US4632960A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Resin composition comprising a thermosetting resin component and a functional, rubbery copolymer component
Assignee: JSR Corp
•
Filing: 1985-08-16
•
Granted: 1986-12-30
•
Expires: 2005-08-16
Abstract
Abstract A resin composition comprising 100 parts by weight of a thermosetting resin and 1 to 100 parts by weight of a functional, rubbery copolymer containing among the monomer units which constitute the copolymer, at least one monomer containing a substituent selected from the group consisting of epoxy, hydroxyl, carboxyl and amino groups, said copolymer being prepared by one of three emulsion polymerization processes in which a nonionic surface active agent and/or ionic surface active agent is employed as the emulsifying agent.
Inventors
- 👤 Hozumi Sato
- 👤 Tatsuaki Matsunaga
- 👤 Shin-ichiro Iwanaga
- 👤 Hiroji Enyo
- 👤 Yoshiaki Kawamura
- 👤 Yasuhiko Takemura
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 12:15
CPC Classifications
C; C08; C08L; C08L61/00; C08L61/04; C08L61/06; C08L61/20; C08L63/00
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
463 words
A resin composition comprising 100 parts by weight of a thermosetting resin selected from the group consisting of an epoxy resin, a phenol resin, a urea resin and a melamine resin and 1 to 100 parts by weight of a functional, rubbery copolymer of one of the following types: (I) a copolymer comprising monomer units of (i) from 1 to 20% by weight of least one monomer containing a substituent selected from the group consisting of epoxy, hydroxyl, carboxyl and amino groups, (ii) from 15 to 20% by weight of acrylonitrile and (iii) from 40 to 80% by weight of butadiene, isoprene or a mixture thereof; (II) a copolymer comprising monomer units of (i) from 1 to 20% by weight of at least one monomer containing a substituent selected from the group consisting of epoxy, hydroxyl, carboxyl and amino groups, (ii) from 40 to 99% by weight of an alkyl(meth)acrylate, an alkoxyalkyl(meth)acrylate or a mixture thereof and (iii) from 0 to 30% by weight of other monomers copolymerizable with the monomers (i) and (ii); (III) a copolymer comprising monomer units of (i) from 1 to 20% by weight of at least one monomer containing a substituent selected from the group consisting of epoxy, hydroxyl, carboxyl and amino groups, (ii) from 15 to 50% by weight of acrylonitrile, (iii) from 20 to 60% by weight of butadiene, isoprene or a mixture thereof and (iv) from 5 to 65% by weight of an alkyl(meth)acrylate, an alkoxyalkyl(meth)acrylate or a mixture thereof; said copolymer being produced by one of the following methods: (a) emulsion polymerizing the monomers which constitute said copolymer in the presence of an emulsifier consisting of 1 to 15 parts by weight of a nonionic surface active agent and 0 to 10 parts by weight of an ionic surface active agent per 100 parts by weight of the monomers, the weight ratio of the ionic surface active agent to the nonionic surface active agent being 0-2.0:1, recovering unreacted monomers, adding a metal-free electrolyte to the resulting polymer emulsion, heating the resulting mixture to precipitate a copolymer and then drying the copolymer; (b) emulsion polymerizing the monomers which constitute said copolymer in the presence of an ionic surface active agent as an emulsifier, recovering unreacted monomers, adding to the resulting polymer emulsion a metal-free electrolyte and a nonionic surface active agent, heating the resulting mixture to precipitate a copolymer, and then drying the polymer; (c) emulsion polymerizing the monomers which constitute said copolymer in the presence of a nonionic surface active agent as an emulsifier at a temperature lower than the cloud point of the nonionic surface active agent and then heating the resulting polymer latex to a temperature not lower than said cloud point to coagulate the latex without the addition of a coagulent.
Claim 2
Dependent Claim
463 words
A resin composition comprising 100 parts by weight of a thermosetting resin selected from the group consisting of an epoxy resin, a phenol resin, a urea resin and a melamine resin and 1 to 100 parts by weight of a functional, rubbery copolymer of one of the following types: (I) a copolymer comprising monomer units of (i) from 1 to 20% by weight of least one monomer containing a substituent selected from the group consisting of epoxy, hydroxyl, carboxyl and amino groups, (ii) from 15 to 20% by weight of acrylonitrile and (iii) from 40 to 80% by weight of butadiene, isoprene or a mixture thereof; (II) a copolymer comprising monomer units of (i) from 1 to 20% by weight of at least one monomer containing a substituent selected from the group consisting of epoxy, hydroxyl, carboxyl and amino groups, (ii) from 40 to 99% by weight of an alkyl(meth)acrylate, an alkoxyalkyl(meth)acrylate or a mixture thereof and (iii) from 0 to 30% by weight of other monomers copolymerizable with the monomers (i) and (ii); (III) a copolymer comprising monomer units of (i) from 1 to 20% by weight of at least one monomer containing a substituent selected from the group consisting of epoxy, hydroxyl, carboxyl and amino groups, (ii) from 15 to 50% by weight of acrylonitrile, (iii) from 20 to 60% by weight of butadiene, isoprene or a mixture thereof and (iv) from 5 to 65% by weight of an alkyl(meth)acrylate, an alkoxyalkyl(meth)acrylate or a mixture thereof; said copolymer being produced by one of the following methods: (a) emulsion polymerizing the monomers which constitute said copolymer in the presence of an emulsifier consisting of 1 to 15 parts by weight of a nonionic surface active agent and 0 to 10 parts by weight of an ionic surface active agent per 100 parts by weight of the monomers, the weight ratio of the ionic surface active agent to the nonionic surface active agent being 0-2.0:1, recovering unreacted monomers, adding a metal-free electrolyte to the resulting polymer emulsion, heating the resulting mixture to precipitate a copolymer and then drying the copolymer; (b) emulsion polymerizing the monomers which constitute said copolymer in the presence of an ionic surface active agent as an emulsifier, recovering unreacted monomers, adding to the resulting polymer emulsion a metal-free electrolyte and a nonionic surface active agent, heating the resulting mixture to precipitate a copolymer, and then drying the polymer; (c) emulsion polymerizing the monomers which constitute said copolymer in the presence of a nonionic surface active agent as an emulsifier at a temperature lower than the cloud point of the nonionic surface active agent and then heating the resulting polymer latex to a temperature not lower than said cloud point to coagulate the latex without the addition of a coagulent.
