent saturated hydrocarbon group, R, having the structure, --C n H 2n --, wherein n is an integer having a value of from 1 to 10; an oxy radical, --O--; and a carbonyl group, --C(O)--; and, in addition X' may be a carbonyloxy group, --O(O)C--, the carbon atom of which is bonded to the 2-position of the dihydropyranyl ring; X and X' may be the same or different provided that taken together they contain either zero or 2 oxygen atoms; a has a value of from zero to 1, a being zero only when X' is the aforesaid carbonyloxy group; Q is a member of the class consisting of the aforesaid R group; a dioxylakylene group, --ORO--, wherein R is as defined above; a dicarboxylate group, --OC--(O)--R'--C(O)O,-- wherein R' is the nucleus of a dicarboxylic acid; and a polycarbamate group such as the dicarbamate group, --OC(O)NH--R"--NH--C(O)O--, wherein R", as illustrated is the nucleus of a diisocyanate; and X, X' and Q taken together is such that the linking chain, --X--Q--X'--, contains an even number of oxygen atoms from two to four, provided that when X and X' are both oxy radicals, the linking chain contains no other oxygen atoms (that is, Q or R), and when X and X' are both carbonyl groups, the linking chain contains four oxygen atoms (that is, Q is --ORO--).

Claim 4

A composition as defined in claim 1 wherein the cyclic vinyl ether compound is 3,4-dihydro-2H-pyran-2-methyl(3,4-dihydro-2H-pyran-2-carboxylates) having the formula: ##STR44## wherein Z and Z' are as above-defined.

Claim 5

A composition as defined in claim 1 wherein the cyclic vinyl ether compound is alkanedioxy-bis(3',4'-dihydro-2'H-pyran-2'-carbonyl) compounds having the structure: ##STR45## wherein Z and Z' are as defined in claim 2, and n is an integer from 1 to 10

Claim 6

A composition as defined in claim 1 wherein the cyclic vinyl ether compound is bis-(3',4'-dihydro-2'H-pyran-2'-oxy)alkanes having the formula: ##STR46## wherein Z, Z' are as defined in claim 2 and n is as defined in claim 4.

Claim 7

A composition as defined in claim 1 wherein the cyclic vinyl ether compound is bis-(3',4'-dihydro-2'H-pyran-2'-alkoxy)alkanes having the formula: ##STR47## wherein Z, Z' are as defined in claim 2 and n is as defined in claim 4.

Claim 8

A composition as defined in claim 1 wherein the cyclic vinyl ether compound is bis-(3',4'-dihydro-2'H-pyran-2'-alkyl)carboxylates having the general formula: ##STR48## wherein Z, Z' are as defined in claim 2, n is as defined in claim 4 and R' is the nucleus of a dicarboxylic acid and may be a bivalent aliphatic, cycloaliphatic or aromatic nucleus including corresponding halogen-substituted nuclei.

Claim 9

A composition as defined in claim 1 wherein the cyclic vinyl ether compound has the general formula: ##STR49## wherein Z, Z' are as defined in claim 2, n is as defined in claim 4, R" is an aliphatic, cycloaliphatic or aromatic radical which may be unsubstituted hydrocarbyl groups or hydrocarbyl groups substituted with halogen or alkoxy groups.

Claim 10

A composition as defined in claim 1 wherein said vinyl cycloaliphatic monoepoxide is vinyl cyclohexene monoepoxide.

Claim 11

A composition as claimed in claim 1 wherein the photoinitiator is selected from diazonium salts or onium salts, or mixtures thereof.

Claim 12

A radiation cured coating derived from the composition of claim 1.