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US4624989A Expired / Lapsed US ⏱️ 0.0 years remaining

Thermoplastic elastomers containing cross-linked epihalohydrin rubbers

Assignee: Hercules LLC
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Filing: 1986-01-31
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Granted: 1986-11-25
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Expires: 2006-01-31
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Abstract

Abstract Disclosed is a thermoplastic elastomer containing a cross-linked polyepihalohydrin rubber made by simultaneously cross-linking the rubber and blending the rubber with a crystalline polyolefin in the presence of a chlorinated hydrocarbon having a chlorine content of about 20% to about 70% by weight.

Inventors

  • 👤 Dominic A. Berta

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 08:55
CPC Classifications
C; C08; C08L; C08L15/00; C08L15/02; C08L23/00; C08L23/02; C08K; C08K3/00; C08K3/18; C08K3/20; C08K3/22; C08K5/00; C08K5/0008; C08K5/0025; C08K5/04; C08K5/09; C08L23/10; C08L23/14; C08L23/26; C08L23/28; C08L23/286; C08L61/00; C08L61/20; C08L71/00; C08L71/02; C08L71/03; C08L2312/00

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 69 words
A composition comprising a substantially homogenous blend of a cross-linked polyepihalohydrin rubber, a crystalline polyolefin that is a polymerized mixture of one or more olefins selected from the group consisting of ethylene, propylene, 1-butene, 1-pentene, 1-hexene, 2-methyl-1-propene, 3-methyl-1-pentene, 4-methyl-1-pentene, and 5-methyl-1-hexene, and a chlorinated hydrocarbon having a chlorine content of about 20% to about 70% by weight, wherein said hydrocarbon is a chlorinated paraffin, chlorinated polyethylene, or chlorinated polyisoprene.
Claim 2
Dependent Claim 69 words
A composition comprising a substantially homogenous blend of a cross-linked polyepihalohydrin rubber, a crystalline polyolefin that is a polymerized mixture of one or more olefins selected from the group consisting of ethylene, propylene, 1-butene, 1-pentene, 1-hexene, 2-methyl-1-propene, 3-methyl-1-pentene, 4-methyl-1-pentene, and 5-methyl-1-hexene, and a chlorinated hydrocarbon having a chlorine content of about 20% to about 70% by weight, wherein said hydrocarbon is a chlorinated paraffin, chlorinated polyethylene, or chlorinated polyisoprene.
Claim 3
Dependent Claim 13 words
The composition of claim 1 wherein the cross-linked polyepihalohydrin rubber is cross-linked polyepichlorohydrin.
Claim 4
Dependent Claim 19 words
The composition of claim 1, wherein the cross-linked polyepihalohydrin rubber is a cross-linked copolymer of epichlorohydrin and ethylene oxide.
Claim 5
Dependent Claim 21 words
The composition of claim 1, wherein the cross-linked polyepihalohydrin rubber is a cross-linked terpolymer of epichlorohydrin, ethylene oxide, and allylglycidyl ether.
Claim 6
Dependent Claim 15 words
The composition of claim 1, wherein the polyolefin is a copolymer of propylene and 1-butene.
Claim 7
Dependent Claim 10 words
The composition of claim 1, wherein the polyolefin is polypropylene.
Claim 8
Dependent Claim 10 words
The composition of claim 1, wherein the polyolefin is polyethylene.
Claim 9
Dependent Claim 12 words
The composition of claim 1, wherein the chlorinated hydrocarbon is chlorinated polyethylene.
Claim 10
Dependent Claim 21 words
The composition of claim 1, wherein the chlorinated hydrocarbon has a chlorine content from about 25% to about 42% by weight.
Claim 11
Independent Claim 118 words
A method making a thermoplastic elastomer comprising the steps of (a) blending a polyepihalohydrin rubber and a crystalline polyolefin that is a polymerized mixture of one or more olefins selected from the group consisting of ethylene, propylene, 1-butene, 1-pentene, 1-hexene, 2-methyl-1-propene, 3-methyl-1-pentene, 4-methyl-1-pentene, and 5-methyl-1-hexene in the presence of a chlorinated hydrocarbon having a chlorine content of about 20% to about 70% by weight, wherein said hydrocarbon is a chlorinated paraffin, chlorinated polyethylene, or chlorinated polyisoprene, and (b) simultaneously cross-linking the polyepihalohydrin rubber by heating the blend in the presence of a curing system that cross-links the polyepihalohydrin rubber in preference to the polyolefin and the hydrocarbon and comprises a cross-linking agent and at least one curing accelerator.
Claim 12
Independent Claim 118 words
A method making a thermoplastic elastomer comprising the steps of (a) blending a polyepihalohydrin rubber and a crystalline polyolefin that is a polymerized mixture of one or more olefins selected from the group consisting of ethylene, propylene, 1-butene, 1-pentene, 1-hexene, 2-methyl-1-propene, 3-methyl-1-pentene, 4-methyl-1-pentene, and 5-methyl-1-hexene in the presence of a chlorinated hydrocarbon having a chlorine content of about 20% to about 70% by weight, wherein said hydrocarbon is a chlorinated paraffin, chlorinated polyethylene, or chlorinated polyisoprene, and (b) simultaneously cross-linking the polyepihalohydrin rubber by heating the blend in the presence of a curing system that cross-links the polyepihalohydrin rubber in preference to the polyolefin and the hydrocarbon and comprises a cross-linking agent and at least one curing accelerator.
Claim 13
Dependent Claim 87 words
A cross-linkable composition comprising a polyepihalohydrin rubber, a crystalline polyolefin that is a polymerized mixture of one or more olefins selected from the group consisting of ethylene, propylene, 1-butene, 1-pentene, 1-hexene, 2-methyl-1-propene, 3-methyl-1-pentene, 4-methyl-1-pentene, and 5-methyl-1-hexene, a chlorinated hydrocarbon having a chlorine content of about 20% to about 70% by weight, wherein said hydrocarbon is a chlorinated paraffin, chlorinated polyethylene, or chlorinated polyisoprene, and a curing system that cross-links the rubber in preference to the hydrocarbon and comprises a cross-linking agent and at least one curing accelerator.
Claim 14
Dependent Claim 87 words
A cross-linkable composition comprising a polyepihalohydrin rubber, a crystalline polyolefin that is a polymerized mixture of one or more olefins selected from the group consisting of ethylene, propylene, 1-butene, 1-pentene, 1-hexene, 2-methyl-1-propene, 3-methyl-1-pentene, 4-methyl-1-pentene, and 5-methyl-1-hexene, a chlorinated hydrocarbon having a chlorine content of about 20% to about 70% by weight, wherein said hydrocarbon is a chlorinated paraffin, chlorinated polyethylene, or chlorinated polyisoprene, and a curing system that cross-links the rubber in preference to the hydrocarbon and comprises a cross-linking agent and at least one curing accelerator.

References Cited (Backward Citations)

US4032479A Cited
US4251648A Cited
US4251648B1 Cited
US4408013A Cited
US4463136A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-11-24 1990-05-26 1990-11-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-11-24 1994-05-26 1994-11-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-11-24 1998-05-26 1998-11-25 $7700.00 Window Closed / Lapsed

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