Claim 3
Dependent Claim
15 words
A resin composition according to claim 1, wherein the thermosetting resin is a phenol resin.
Claim 4
Dependent Claim
69 words
A resin composition according to claim 2, wherein the functional, rubbery copolymer is produced by subjecting the constituent monomers to emulsion polymerization using a nonionic surface active agent as an emulsifier at a temperature lower than the cloud point of the nonionic surface active agent and then heating the resulting polymer latex to a temperature not lower than said cloud point to coagulate a polymer without using any coagulant.
Claim 5
Dependent Claim
26 words
The resin composition of claim 1, wherein, in said method (a) for preparing said copolymer, said process further comprising washing the precipitated copolymer obtained with water.
Claim 6
Dependent Claim
26 words
The resin composition of claim 1, wherein, in said method (b) for preparing said copolymer, said process further comprising washing the precipitated copolymer obtained with water.
Claim 7
Dependent Claim
14 words
The resin composition of claim 1, wherein said thermosetting resin is an epoxy resin.
Claim 8
Dependent Claim
22 words
The resin composition of claim 1, wherein said carboxyl group containing monomer is acrylic acid, methacrylic acid, maleic acid or fumaric acid.
Claim 9
Dependent Claim
21 words
The resin composition of claim 1, wherein said epoxy group containing monomer is glycidyl(meth)acrylate, allyl glycidyl ether or vinyl glycidyl ether.
Claim 10
Dependent Claim
17 words
The resin composition of claim 1, wherein said hydroxyl group containing monomer is 1-hydroxypropyl(meth)acrylate, 2-hydroxypropyl(meth)acrylate, or hydroxyethyl(meth)acrylate.
Claim 11
Dependent Claim
17 words
The resin composition of claim 1, wherein said amino group containing monomer is dimethylaminoethyl(meth)acrylate, diethylaminoethyl(meth)acrylate, or dibutylaminoethyl(meth)acrylate.
Claim 12
Dependent Claim
19 words
The resin composition of claim 1, wherein said alkyl(meth)acrylate is ethylacrylate, ethylmethacrylate, propylacrylate, butylacrylate, butylmethacrylate, hexylacrylate, 2-ethylhexylacrylate or octylacrylate.
Claim 13
Dependent Claim
18 words
The resin composition of claim 1, wherein said alkoxyalkyl(meth)acrylate is ethoxyethylacrylate, methoxyethylacrylate, propoxyethylacrylate, methoxyethylmethacrylate, ethoxyethylmethacrylate, butoxyethylacrylate or butoxyethylmethacrylate.
Claim 14
Dependent Claim
37 words
The resin composition of claim 1, wherein said nonionic surface active agent is polyoxyethylene alkyl ether, polyoxyethylene alkylaryl ether, polyoxyethylene fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene-oxypropylene block polymer, alkylsulfinyl alcohol or fatty acid monoglyceride.
Claim 15
Dependent Claim
37 words
The resin composition of claim 1, wherein said nonionic surface active agent is present in the emulsion polymerization medium in an amount of from 1 to 15 parts by weight per 100 parts by weight of monomer.
Claim 16
Dependent Claim
29 words
The resin composition of claim 1, wherein said ionic surface active agent is an anionic surface active agent, a cationic surface active agent or an amphoteric surface active agent.
Claim 17
Dependent Claim
39 words
The resin composition of claim 1, wherein, in the emulsified polymerization medium, said ionic surface active agent is present in an amount of from 0 to 10 parts by weight per 100 parts by weight of the monomer ingredients.
Claim 18
Dependent Claim
29 words
The resin composition of claim 1, wherein from 1 to 50 parts by weight of said rubbery copolymer is combined with 100 parts by weight of said thermosetting resin.
