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US4645340A Expired / Lapsed US ⏱️ 0.0 years remaining

Optically reflective sphere for efficient collection of Raman scattered light

Assignee: TRUSTEES OF BOSTONUNIVERSITY
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Filing: 1983-06-01
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Granted: 1987-02-24
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Expires: 2003-06-01
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Abstract

Abstract A device for the collection of Raman scattered light by means of an internally reflective sphere 10 wherein a light source 12 provides light to and through a sample 16, which light is reflected back through that sample by the internally reflective sphere 10. The sample is viewed by means of a spectrograph 30 focused by lenses 26, 28 or a fiberoptic light pipe 46.

Inventors

  • 👤 Daniel J. Graham
  • 👤 Richard A. Mushlin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 06:08
CPC Classifications
G; G01; G01N; G01N21/00; G01N21/62; G01N21/63; G01N21/65; G01N2201/00; G01N2201/06; G01N2201/065

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 89 words
A device for Raman scattered light collection and analysis characterized by: a. an internally optically reflective sphere having an illuminating aperture and a detection aperture therein; b. means for placing a material sample entirely in the center of the sphere; c. means for illuminating the material sample through the illuminating aperture such that light is redirected through the sample with reflection from the sphere; and d. detecting means for detecting Raman scattered light which is directed radially outward from the sample through the detection aperture toward the detecting means.
Claim 2
Independent Claim 89 words
A device for Raman scattered light collection and analysis characterized by: a. an internally optically reflective sphere having an illuminating aperture and a detection aperture therein; b. means for placing a material sample entirely in the center of the sphere; c. means for illuminating the material sample through the illuminating aperture such that light is redirected through the sample with reflection from the sphere; and d. detecting means for detecting Raman scattered light which is directed radially outward from the sample through the detection aperture toward the detecting means.
Claim 3
Dependent Claim 40 words
A device as claimed in claim 1 wherein the sphere is constructed of glass and where the inside surface of the glass is coated with a reflective film so that the interior of the sphere is highly reflective to light.
Claim 4
Dependent Claim 16 words
A device as claimed in claim 1 wherein the sphere is supported by a multipoint cradle.
Claim 5
Dependent Claim 18 words
A device as claimed in claim 1 wherein the means for illuminating is a nearly monochromatic light source.
Claim 6
Dependent Claim 31 words
A device as claimed in claim 1 or 2 wherein Raman scattered light is collected by a light pipe for analysis and conveyed to a spectrum analyzer by the light pipe.
Claim 7
Dependent Claim 35 words
A device as claimed in claim 1 or 2 wherein at least one lens of focal length approximately equal to the radius of the sphere is used to collect Raman scattered light for spectroscopic analysis.
Claim 8
Independent Claim 130 words
A device for Raman scattered light collection and analysis comprising: an internally optically reflective sphere; means for placing a material sample in the center of the sphere; means for illuminating the material sample through a first pinhole in the sphere; a second pinhole diametrically opposite the first pinhole and light source; a first concave mirror outside of the sphere behind said second pinhole; a third pinhole displaced from the first and second pinholes; a second concave mirror outside of the sphere behind said third pinhole, the third pinhole and the second mirror being positioned such that the second mirror receives light from the first concave mirror and reintroduces it through the third pinhole into the sphere directed toward the sample; and means for detecting Raman scattered light from the sample.
Claim 9
Independent Claim 130 words
A device for Raman scattered light collection and analysis comprising: an internally optically reflective sphere; means for placing a material sample in the center of the sphere; means for illuminating the material sample through a first pinhole in the sphere; a second pinhole diametrically opposite the first pinhole and light source; a first concave mirror outside of the sphere behind said second pinhole; a third pinhole displaced from the first and second pinholes; a second concave mirror outside of the sphere behind said third pinhole, the third pinhole and the second mirror being positioned such that the second mirror receives light from the first concave mirror and reintroduces it through the third pinhole into the sphere directed toward the sample; and means for detecting Raman scattered light from the sample.
Claim 10
Independent Claim 168 words
A device for Raman scattered light collection and analysis comprising: an internally optically reflective sphere; means for placing a material sample in the center of the sphere; means for illuminating the material sample through a first pinhole in the sphere; a second pinhole diametrically opposite the first pinhole and light source; a first concave mirror outside of the sphere behind said second pinhole; a third pinhole displaced from the first and second pinholes; a second concave mirror outside of the sphere behind said third pinhole, the third pinhole and the second mirror being positioned such that the second mirror receives light from the first concave mirror and reintroduces it through the third pinhole into the sphere directed toward the sample; a fourth pinhole opposite said third pinhole; a mirror positioned outside of the sphere behind said fourth pinhole to receive light from the second mirror and focus the light back through the fourth pinhole onto the material sample; and means for detecting Raman scattered light from the sample.
Claim 11
Independent Claim 168 words
A device for Raman scattered light collection and analysis comprising: an internally optically reflective sphere; means for placing a material sample in the center of the sphere; means for illuminating the material sample through a first pinhole in the sphere; a second pinhole diametrically opposite the first pinhole and light source; a first concave mirror outside of the sphere behind said second pinhole; a third pinhole displaced from the first and second pinholes; a second concave mirror outside of the sphere behind said third pinhole, the third pinhole and the second mirror being positioned such that the second mirror receives light from the first concave mirror and reintroduces it through the third pinhole into the sphere directed toward the sample; a fourth pinhole opposite said third pinhole; a mirror positioned outside of the sphere behind said fourth pinhole to receive light from the second mirror and focus the light back through the fourth pinhole onto the material sample; and means for detecting Raman scattered light from the sample.
Claim 12
Independent Claim 61 words
A method of analyzing Raman light scattered by a material sample comprising: placing a material sample entirely at the center of an internally, optically reflective sphere; shining light through the material sample and redirecting light through the sample with reflection from the sphere; and through an aperture in the sphere detecting Raman light scattered and directed radially outward from the sample.
Claim 13
Independent Claim 61 words
A method of analyzing Raman light scattered by a material sample comprising: placing a material sample entirely at the center of an internally, optically reflective sphere; shining light through the material sample and redirecting light through the sample with reflection from the sphere; and through an aperture in the sphere detecting Raman light scattered and directed radially outward from the sample.
Claim 14
Dependent Claim 41 words
A method of analyzing Raman light scattered by a material sample as claimed in claim 9 wherein the Raman scatterd light is detected through a light pipe placed between the sample on one end and a spectrograph at the other end.
Claim 15
Dependent Claim 25 words
A method of analyzing Raman light scattered by a material sample as claimed in claim 9 wherein laser light is shown through the material sample.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-02-23 1990-08-25 1991-02-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-02-23 1994-08-25 1995-02-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-02-23 1998-08-25 1999-02-24 $7700.00 Window Closed / Lapsed

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