US4639416A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Internal latent image-type silver halide emulsion
Assignee: Fujifilm Holdings Corp
•
Filing: 1984-05-11
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Granted: 1987-01-27
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Expires: 2004-05-11
Abstract
Abstract An internal latent image-type silver halide emulsion containing core/shell type silver halide grains with a mean grain size of about 0.4 μm or less, the grains comprising a core of chemically sensitized silver halide and a shell of silver halide covering at least the light-sensitive sites of the core and the surface of the grains being chemically sensitized wherein the core is chemically sensitized to such an extent that the difference between fog density F 1 and fog density F 2 as defined herein (i.e., internal fog density) is at least 0.10. This emulsion permits the formation of good reversal images in which D max is high and D min is low and, furthermore, has a superior storage stability.
Inventors
- 👤 Tetsuo Yoshida
- 👤 Tadayoshi Kokubo
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 18:04
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/485; G03C1/035; G03C2001/03535; Y; Y10; Y10S; Y10S430/00; Y10S430/141
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
245 words
An internal latent image silver halide emulsion containing core/shell silver halide grains with a mean grain size of about 0.4 μm or less, said grains comprising a core of chemically sensitized silver halide and a shell of silver halide covering at least the light-sensitive sites of the core, and the surface of said grains being chemically sensitized, wherein the core is chemically sensitized to such an extent that the difference between fog density F 1 and fog density F 2 as defined below is at least 0.10, where fog density F 1 is the fog density when the internal latent image emulsion is coated in an amount (as silver) of 1.5 g/m 2 and developed with Developer D as described below at 20° C. for 13 minutes without application of imagewise exposure, not including base density; ______________________________________
Composition of Developer D
______________________________________
N--Methyl-p-aminophenol Sulfate
2.5 g
L--Ascorbic Acid 10 g
Sodium Metaborate 35 g
Potassium Bromide 1 g
Sodium Thiosulfate 3 g
Water to make 1,000 ml
______________________________________ and fog density F 2 is the fog density when the internal latent image emulsion is coated in an amount (as silver) of 1.5 g/m 2 and developed with Developer E as described below at 20° C. for 13 minutes without application of imagewise exposure, not including base density ______________________________________
Composition of Developer E
______________________________________
N--Methyl-p-aminophenol Sulfate
2.5 g
L--Ascoribc Acid 10 g
Sodium Metaborate 35 g
Potassium Bromide 1 g
Water to make 1,000 ml
______________________________________
Claim 2
Dependent Claim
245 words
An internal latent image silver halide emulsion containing core/shell silver halide grains with a mean grain size of about 0.4 μm or less, said grains comprising a core of chemically sensitized silver halide and a shell of silver halide covering at least the light-sensitive sites of the core, and the surface of said grains being chemically sensitized, wherein the core is chemically sensitized to such an extent that the difference between fog density F 1 and fog density F 2 as defined below is at least 0.10, where fog density F 1 is the fog density when the internal latent image emulsion is coated in an amount (as silver) of 1.5 g/m 2 and developed with Developer D as described below at 20° C. for 13 minutes without application of imagewise exposure, not including base density; ______________________________________
Composition of Developer D
______________________________________
N--Methyl-p-aminophenol Sulfate
2.5 g
L--Ascorbic Acid 10 g
Sodium Metaborate 35 g
Potassium Bromide 1 g
Sodium Thiosulfate 3 g
Water to make 1,000 ml
______________________________________ and fog density F 2 is the fog density when the internal latent image emulsion is coated in an amount (as silver) of 1.5 g/m 2 and developed with Developer E as described below at 20° C. for 13 minutes without application of imagewise exposure, not including base density ______________________________________
Composition of Developer E
______________________________________
N--Methyl-p-aminophenol Sulfate
2.5 g
L--Ascoribc Acid 10 g
Sodium Metaborate 35 g
Potassium Bromide 1 g
Water to make 1,000 ml
______________________________________
Claim 3
Dependent Claim
34 words
The silver halide emulsion of claim 1, wherein said silver halide of the core and of the shell is chemically sensitized using sulfur sensitization, reduction sensitization, noble metal sensitization or a combination of such.
Claim 4
Dependent Claim
31 words
The silver halide emulsion of claim 1, wherein the chemically sensitized silver halide of the core and of the shell is sensitized using a combination of gold sensitization and sulfur sensitization.
Claim 5
Dependent Claim
44 words
The silver halide emulsion of claim 1, wherein the chemically sensitized silver halide of the core and of the shell is sensitized at a pH of 9 or less, a pAg of 10 or less and at a temperature of 40° C. or less.
Claim 6
Dependent Claim
65 words
The silver halide emulsion of claim 1, wherein the core of chemically sensitized silver halide is doped with one or more metal ions selected from the group consisting of cadmium ions, zinc ions, thallium ions, iridium ions, iridium complex ions, rhodium ions, rhodium complex ions, iron ions or iron complex ions, in an amount of at least 10 -6 mol per mol of silver halide.
Claim 7
Dependent Claim
25 words
The silver halide emulsion of claim 1, wherein said silver halide is silver bromide, silver iodide, silver chloride, silver chlorobromide, silver bromoiodide or silver chlorobromoiodide.
Claim 8
Dependent Claim
28 words
The silver halide emulsion of claim 1, wherein said silver halide comprises at least 50 mol% of silver bromide and about 10 mol% or less of silver iodide.
Claim 9
Dependent Claim
29 words
The silver halide emulsion of claim 1, wherein the difference between fog density F 1 and fog density F 2 is at least 0.15 and not more than 0.50.
Claim 10
Dependent Claim
24 words
The silver halide emulsion of claim 1, wherein the core/shell silver halide grains have a mean grain size of about 0.05 to 0.4 μm.
Claim 11
Dependent Claim
24 words
The silver halide emulsion of claim 9, wherein the core/shell silver halide grains have a mean grain size of about 0.1 to 0.3 μm.
Claim 12
Dependent Claim
24 words
A photographic light-sensitive element comprising a support having thereon at least one layer containing the internal latent image silver halide emulsion of claim 1.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-01-26 | 1990-07-28 | 1991-01-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-01-26 | 1994-07-28 | 1995-01-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-01-26 | 1998-07-28 | 1999-01-27 | $7700.00 | Window Closed / Lapsed |