Claim 19
Dependent Claim
383 words
A resin composition comprising 100 parts by weight of a thermosetting epoxy resin and 1 to 100 parts by weight of a functional, rubbery copolymer of one of the following types: (I) a copolymer comprising monomer units of (i) from 1 to 20% by weight of at least one monomer containing a substituent selected from the group consisting of epoxy, hydroxyl, carboxyl and amino groups, (ii) 15 to 50% by weight of acrylonitrile and (iii) from 40 to 80% by weight of butadiene, isoprene or a mixture thereof; (II) a copolymer comprising monomer units of (i) from 1 to 20% by weight of at least one monomer containing a substituent selected from the group consisting of epoxy, hydroxyl, carboxyl and amino groups, (ii) from 40 to 99% by weight of an alkyl(meth)acrylate, an alkoxyalkyl(meth)acrylate or a mixture thereof and (iii) from 0 to 30% by weight of other monomers copolymerizable with the monomers (I) and (ii); (III) a copolymer comprising monomer units of (i) from 1 to 20% by weight of at least one monomer containing a substituent selected from the group consisting of epoxy, hydroxyl, carboxyl and amino groups, (ii) from 15 to 50% by weight of acrylonitrile, (iii) from 20 to 60% by weight of butadiene, isoprene or a mixture thereof and (iv) 5 to 65% by weight of an alkyl(meth)acrylate, an alkoxyalkyl(meth)acrylate or a mixture thereof; said copolymer being produced by one of the following methods: (a) emulsion polymerizing the monomers which constitute said copolymer in the presence of an emulsifier consisting of 1 to 15 parts by weight of a nonionic surface active agent and 0 to 10 parts by weight of an ionic surface active agent per 100 parts by weight of the monomers, the weight ratio of the ionic surface active agent to the nonionic surface active agent being 0-2.0:1, recovering unreacted monomers, adding a metal-free electrolyte to the resulting polymer emulsion, heating the resulting mixture to precipitate a copolymer, and then drying the copolymer; (b) emulsion polymerizing the monomers which constitute said copolymer in the presence of an ionic surface active agent as an emulsifier, recovering unreacted monomers, adding to the resulting polymer emulsion a metal-free electrolyte and a nonionic surface active agent, heating the resulting mixture to precipitate a copolymer and then drying the copolymer.
Claim 20
Dependent Claim
383 words
A resin composition comprising 100 parts by weight of a thermosetting epoxy resin and 1 to 100 parts by weight of a functional, rubbery copolymer of one of the following types: (I) a copolymer comprising monomer units of (i) from 1 to 20% by weight of at least one monomer containing a substituent selected from the group consisting of epoxy, hydroxyl, carboxyl and amino groups, (ii) 15 to 50% by weight of acrylonitrile and (iii) from 40 to 80% by weight of butadiene, isoprene or a mixture thereof; (II) a copolymer comprising monomer units of (i) from 1 to 20% by weight of at least one monomer containing a substituent selected from the group consisting of epoxy, hydroxyl, carboxyl and amino groups, (ii) from 40 to 99% by weight of an alkyl(meth)acrylate, an alkoxyalkyl(meth)acrylate or a mixture thereof and (iii) from 0 to 30% by weight of other monomers copolymerizable with the monomers (I) and (ii); (III) a copolymer comprising monomer units of (i) from 1 to 20% by weight of at least one monomer containing a substituent selected from the group consisting of epoxy, hydroxyl, carboxyl and amino groups, (ii) from 15 to 50% by weight of acrylonitrile, (iii) from 20 to 60% by weight of butadiene, isoprene or a mixture thereof and (iv) 5 to 65% by weight of an alkyl(meth)acrylate, an alkoxyalkyl(meth)acrylate or a mixture thereof; said copolymer being produced by one of the following methods: (a) emulsion polymerizing the monomers which constitute said copolymer in the presence of an emulsifier consisting of 1 to 15 parts by weight of a nonionic surface active agent and 0 to 10 parts by weight of an ionic surface active agent per 100 parts by weight of the monomers, the weight ratio of the ionic surface active agent to the nonionic surface active agent being 0-2.0:1, recovering unreacted monomers, adding a metal-free electrolyte to the resulting polymer emulsion, heating the resulting mixture to precipitate a copolymer, and then drying the copolymer; (b) emulsion polymerizing the monomers which constitute said copolymer in the presence of an ionic surface active agent as an emulsifier, recovering unreacted monomers, adding to the resulting polymer emulsion a metal-free electrolyte and a nonionic surface active agent, heating the resulting mixture to precipitate a copolymer and then drying the copolymer.
Claim 21
Dependent Claim
26 words
The resin composition of claim 18, wherein, in said method (a) for preparing said copolymer, said process further comprising washing the precipitated copolymer obtained with water.
Claim 22
Dependent Claim
26 words
The resin composition of claim 19 wherein, in said method (b) for preparing said copolymer, said process further comprising washing the precipitated copolymer obtained with water.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-12-29 | 1990-06-30 | 1990-12-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-12-29 | 1994-06-30 | 1994-12-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-12-29 | 1998-06-30 | 1998-12-30 | $7700.00 | Window Closed / Lapsed |