← Back to Patent Explorer
US4634514A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrochemical apparatus and method of manufacturing the same

Assignee: NGK Insulators Ltd
•
Filing: 1986-02-07
•
Granted: 1987-01-06
•
Expires: 2006-02-07
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract In an electrochemical apparatus utilizing an electrochemical cell having a solid-electrolyte and at least one pair of porous electrodes arranged in contact with the solid-electrolyte, wherein one electrode of the pair of electrodes is exposed through a diffusion means having a diffusion resistance with respect to a gas to be measured in a space in which the gas to be measured is present, and an atmosphere near one of the electrodes is controlled by an electrode reaction due to a current flowing through the pair of electrodes, a first branch conductor and a second branch conductor are formed by dividing one of conductors respectively connected to the electrodes, and at least one adjustable first resistive means and at least one second resistive means are respectively formed in the first branch conductor and the second branch conductor. Therefore, a predetermined current flows through either the first or second resistive means, and thus it is possible to obtain the electrochemical apparatus which maintains a constant quality in large scale manufacturing.

Inventors

  • 👤 Hitoshi Nishizawa
  • 👤 Kazuyoshi Shibata

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 16:11
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/26; G01N27/416; G01N27/417; G01N27/403; G01N27/406; G01N27/4065; G01N27/407; Y; Y10; Y10T; Y10T29/00; Y10T29/49; Y10T29/49002

