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US4643737A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyol-acid anhydride-N-alkyl-alkylene diamine reaction product and motor fuel composition containing same

Assignee: Texaco Inc
•
Filing: 1985-10-25
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Granted: 1987-02-17
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Expires: 2005-10-25
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Abstract

Abstract Gasoline of reduced combusiton chamber deposits attained by addition of, as an additive, a reaction product of alpha-hydroxy omega hydroxy-poly (oxyethylene) poly (oxypropylene) poly (oxyethylene) block copolymer, maleic anhydride and N-tallow-1,3-propane diamine.

Inventors

  • 👤 Rodney L. Sung
  • 👤 Robert H. Jenkins, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 08:29
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/10; C10L1/14; C10L1/22; C10L1/222; C10L1/2222; C10L1/221

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 94 words
A fuel composition for an internal combustion engine comprising: (a) a major portion of a liquid hydrocarbon fuel and (b) a minor amount, as a deposit inhibitor additive, of a reaction product of a process comprising: (i) reacting a dibasic acid anhydride with a polyol of the formula ##STR6## where a+c is about 10 to about 80 and b is about 5 to about 70; thereby forming an ester of maleic acid; (ii) reacting said ester of maleic acid with an N-alkyl-alkylene diamine, thereby forming the reaction product; and (iii) recovering said reaction product.
Claim 2
Dependent Claim 94 words
A fuel composition for an internal combustion engine comprising: (a) a major portion of a liquid hydrocarbon fuel and (b) a minor amount, as a deposit inhibitor additive, of a reaction product of a process comprising: (i) reacting a dibasic acid anhydride with a polyol of the formula ##STR6## where a+c is about 10 to about 80 and b is about 5 to about 70; thereby forming an ester of maleic acid; (ii) reacting said ester of maleic acid with an N-alkyl-alkylene diamine, thereby forming the reaction product; and (iii) recovering said reaction product.
Claim 3
Dependent Claim 22 words
The fuel composition of claim 1, wherein said polyol has a molecular weight M n ranging from about 800 to about 2000.
Claim 4
Dependent Claim 14 words
The fuel composition of claim 1, wherein said polyol reacts with a dibasic acid.
Claim 5
Dependent Claim 28 words
The fuel composition of claim 3, wherein said dibasic acid anhydride has the formula ##STR7## where R is H, CH 3 -- or C 2 H 5 --.
Claim 6
Dependent Claim 36 words
The fuel composition of claim 1, wherein said N-alkyl-alkylene diamine has the formula R'--NH--R"--NH.sub.2 wherein R' is a (C 12 -C 18 ) hydrocarbon group and R" is a (C 3 -C 12 ) hydrocarbon group.
Claim 7
Dependent Claim 140 words
A fuel composition for an internal combustion engine comprising: (a) a major portion of a liquid hydrocarbon fuel having a boiling point of about 75° F. to about 450° F.; and (b) a minor amount, as a deposit-inhibiting additive of a reaction product of the process comprising: (i) reacting a polyol ##STR8## where a+c is about 10 to about 80 and b is about 5 to about 70, with a dibasic acid anhydride ##STR9## where R is H, CH 3 -- or C 2 H 5 --, thereby forming an ester of maleic acid; (ii) reacting said ester of maleic acid with an N-alkyl alkylene diamine R'--NH--R"--NH.sub.2 where R' is a (C 12 -C 18 ) hydrocarbon group and R" is (C 3 -C 12 ) hydrocarbon group, thereby forming a reaction product ##STR10## and (iii) recovering said reaction product.
Claim 8
Dependent Claim 140 words
A fuel composition for an internal combustion engine comprising: (a) a major portion of a liquid hydrocarbon fuel having a boiling point of about 75° F. to about 450° F.; and (b) a minor amount, as a deposit-inhibiting additive of a reaction product of the process comprising: (i) reacting a polyol ##STR8## where a+c is about 10 to about 80 and b is about 5 to about 70, with a dibasic acid anhydride ##STR9## where R is H, CH 3 -- or C 2 H 5 --, thereby forming an ester of maleic acid; (ii) reacting said ester of maleic acid with an N-alkyl alkylene diamine R'--NH--R"--NH.sub.2 where R' is a (C 12 -C 18 ) hydrocarbon group and R" is (C 3 -C 12 ) hydrocarbon group, thereby forming a reaction product ##STR10## and (iii) recovering said reaction product.
Claim 9
Dependent Claim 20 words
A motor fuel composition according to claim 6 containing from about 0.001 to 0.01 weight percent of said reaction product.
Claim 10
Dependent Claim 20 words
A motor fuel composition according to claim 1 containing from about 0.001 to 0.01 weight percent of said reaction product.
Claim 11
Dependent Claim 24 words
The motor fuel composition of claim 1, wherein the process is carried out at a temperature of about 100° C. for about 2 hours.
Claim 12
Dependent Claim 24 words
The motor fuel composition of claim 6, wherein the process is carried out at a temperature of about 100° C. for about 2 hours.

References Cited (Backward Citations)

US4384872A Cited
US4348210A Cited
US4419105A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-02-16 1990-08-18 1991-02-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-02-16 1994-08-18 1995-02-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-02-16 1998-08-18 1999-02-17 $7700.00 Window Closed / Lapsed

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