US4623567A
Expired / Lapsed
US
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Compositions of ethylene polymers for the manufacture of films
Assignee: Norsolor SA
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Filing: 1983-06-03
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Granted: 1986-11-18
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Expires: 2003-06-03
Abstract
Abstract A composition comprising from 25 to 95 weight percent of at least one free-radical ethylene polymer and from 5 to 75 weight percent of at least one ethylene α-olefin copolymer, wherein the α-olefin contains at least 4 carbon atoms, wherein the copolymer has a specific gravity between 0.905 and 0.940 and a melt index between 0.4 and 3 dg/min, and wherein the free-radical ethylene polymer has a melt index between 0.15 and 3 dg/min. Application to the manufacture of films having a thickness between 8 and 200 microns and other applications.
Inventors
- 👤 Marius Hert
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 22:05
CPC Classifications
C; C08; C08L; C08L23/00; C08L23/02; C08L23/04; C08L23/08; C08L23/06; C08L23/0807; C08L23/0815; Y; Y10; Y10T; Y10T428/00; Y10T428/13; Y10T428/1352; Y10T428/139; Y10T428/29; Y10T428/2913
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
205 words
A composition comprising (a) from 25 to 95 weight percent of at least one free-radical ethylene polymer having a melt index between 0.15 and 2 dg/min, the free radical ethylene polymer being obtained by polymerization under high pressure and high temperature conditions and (b) from 5 to 75 weight percent of at least one ethylene α-olefin copolymer, wherein said α-olefin contains at least 4 carbon atoms, wherein said copolymer has a specific gravity between 0.905 and 0.940 and an average proportion of α-olefin units between 1 and 8 mole percent, said copolymer comprising both crystalline fractions and amorphous fractions and having a melt index between 0.4 and 3 dg/min, wherein said crystalline fractions of said copolymer have a single melting peak between 118° and 130° C. and represent from 20 to 50 weight percent of the total copolymer, the copolymer having a polydispersity index of between about 3 and about 9 for binary polymers and between about 4 and about 12 for ternary polymers; wherein the distribution of α-olefin units in the copolymer is heterogeneous, and wherein the proportion of α-olefin units in the copolymer varies between at least 0.2 and at most 5 times the average proportion of α-olefin units in the various fractions.
Claim 2
Dependent Claim
205 words
A composition comprising (a) from 25 to 95 weight percent of at least one free-radical ethylene polymer having a melt index between 0.15 and 2 dg/min, the free radical ethylene polymer being obtained by polymerization under high pressure and high temperature conditions and (b) from 5 to 75 weight percent of at least one ethylene α-olefin copolymer, wherein said α-olefin contains at least 4 carbon atoms, wherein said copolymer has a specific gravity between 0.905 and 0.940 and an average proportion of α-olefin units between 1 and 8 mole percent, said copolymer comprising both crystalline fractions and amorphous fractions and having a melt index between 0.4 and 3 dg/min, wherein said crystalline fractions of said copolymer have a single melting peak between 118° and 130° C. and represent from 20 to 50 weight percent of the total copolymer, the copolymer having a polydispersity index of between about 3 and about 9 for binary polymers and between about 4 and about 12 for ternary polymers; wherein the distribution of α-olefin units in the copolymer is heterogeneous, and wherein the proportion of α-olefin units in the copolymer varies between at least 0.2 and at most 5 times the average proportion of α-olefin units in the various fractions.
Claim 3
Dependent Claim
17 words
The composition of claim 1, wherein said ethylene/α-olefin copolymer has a molecular weight between 15,000 and 60,000.
Claim 4
Dependent Claim
22 words
The composition of claim 1, wherein said copolymer contains two α-olefins, in a ratio of respective average proportions between 0.25 and 4.
Claim 5
Dependent Claim
20 words
The composition of claim 1, wherein said α-olefins are selected from the group consisting of but-1-ene, hex-1-ene, 4-methylpent-1-ene, and oct-1-ene.
Claim 6
Dependent Claim
24 words
The composition of claim 1, wherein the total unsaturation ratio of said copolymer is between 0.25 and 0.50 double bonds per 1000 carbon atoms.
Claim 7
Dependent Claim
24 words
The composition of claim 4, wherein the total unsaturation ratio of said copolymer is between 0.32 and 0.45 double bonds per 1000 carbon atoms.
Claim 8
Dependent Claim
19 words
The composition of claim 1, wherein said free-radical ethylene polymer has a melt index between 0.15 and 0.45 dg/min.
Claim 9
Dependent Claim
27 words
The composition of claim 1, further comprising up to 15 weight percent high density polyethylene, with respect to the sum of free-radical ethylene polymer and ethylene/α-olefin copolymer.
Claim 10
Dependent Claim
45 words
The composition of claim 7, further comprising up to 10 weight percent, with respect to the sum of free-radical ethylene polymer and ethylene/α-olefin copolymer, of an ethylene/vinylacetate copolymer with a melt index between 3 and 20 dg/min and comprising 20 to 40 weight percent vinylacetate.
Claim 11
Dependent Claim
20 words
A film having a thickness of between about 8 and 200 μm and made from the composition of claim 1.
Claim 12
Dependent Claim
21 words
A retractable housing having a thickness of between about 25 and 150 μm and made from the composition of claim 1.
Claim 13
Dependent Claim
13 words
A tube for sheathing telecommunication cables made from the composition of claim 1.
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1989-11-17 | 1990-05-19 | 1990-11-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-11-17 | 1994-05-19 | 1994-11-18 | $3760.00 | Window Closed / Lapsed |
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