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US4642197A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the production of a washing additive in tablet form

Assignee: Henkel AG and Co KGaA
•
Filing: 1985-05-13
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Granted: 1987-02-10
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Expires: 2005-05-13
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Abstract

Abstract A powdery activator for per compounds is granulated by, at the same time, mixing it together with nonionic surface-active compounds certain nitrogen-containing compounds and, optionally, the water-soluble salt of an alkane polyphosphonic acid. The granulate thus obtained is powdered with a powdery absorbent and the powdered granulate is sprayed with a liquid binder and dried to a water content of at most 6% by weight. After the addition of a tablet disintegrating agent, the dried granulate is formed by compression under special conditions into tablets having special properties. When added to a wash liquor containing a standard detergent containing a per compound, the tablets improve the removal of fatty/oily stains, pigment-containing soil and bleachable stains.

Inventors

  • 👤 Hans Kruse
  • 👤 Klaus Koester
  • 👤 Franz-Josef Carduck
  • 👤 Heinz-Manfred Wilsberg
  • 👤 Rolf Puchta

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 14:49
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/39; C11D3/3902; C11D3/3905; C11D3/3907; C11D1/00; C11D1/02; C11D1/04; C11D1/10; C11D1/38; C11D1/42; C11D1/44; C11D1/62; C11D17/00; C11D17/0039; C11D17/0047; C11D17/0065; C11D17/0073; C11D3/3935

