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US4629000A Expired / Lapsed US ⏱️ 0.0 years remaining

Oil recovery by surfactant-alcohol waterflooding

Assignee: Mobil Oil AS
•
Filing: 1986-05-13
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Granted: 1986-12-16
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Expires: 2006-05-13
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Abstract

Abstract Waterflooding process for the recovery of oil from a subterranean formation in which at least a portion of the injected fluid consists of an oil slug containing a preferentially oil-soluble alcohol and a preferentially oil-soluble ether-linked sulfate or sulfonate. Specifically disclosed ether-linked surfactants include sulfonated or sulfated polyethoxylated alkylphenols. Specifically disclosed alcohols include aliphatic alcohols containing from 5 to 7 carbon atoms and having a water solubility of less than 3 percent.

Inventors

  • 👤 Billy G. Hurd

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 11:38
CPC Classifications
C; C09; C09K; C09K8/00; C09K8/58; C09K8/584; Y; Y10; Y10S; Y10S507/00; Y10S507/935; Y10S507/936

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 176 words
In a method for the recovery of oil from a subterranean oil reservoir penetrated by spaced injection and production systems in which an aqueous fluid is introduced into said reservoir via said injection system to displace oil to said production system, the improvement comprising preceding the aqueous fluid introduction with an oil slug consisting of oil, a preferentially oil-soluble alcohol of limited water solubility having from 5 to 7 carbon atoms and a preferentially oil-soluble anionic surfactant is within the range of 0.2-1.0, said surfactant characterized by one of the formulae ##STR3## wherein the R 1 groups are the same or different and are straight or branched-chain aliphatic groups containing from 8 to 12 carbon atoms, n is 2 or 3, q is at least 2, x is a number within the range of 1 to 20, Ar is phenyl or naphthyl, R 2 is a C 1 to C 4 alkyl group, R 3 is a hydrogen, a hydroxy group or a methyl group, and M is an alkali metal, ammonium, or substituted ammonium ion.
Claim 2
Dependent Claim 176 words
In a method for the recovery of oil from a subterranean oil reservoir penetrated by spaced injection and production systems in which an aqueous fluid is introduced into said reservoir via said injection system to displace oil to said production system, the improvement comprising preceding the aqueous fluid introduction with an oil slug consisting of oil, a preferentially oil-soluble alcohol of limited water solubility having from 5 to 7 carbon atoms and a preferentially oil-soluble anionic surfactant is within the range of 0.2-1.0, said surfactant characterized by one of the formulae ##STR3## wherein the R 1 groups are the same or different and are straight or branched-chain aliphatic groups containing from 8 to 12 carbon atoms, n is 2 or 3, q is at least 2, x is a number within the range of 1 to 20, Ar is phenyl or naphthyl, R 2 is a C 1 to C 4 alkyl group, R 3 is a hydrogen, a hydroxy group or a methyl group, and M is an alkali metal, ammonium, or substituted ammonium ion.
Claim 3
Dependent Claim 24 words
The method of claim 1 wherein said alcohol has a water solubility at the temperature of said reservoir of less than 3.0 weight percent.
Claim 4
Dependent Claim 10 words
The method of claim 1 wherein said alcohol is pentanol.
Claim 5
Dependent Claim 10 words
The method of claim 1 wherein said alcohol is hexanol.
Claim 6
Dependent Claim 21 words
The method of claim 1 wherein n is 2 and x is a number within the range of 3 to 10.
Claim 7
Dependent Claim 15 words
The method of claim 1 wherein the said oil-soluble anionic surfactant has the formula ##STR4##
Claim 8
Dependent Claim 10 words
The method of claim 6 wherein the alcohol is pentanol.
Claim 9
Dependent Claim 10 words
the method of claim 6 wherein the alcohol is hexanol.

References Cited (Backward Citations)

US3493048A Cited
US3508611A Cited
US3508612A Cited
US3477511A Cited
US3827497A Cited
US4017405A Cited
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US4110229A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-12-15 1990-06-16 1990-12-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-12-15 1994-06-16 1994-12-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-12-15 1998-06-16 1998-12-16 $7700.00 Window Closed / Lapsed

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