US4631119A
Expired / Lapsed
US
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Reversible, electrochemically-switched lariat ethers
Assignee: Washington University in St. Louis
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Filing: 1985-05-22
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Granted: 1986-12-23
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Expires: 2005-05-22
Abstract
Abstract This invention relates to novel heteromacrocyclic compounds which have electrochemically reducible sidearms containing uncharged Lewis basic donor groups appropriately placed to interact with a macroring-bound cation and an electrochemical switching process utilizing same. Reduction of the sidearm's aromatic residue produces a radical anion species. The resulting ligand binds a cation more strongly than does the neutral species. These compounds are therefore of utility as electrochemically controlled cation binders.
Inventors
- 👤 George W. Gokel
- 👤 Luis Echegoyen
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 05:17
CPC Classifications
C; C07; C07D; C07D273/00; C07D323/00
Claims Analysis
Total Claims: 2
Claim 1
Independent Claim
153 words
The electrochemical process of forming a radical anion of a heteromacrocyclic ring compound composed of a substituted heteromacrocyclic ring containing 12-36 contiguous atoms selected from the group C, N, O or S, said N, O or S being separated by at least two carbon atoms, one or more of said ring C or N atoms having attached thereto a substituted or unsubstituted sidearm consisting of C, N, O of S, said sidearm having attached thereto at the other terminus thereof a substituted carbocyclic aromatic or substituted or unsubstituted heteroaromatic residue containing at least one uncharged Lewis basic donor group, the reduction potential of said residue being less than 2.0 V vs. SCE, said sidearm being of sufficient length and flexibility, such that the donor group on or part of the residue will position itself over the macroring cavity to interact with any ring bound cation which is present, which comprises electron transfer thereto.
Claim 2
Dependent Claim
153 words
The electrochemical process of forming a radical anion of a heteromacrocyclic ring compound composed of a substituted heteromacrocyclic ring containing 12-36 contiguous atoms selected from the group C, N, O or S, said N, O or S being separated by at least two carbon atoms, one or more of said ring C or N atoms having attached thereto a substituted or unsubstituted sidearm consisting of C, N, O of S, said sidearm having attached thereto at the other terminus thereof a substituted carbocyclic aromatic or substituted or unsubstituted heteroaromatic residue containing at least one uncharged Lewis basic donor group, the reduction potential of said residue being less than 2.0 V vs. SCE, said sidearm being of sufficient length and flexibility, such that the donor group on or part of the residue will position itself over the macroring cavity to interact with any ring bound cation which is present, which comprises electron transfer thereto.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-12-22 | 1990-06-23 | 1990-12-23 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-12-22 | 1994-06-23 | 1994-12-23 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-12-22 | 1998-06-23 | 1998-12-23 | $7700.00 | Window Closed / Lapsed |