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 263 words
A process for the production of a washion additive in tablet form containing on a weight basis of said tablet (1) 2 to 30% of at least one activator for per compounds (2) 2 to 30% of at least one nonionic surface-active compound, (3) 0.5 to 20% of at least one surface-active nitrogen-containing compound selected from the group consisting of quaternary ammonium compounds, fatty amine compounds, aminopropionic acid compounds, and mixtures thereof, (4) 0 to 5% of at least one water-soluble salt of an alkane polyphosphonic acid, and (5) 0 to 5% of at least one foam regulator, as wash-active ingredients, comprising the steps of: A. granulating component (1) while simultaneously mixing therewith components (2) and (3) as well as components (4) and (5) if present, together with tabletting aids; B. powdering the resulting granulate with a powder-form adsorbent; C. spraying the powdered granulate with a liquid binder, said liquid binder being a solution of cane sugar or sorbitol; D. drying the granulate to a water content of not more than 6% by weight to form a free-flowing granulate; E. mixing the dried granulate with at least one tablet disintegrating agent; and F. compressing the granulate into tablets of more than 30 mm in diameter and having a depth of 0.75 to 1.1 times their diameter but said depth being at least 25 mm, a density of from 0.8 to 1.2 g/cm 3 , a weight of from 15 to 50g, and a breaking strength of from 6 to 12 kg, whereby the tablets contain sufficient detergency-boosting ingredients for one load of washing.
Claim 2
Dependent Claim 263 words
A process for the production of a washion additive in tablet form containing on a weight basis of said tablet (1) 2 to 30% of at least one activator for per compounds (2) 2 to 30% of at least one nonionic surface-active compound, (3) 0.5 to 20% of at least one surface-active nitrogen-containing compound selected from the group consisting of quaternary ammonium compounds, fatty amine compounds, aminopropionic acid compounds, and mixtures thereof, (4) 0 to 5% of at least one water-soluble salt of an alkane polyphosphonic acid, and (5) 0 to 5% of at least one foam regulator, as wash-active ingredients, comprising the steps of: A. granulating component (1) while simultaneously mixing therewith components (2) and (3) as well as components (4) and (5) if present, together with tabletting aids; B. powdering the resulting granulate with a powder-form adsorbent; C. spraying the powdered granulate with a liquid binder, said liquid binder being a solution of cane sugar or sorbitol; D. drying the granulate to a water content of not more than 6% by weight to form a free-flowing granulate; E. mixing the dried granulate with at least one tablet disintegrating agent; and F. compressing the granulate into tablets of more than 30 mm in diameter and having a depth of 0.75 to 1.1 times their diameter but said depth being at least 25 mm, a density of from 0.8 to 1.2 g/cm 3 , a weight of from 15 to 50g, and a breaking strength of from 6 to 12 kg, whereby the tablets contain sufficient detergency-boosting ingredients for one load of washing.
Claim 3
Dependent Claim 32 words
The process of claim 1 wherein, before said granulate is formed, from 1 to 5% by weight, base on the granulate without its protective layer, of a granulate disintegrating agent is added.
Claim 4
Dependent Claim 37 words
The process of claim 1 wherein in step E. from 10 to 20% by weight, based on the final mixture before tabletting of at least one tablet disintegrating agent is added to said dried granulate before tabletting.
Claim 5
Dependent Claim 18 words
The process of claim 3 wherein a mixture of at least two different tablet disintegrating agents are added.
Claim 6
Dependent Claim 27 words
The process of claim 4 wherein said tablet disintegrating agents are selected from the group consisting of crosslinked polyvinyl pyrrolidone, cellulose ethers and swellable magnesium aluminum silicate.
Claim 7
Dependent Claim 38 words
The process of claim 5 wherein, where two different disintegrating agents are mixed, crosslinked polyvinyl pyrrolidone is added in admixture with cellulose ethers and/or swellable magnesium aluminum silicate in a ratio by weight of from 8:1 to 2:1.
Claim 8
Dependent Claim 123 words
The process of claim 1 wherein said activator for per compounds is an N-acyl or O-acyl compound, said nonionic surface-active compound is a C 12 -C 18 alkanol ethoxylate, said surface-active nitrogen-containing compound is selected from the group consisting of quaternary ammonium compounds containing a C 10 -C 20 alkyl or alkenyl radical and, for the rest, C 1 -C 4 alkyl radicals, adducts of from 1 to 6 mols of ethylene oxide onto 1 mol of a primary fatty amine containing a C 10 -C 16 alkyl or alkenyl radical and the sodium salt of β-aminoalkyl or alkenyl propionic acid corresponding to the formula R--NH--CH 2 --CH 2 --COONa, in which R is a C 10 -C 16 alkyl or alkenyl radical.
Claim 9
Dependent Claim 19 words
The process of claim 1 wherein said at least one water-soluble salt of an alkane polyphosphonic acid is present.
Claim 10
Dependent Claim 18 words
The process of claim 1 wherein said at least one foam regulator is present and is foam inhibitor.
Claim 11
Dependent Claim 29 words
The process of claim 1 wherein said tabletting aids in said granulation step A. are one or more water-insoluble or water-soluble powdery carriers for liquid or pasty wash-active ingredients.
Claim 12
Dependent Claim 32 words
The process of claim 7 wherein said C 12 -C 18 alkanol ethoxylate is a C 14 -C 15 oxoalcohol ethoxylated with about 7 mols of ethylene oxide per mol of alcohol.
Claim 13
Dependent Claim 14 words
The process of claim 7 wherein said quaternary ammonium compound is tetradecyl trimethylammonium bromide.
Claim 14
Dependent Claim 33 words
The process of claim 8 wherein said alkane polyphosphonic acid is an alkali-metal salt of an acid selected from the group consisting of phosphonoalkane polyphosphonic acids and amino- and hydroxy-substituted alkane polyphosphonic acids.
Claim 15
Dependent Claim 41 words
The process of claim 13 wherein said alkali-metal salt of an acid is an acid selected from the group consisting of amino-tris-(methylenephosphonic acid), dimethylamino-methane disphosponic acids, 1-hydroxyethane-1, 1-disphosphonic acid, 1-phosphonoethane-1, 2-dicarboxylic acid, 2-phosphonobutane-1, 2, 4-tricarboxylic acid and, ethylenediamine tetramethylene, phosphonic acid.
Claim 16
Dependent Claim 22 words
The process of claim 14 wherein said alkali metal salt of an acid is the hexasodium salt of ethylenediamine tetramethylene phosphonic acid.

References Cited (Backward Citations)

US3789002A Cited
GB1423536A Cited
DE2535183A1 Cited
EP0000226A1 Cited
DE2857153A1 Cited
US4220562A Cited
US4290903A Cited
US4444674A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-02-09 1990-08-11 1991-02-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-02-09 1994-08-11 1995-02-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-02-09 1998-08-11 1999-02-10 $7700.00 Window Closed / Lapsed

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