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US4640852A Expired / Lapsed US ⏱️ 0.0 years remaining

Multiple layer films containing oriented layers of nylon and ethylene vinyl alcohol copolymer

Assignee: Pechiney Plastic Packaging Inc
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Filing: 1984-11-28
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Granted: 1987-02-03
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Expires: 2004-11-28
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Abstract

Abstract A multiple layer sheet structure has oriented layers of nylon and EVOH. Additional layers may or may not be utilized, and may or may not be oriented. Where additional layers are used, one of the additional layers, on the exterior surface of the structure, is preferably heat sealable. The structure shows improved impact resistance, after retort processing, over similar structures not having oriented nylon and EVOH layers. In certain embodiments, retort processed pouches made from the packaging structures have improved stress crack resistance when dropped onto a hard surface.

Inventors

  • 👤 William F. Ossian

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 14:52
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/06; B32B27/08; B29; B29C; B29C48/00; B29C48/03; B29C48/07; B29C48/08; B29C48/16; B29C48/18; B29C48/185; B32B27/18; B32B27/22; B32B27/30; B32B27/306; B32B27/34; B32B7/00; B32B7/04; B32B7/12; B65; B65D; B65D31/00; B65D31/02; B32B2307/00; B32B2307/30; B32B2307/31; B32B2307/50; B32B2307/514; Y; Y10; Y10S; Y10S428/00; Y10S428/91; Y10T; Y10T428/00; Y10T428/13; Y10T428/1334; Y10T428/1341; Y10T428/28; Y10T428/2813; Y10T428/2817; Y10T428/2826; Y10T428/2848; Y10T428/31504; Y10T428/31725; Y10T428/31739; Y10T428/31743; Y10T428/31746

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 76 words
A multiple layer oriented sheet structure wherein the layers are firmly adhered to each other, said sheet structure comprising a first oriented layer of nylon, and in face to face contact with said first layer, a second oriented layer of ethylene vinyl alcohol copolymer, said second layer containing an effective amount of a plasticizer therefore, said sheet structure being capable of withstanding retort conditions for 30 minutes at 250° F. without substantial embrittlement of said layers.
Claim 2
Dependent Claim 76 words
A multiple layer oriented sheet structure wherein the layers are firmly adhered to each other, said sheet structure comprising a first oriented layer of nylon, and in face to face contact with said first layer, a second oriented layer of ethylene vinyl alcohol copolymer, said second layer containing an effective amount of a plasticizer therefore, said sheet structure being capable of withstanding retort conditions for 30 minutes at 250° F. without substantial embrittlement of said layers.
Claim 3
Dependent Claim 119 words
A multiple layer oriented sheet structure wherein the layers are firmly adhered to each other, said sheet structure comprising a first oriented layer of nylon, and in face to face contact with said first layer, a second oriented layer of ethylene vinyl alcohol copolymer, and a third oriented layer of nylon in face to face contact with said second layer of ethylene vinyl alcohol copolymer, said structure thus comprising a layer of ethylene vinyl alcohol copolymer with a layer of nylon on each of the surfaces thereof, said second layer containing an effective amount of a plasticizer therefore, said sheet structure being capable of withstanding retort conditions for 30 minutes at 250° F. without substantial embrittlement of said layers.
Claim 4
Dependent Claim 119 words
A multiple layer oriented sheet structure wherein the layers are firmly adhered to each other, said sheet structure comprising a first oriented layer of nylon, and in face to face contact with said first layer, a second oriented layer of ethylene vinyl alcohol copolymer, and a third oriented layer of nylon in face to face contact with said second layer of ethylene vinyl alcohol copolymer, said structure thus comprising a layer of ethylene vinyl alcohol copolymer with a layer of nylon on each of the surfaces thereof, said second layer containing an effective amount of a plasticizer therefore, said sheet structure being capable of withstanding retort conditions for 30 minutes at 250° F. without substantial embrittlement of said layers.
Claim 5
Dependent Claim 108 words
A multiple layer flexible packaging sheet structure wherein the layers are firmly adhered to each other in face to face contact, said sheet structure comprising in order: (a) a first oriented layer of nylon; (b) a second oriented layer of ethylene vinyl alcohol copolymer; (c) a third oriented layer of nylon; (d) a fourth adhesive layer; and (e) a fifth layer of a heat sealable olefinic polymer; at least said recited first, second, and third layers being molecularly oriented, said second layer containing an effective amount of a plasticizer therefore, said sheet structure being capable of withstanding retort conditions for 30 minutes at 250° F. without substantial embrittlement.
Claim 6
Dependent Claim 108 words
A multiple layer flexible packaging sheet structure wherein the layers are firmly adhered to each other in face to face contact, said sheet structure comprising in order: (a) a first oriented layer of nylon; (b) a second oriented layer of ethylene vinyl alcohol copolymer; (c) a third oriented layer of nylon; (d) a fourth adhesive layer; and (e) a fifth layer of a heat sealable olefinic polymer; at least said recited first, second, and third layers being molecularly oriented, said second layer containing an effective amount of a plasticizer therefore, said sheet structure being capable of withstanding retort conditions for 30 minutes at 250° F. without substantial embrittlement.
Claim 7
Dependent Claim 28 words
A multiple layer sheet structure as in claim 3 and including a sixth layer of an adhesive adhering a seventh olefinic heat seal layer to said fifth layer.
Claim 8
Dependent Claim 17 words
A multiple layer sheet structure as in claim 4 wherein said fourth and sixth layers are polymeric.
Claim 9
Dependent Claim 47 words
A multiple layer sheet structure as in claim 4 wherein the predominant polymer of the composition of said seventh layer is selected from the group consisting of linear low density polyethylene copolymer, propylene ethylene copolymer, and blends of linear low density polyethylene copolymer and propylene ethylene copolymer.
Claim 10
Dependent Claim 47 words
A multiple layer sheet structure as in claim 5 wherein the predominant polymer of the composition of said seventh layer is selected from the group consisting of linear low density polyethylene copolymer, propylene ethylene copolymer, and blends of linear low density polyethylene copolymer and propylene ethylene copolymer.
Claim 11
Dependent Claim 12 words
A retortable pouch made from the packaging sheet structure of claim 3.
Claim 12
Dependent Claim 12 words
A retortable pouch made from the packaging sheet structure of claim 4.
Claim 13
Dependent Claim 12 words
A retortable pouch made from the packaging sheet structure of claim 5.
Claim 14
Dependent Claim 12 words
A retortable pouch made from the packaging sheet structure of claim 6.
Claim 15
Dependent Claim 118 words
A retortable pouch made from a multiple layer flexible sheet structure, wherein the layers are firmly adhered to each other in face to face contact, said sheet structure comprising, in order: (a) a first layer of nylon; (b) a second layer of ethylene vinyl alcohol copolymer containing an effective amount of a plasticizer therefore; (c) a third layer of nylon; (d) a fourth layer of anhydride modified polyolefin; and (e) a fifth layer of a heat sealable olefinic polymer; said film having been made by coextruding said first, second, third, fourth and fifth layers to form a five layer film, and subsequently molecularly orienting said five layer film, such that each of said five layers is molecularly oriented.
Claim 16
Dependent Claim 118 words
A retortable pouch made from a multiple layer flexible sheet structure, wherein the layers are firmly adhered to each other in face to face contact, said sheet structure comprising, in order: (a) a first layer of nylon; (b) a second layer of ethylene vinyl alcohol copolymer containing an effective amount of a plasticizer therefore; (c) a third layer of nylon; (d) a fourth layer of anhydride modified polyolefin; and (e) a fifth layer of a heat sealable olefinic polymer; said film having been made by coextruding said first, second, third, fourth and fifth layers to form a five layer film, and subsequently molecularly orienting said five layer film, such that each of said five layers is molecularly oriented.
Claim 17
Dependent Claim 154 words
A retortable pouch made from a multiple layer flexible sheet structure, wherein the layers are firmly adhered to each other in face to face contact, said sheet structure comprising, in order; (a) a first layer of nylon; (b) a second layer of ethylene vinyl alcohol copolymer containing an effective amount of a plasticizer therefore; (c) a third layer of nylon; (d) a fourth layer of anhydride modified polyolefin; (e) a fifth layer of a heat sealable olefinic polymer; (f) a sixth polymeric adhesive layer; and (g) a seventh olefinic heat seal layer; said film having been formed by: (1) coextruding said first, second, third, fourth and fifth layers to form a five layer film; (2) molecularly orienting said five layer film, such that each of said five layers is molecularly oriented; (3) forming said seventh olefinic layer; and (4) adhering said seventh layer to said fifth layer by means of said sixth adhesive layer.
Claim 18
Dependent Claim 154 words
A retortable pouch made from a multiple layer flexible sheet structure, wherein the layers are firmly adhered to each other in face to face contact, said sheet structure comprising, in order; (a) a first layer of nylon; (b) a second layer of ethylene vinyl alcohol copolymer containing an effective amount of a plasticizer therefore; (c) a third layer of nylon; (d) a fourth layer of anhydride modified polyolefin; (e) a fifth layer of a heat sealable olefinic polymer; (f) a sixth polymeric adhesive layer; and (g) a seventh olefinic heat seal layer; said film having been formed by: (1) coextruding said first, second, third, fourth and fifth layers to form a five layer film; (2) molecularly orienting said five layer film, such that each of said five layers is molecularly oriented; (3) forming said seventh olefinic layer; and (4) adhering said seventh layer to said fifth layer by means of said sixth adhesive layer.
Claim 19
Dependent Claim 139 words
A retortable pouch made from a multiple layer flexible sheet structure, wherein the layers are firmly adhered to each other in face to face contact, said sheet structure comprising, in order; (a) a first layer of nylon; (b) a second layer of ethylene vinyl alcohol copolymer containing an effective amount of a plasticizer therefore; (c) a third layer of nylon; (d) a fourth layer of anhydride modified polyolefin; and (e) a fifth layer of a heat sealable olefinic polymer; said film having been formed by: (1) coextruding said first, second, and third layers to form a three layer film; (2) molecularly orienting said three layer film, such that each of said three layers is molecularly oriented; (3) extruding said fifth olefinic layer; and (4) adhering said fifth layer to said third layer by means of said fourth adhesive layer.
Claim 20
Dependent Claim 139 words
A retortable pouch made from a multiple layer flexible sheet structure, wherein the layers are firmly adhered to each other in face to face contact, said sheet structure comprising, in order; (a) a first layer of nylon; (b) a second layer of ethylene vinyl alcohol copolymer containing an effective amount of a plasticizer therefore; (c) a third layer of nylon; (d) a fourth layer of anhydride modified polyolefin; and (e) a fifth layer of a heat sealable olefinic polymer; said film having been formed by: (1) coextruding said first, second, and third layers to form a three layer film; (2) molecularly orienting said three layer film, such that each of said three layers is molecularly oriented; (3) extruding said fifth olefinic layer; and (4) adhering said fifth layer to said third layer by means of said fourth adhesive layer.
Claim 21
Dependent Claim 161 words
A retortable pouch made from a multiple layer flexible sheet structure, wherein the layers are firmly adhered to each other in face to face contact, said sheet structure comprising, in order; (a) a first layer of nylon; (b) a second layer of ethylene vinyl alcohol copolymer containing an effective amount of a plasticizer therefore; (c) a third layer of nylon; (d) a fourth layer of an anhydride modified polyolefin; (e) a fifth layer of a heat sealable olefinic polymer; (f) a sixth polymeric adhesive layer; and (g) a seventh olefinic heat seal layer; said film having been formed by; (1) coextruding said first, second, and third layers to form a three layer film; (2) molecularly orienting said three layer film, such that each of said three layers is molecularly oriented; (3) forming said fifth, sixth and seventh layers and adhering them together with good adhesion; and (4) adhering said fifth layer to said third layer by means of said fourth layer.
Claim 22
Dependent Claim 161 words
A retortable pouch made from a multiple layer flexible sheet structure, wherein the layers are firmly adhered to each other in face to face contact, said sheet structure comprising, in order; (a) a first layer of nylon; (b) a second layer of ethylene vinyl alcohol copolymer containing an effective amount of a plasticizer therefore; (c) a third layer of nylon; (d) a fourth layer of an anhydride modified polyolefin; (e) a fifth layer of a heat sealable olefinic polymer; (f) a sixth polymeric adhesive layer; and (g) a seventh olefinic heat seal layer; said film having been formed by; (1) coextruding said first, second, and third layers to form a three layer film; (2) molecularly orienting said three layer film, such that each of said three layers is molecularly oriented; (3) forming said fifth, sixth and seventh layers and adhering them together with good adhesion; and (4) adhering said fifth layer to said third layer by means of said fourth layer.

References Cited (Backward Citations)

US4095012A Cited
US4241130A Cited
US4552801A Cited
US4405667A Cited
US4461808A Cited
US4501798A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-02-02 1990-08-04 1991-02-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-02-02 1994-08-04 1995-02-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-02-02 1998-08-04 1999-02-03 $7700.00 Window Closed / Lapsed

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