Patent US4630597A successfully refreshed from Google Patents.
US4622173A
Expired / Lapsed
US
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Non-aqueous liquid laundry detergents containing three surfactants including a polycarboxylic acid ester of a non-ionic
Assignee: Colgate Palmolive Co
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Filing: 1984-12-31
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Granted: 1986-11-11
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Expires: 2004-12-31
Abstract
Abstract A mixture of an acid terminated non-ionic surfactant and a quaternary ammonium salt surfactant provide better detergency than equivalent amounts of either of the surfactant compounds alone. The surfactant mixture is preferably used in conjunction with liquid non-ionic surfactant in heavy duty non-aqueous laundry detergents but can also be used in aqueous liquid detergent compositions and powder detergent compositions.
Inventors
- 👤 Guy Broze
- 👤 Danielle Bastin
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 04:26
CPC Classifications
C; C11; C11D; C11D1/00; C11D1/86; C11D1/38; C11D1/65; C11D17/00; C11D17/0004; C11D1/02; C11D1/04; C11D1/06; C11D1/62; C11D1/66; C11D1/72
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
249 words
A substantially non-aqueous liquid detergent composition comprising a surfactant mixture of from about 40% to about 90% by weight of (a) a liquid nonionic surfactant, and from about 10% to about 60% by weight of a complex of (B) an acid-modified nonionic surfactant which is an esterification reaction product between a nonionic surfactant which is a poly(C2 to C3 alkoxylated) fatty alcohol having a terminal hydroxyl group with a polycarboxylic acid or polycarboxylic acid anhydride, and (C) an ethoxylated or propoxylated quaternary ammonium salt surfactant having the formula (I) ##STR8## wherein R 1 is an organic group containing a straight or branched alkyl or alkenyl group optionally substituted with up to 3 phenyl or hydroxy groups, and optionally interrupted by up to 4 structures selected from the group consisting of ##STR9## and mixtures thereof, where R 4 is an alkyl or hydroxyalkyl group containing 1 to 4 carbon atoms, or a benzyl group, and which contains from about 8 to 22 carbon atoms, and which may additionally contain up to 12 ethylene oxide groups, R 2 is the group R 1 or an alkyl or hydroxyalkyl group containing 1 to 6 carbon atoms, or a benzyl group; R 3 is the group R 2 or (CH 2 CHZO) q H; Z is hydrogen or methyl, and q and p are, independently, numbers from 1 to 12; and X is a water-soluble anion, said complex comprising a molar ratio of (B)/(C) in the range of from about 3:1 to 1:3.
Claim 2
Dependent Claim
249 words
A substantially non-aqueous liquid detergent composition comprising a surfactant mixture of from about 40% to about 90% by weight of (a) a liquid nonionic surfactant, and from about 10% to about 60% by weight of a complex of (B) an acid-modified nonionic surfactant which is an esterification reaction product between a nonionic surfactant which is a poly(C2 to C3 alkoxylated) fatty alcohol having a terminal hydroxyl group with a polycarboxylic acid or polycarboxylic acid anhydride, and (C) an ethoxylated or propoxylated quaternary ammonium salt surfactant having the formula (I) ##STR8## wherein R 1 is an organic group containing a straight or branched alkyl or alkenyl group optionally substituted with up to 3 phenyl or hydroxy groups, and optionally interrupted by up to 4 structures selected from the group consisting of ##STR9## and mixtures thereof, where R 4 is an alkyl or hydroxyalkyl group containing 1 to 4 carbon atoms, or a benzyl group, and which contains from about 8 to 22 carbon atoms, and which may additionally contain up to 12 ethylene oxide groups, R 2 is the group R 1 or an alkyl or hydroxyalkyl group containing 1 to 6 carbon atoms, or a benzyl group; R 3 is the group R 2 or (CH 2 CHZO) q H; Z is hydrogen or methyl, and q and p are, independently, numbers from 1 to 12; and X is a water-soluble anion, said complex comprising a molar ratio of (B)/(C) in the range of from about 3:1 to 1:3.
Claim 3
Dependent Claim
21 words
The composition of claim 1 which further comprises at least one detergent builder salt suspended throughout said liquid non-ionic surfactant (A).
Claim 4
Dependent Claim
21 words
The composition of claim 1 which further comprises an inorganic detergent builder salt which is stably suspended in said surfactant mixture.
Claim 5
Dependent Claim
12 words
The composition of claim 3 wherein said builder salt comprises sodium tripolyphosphate.
Claim 6
Dependent Claim
21 words
The composition of claim 3 wherein the builder salt comprises from about 30% to about 75% by weight of the composition.
Claim 7
Dependent Claim
61 words
The composition of claim 5 which comprises from about 0.5 to 1 part by weight of (A), from about 0.12 to 5 parts by weight of (B) plus (C) at a molar ratio of (B) to (C) in the range of from about 1.5:1 to 1 1.5, and from about 0.8 to 3 parts by weight of inorganic detergent builder salt.
Claim 8
Dependent Claim
22 words
The compositions of claim 1 wherein (B) and (C) are present at a molar ratio of from about 1.5:1 to about 1:1.5.
Claim 9
Dependent Claim
49 words
The composition of claim 1 wherein the liquid non-ionic surfactant (A) comprises at least one compound selected from the group consisting of C 10 to C 18 fatty alcohols which include from 3 to 12 moles of C 2 to C 3 alkylene oxide per mole of fatty alcohol.
Claim 10
Dependent Claim
18 words
The composition of claim 1 wherein (B) and (C) are present at a molar ratio of about 1:1.
Claim 11
Dependent Claim
156 words
The composition of claim 1 wherein the nonionic surfactant (A) is a linear secondary C 13 fatty alcohol condensed with an average 8 moles ethylene oxide per mole of fatty alcohol, and in which no more than 10% by weight of the molecules are condensed with less than 7 or more than 9 moles of ethylene oxide and wherein the quaternary ammonium salt surfactant (C) comprises a compound of formula (I) wherein R 1 is an alkyl or alkenyl group having from about 10 to 20 carbon atoms which may be substituted by an hydroxyl group, and which may additionally contain up to 12 ethylene oxide groups; R 2 is the group R 1 or an alkyl or hydroxyalkyl group containing 1 to 4 carbon atoms, or a benzyl group; R 3 is the group R2 or (CH 2 CHZO; Z is a hydrogen atom; and P and q are, independently, numbers from 1 to 12.
Claim 12
Dependent Claim
16 words
The composition of claim 10 wherein R 3 has the same meaning as R 2 .
Claim 13
Dependent Claim
27 words
The composition of claim 10 wherein R 3 is the group (C 2 H 4 O) q H wherein q is a number from 1 to 12.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-11-10 | 1990-05-12 | 1990-11-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-11-10 | 1994-05-12 | 1994-11-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-11-10 | 1998-05-12 | 1998-11-11 | $7700.00 | Window Closed / Lapsed |