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 173 words
An electrochemical apparatus utilizing an electrochemical cell having a solid-electrolyte and at least one pair of porous electrodes arranged in contact with said solid-electrolyte, wherein one of said pair of electrodes is exposed through a diffusion means having a diffusion resistance to a gas to be measured to a space in which the gas to be measured is present, and an atmosphere near said one of the electrode is controlled by an electrode reaction due to a current flowing through said one pair of electrodes, comprising: a first branch conductor and a second branch conductor formed by dividing one of conductors respectively connected to said electrodes and arranged connectably to an external power source; at least one first resistive means formed in said first branch conductor, a resistive value of which can be arbitrarily adjusted; and at least one second resistive means formed in said second branch conductor; whereby a predetermined current corresponding to a predetermined concentration of the gas to be measured flows through one of said first or second resistive means.
Claim 2
Dependent Claim 173 words
An electrochemical apparatus utilizing an electrochemical cell having a solid-electrolyte and at least one pair of porous electrodes arranged in contact with said solid-electrolyte, wherein one of said pair of electrodes is exposed through a diffusion means having a diffusion resistance to a gas to be measured to a space in which the gas to be measured is present, and an atmosphere near said one of the electrode is controlled by an electrode reaction due to a current flowing through said one pair of electrodes, comprising: a first branch conductor and a second branch conductor formed by dividing one of conductors respectively connected to said electrodes and arranged connectably to an external power source; at least one first resistive means formed in said first branch conductor, a resistive value of which can be arbitrarily adjusted; and at least one second resistive means formed in said second branch conductor; whereby a predetermined current corresponding to a predetermined concentration of the gas to be measured flows through one of said first or second resistive means.
Claim 3
Dependent Claim 51 words
An electrochemical apparatus according to claim 1, further comprising a current measurement means for measuring the current flowing through one of said first resistive means and second resistive means, whereby an output of said current measurement means is used for a detection of gas concentration of the gas to be measured.
Claim 4
Dependent Claim 47 words
An electrochemical apparatus according to claim 1, further comprising a current measurement means connected in series to one of said first resistive means and second resistive means, whereby an output of said current measurement means is used for detecting gas concentration of the gas to be measured.
Claim 5
Dependent Claim 24 words
An electrochemical apparatus according to claim 1, wherein said first resistive means and said second resistive means are integrally formed on said solid electrolyte.
Claim 6
Dependent Claim 25 words
An electrochemical apparatus according to claim 1, wherein temperature coefficients of respective first resistive means and second resistive means are substantially equal to each other.
Claim 7
Dependent Claim 57 words
An electrochemical apparatus according to claim 1, further comprising a second solid-electrolyte and a second electrochemical cell having a pair of porous electrodes and arranged in contact with said second solid-electrolyte, such that one of said pair of electrodes is exposed through said diffusion means to a space in which the gas to be measured is present.
Claim 8
Independent Claim 193 words
A method of manufacturing an electrochemical apparatus utilizing an electrochemical cell having a solid-electrolyte and at least one pair of porous electrodes arranged in contact with said solid-electrolyte, wherein one of said pair of electrodes is exposed through a diffusion means having a diffusion resistance to a gas to be measured in a space in which the gas to be measured is existent, and an atmosphere near said one of the electrodes is controlled by an electrode reaction due to a current flowing through said one pair of electrodes, comprising the steps of: forming a first branch conductor and a second branch conductor by dividing one of conductors respectively connected to said electrodes; forming at least one first resistive means in said first branch conductor, a resistive value of which can be arbitrarily adjusted; forming at least one second resistive means in said second branch conductor; and adjusting the resistive value of said first resistive means to a predetermined value so as to obtain a predetermined output in response to a component concentration of the gas to be measured from a current through one of said first branch conductor and second branch conductor.
Claim 9
Independent Claim 193 words
A method of manufacturing an electrochemical apparatus utilizing an electrochemical cell having a solid-electrolyte and at least one pair of porous electrodes arranged in contact with said solid-electrolyte, wherein one of said pair of electrodes is exposed through a diffusion means having a diffusion resistance to a gas to be measured in a space in which the gas to be measured is existent, and an atmosphere near said one of the electrodes is controlled by an electrode reaction due to a current flowing through said one pair of electrodes, comprising the steps of: forming a first branch conductor and a second branch conductor by dividing one of conductors respectively connected to said electrodes; forming at least one first resistive means in said first branch conductor, a resistive value of which can be arbitrarily adjusted; forming at least one second resistive means in said second branch conductor; and adjusting the resistive value of said first resistive means to a predetermined value so as to obtain a predetermined output in response to a component concentration of the gas to be measured from a current through one of said first branch conductor and second branch conductor.
Claim 10
Dependent Claim 27 words
A method of manufacturing the electrochemical cell according to claim 7, wherein said first resistive means and said second resistive means are integrally formed on said solid-electrolyte.
Claim 11
Dependent Claim 29 words
A method of manufacturing the electrochemical cell according to claim 7, wherein temperature coefficients of respective first resistive means and second resistive means are substantially equal to each other.
Claim 12
Dependent Claim 187 words
An electrochemical apparatus including a connector portion for use in connection with an external power source and an electrochemical cell having a solid-electrolyte arranged in contact with said solid-electrolyte, wherein one of said pair of electrodes is exposed through a diffusion means having a diffusion resistnce with respect to a gas to be measured to a space in which the gas to be measured is existent, and an atmosphere near said one of the electrodes is controlled by an electrode reaction due to a current flowing through said one pair of electrodes, comprising: a first branch conductor and a second branch conductor formed by dividing one of conductors respectively connected to said electrodes and arranged connectably to the external power source through said connector portion; at least one first resistive means arranged between said electrochemical cell and said connector portion, a resistive value of which can be arbitrarily adjusted; and at least one second resistive means formed in said second branch conductor, whereby a predetermined current corresponding to a predetermined concentration of the gas to be measured flows through one of said first or second resistive means.
Claim 13
Dependent Claim 187 words
An electrochemical apparatus including a connector portion for use in connection with an external power source and an electrochemical cell having a solid-electrolyte arranged in contact with said solid-electrolyte, wherein one of said pair of electrodes is exposed through a diffusion means having a diffusion resistnce with respect to a gas to be measured to a space in which the gas to be measured is existent, and an atmosphere near said one of the electrodes is controlled by an electrode reaction due to a current flowing through said one pair of electrodes, comprising: a first branch conductor and a second branch conductor formed by dividing one of conductors respectively connected to said electrodes and arranged connectably to the external power source through said connector portion; at least one first resistive means arranged between said electrochemical cell and said connector portion, a resistive value of which can be arbitrarily adjusted; and at least one second resistive means formed in said second branch conductor, whereby a predetermined current corresponding to a predetermined concentration of the gas to be measured flows through one of said first or second resistive means.
Claim 14
Dependent Claim 28 words
An electrochemical apparatus according to claim 10, wherein both said first resistive means and said second resistive means are arranged between said electrochemical cell and said connector portion.
Claim 15
Dependent Claim 38 words
An electrochemical apparatus according to claim 10, wherein said a portion of the resistive means and the branch conductor arranged between said electrochemical cell and said connector portion are arranged in a protective cover of said electrochemical cell.
Claim 16
Dependent Claim 33 words
An electrochemical apparatus according to claim 10, wherein a portion of the resistive means and the branch conductor arranged between said electrochemical cell and said connector portion are arranged in said connector cell.
Claim 17
Dependent Claim 40 words
An electrochemical apparatus according to claim 10, wherein a portion of the resistive means and branch conductor arranged between said electrochemical cell and said connector portion are arranged in a connection line between said electrochemical cell and said connector portion.

References Cited (Backward Citations)

US3616274A Cited
US4272329A Cited
US4272330A Cited
EP0067326A2 Cited
EP0066851A2 Cited
US4505807A Cited
US4472247A Cited
EP0121905A1 Cited
EP0148622A2 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-01-05 1990-07-07 1991-01-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-01-05 1994-07-07 1995-01-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-01-05 1998-07-07 1999-01-06 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag