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US4622045A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of dyeing wool with acid dyestuffs

Assignee: Sandoz AG
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Filing: 1984-09-28
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Granted: 1986-11-11
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Expires: 2004-09-28
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Abstract

Abstract The invention provides a process for dyeing a textile substrate comprising wool fibres, which process comprises bringing the substrate into contact with an aqueous dyebath containing an acid dyestuff or a mixture of acid dyestuffs having (a) a build-up power on wool of from 90 to 98% at pH 4.5; together with (b) a migrating ability on wool of from 25 to 40%, at pH 4.5; (a) and (b) being determined under specific conditions, in the presence of a levelling agent which is the alkoxylation product of an amine substituted by a fatty saturated or unsaturated residue, the aqueous dyebath containing a mixture of acid dyestuffs when the substrate is a wool/synthetic polyamide fibre blend. These dyestuffs give level, fast and reproducible dyeings of a high quality.

Inventors

  • 👤 Josef Frauenknecht
  • 👤 Karl Zeller

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 04:01
CPC Classifications
D; D06; D06P; D06P3/00; D06P3/82; D06P3/8204; D06P3/8271; D06P3/02; D06P3/04; D06P3/14; D06P3/16; D06P3/8209; Y; Y10; Y10S; Y10S8/00; Y10S8/916; Y10S8/917

Claims Analysis

Total Claims: 26
Claim 1
Independent Claim 234 words
A process for dyeing a textile substrate comprising wool fibers, which process comprises bringing the substrate into contact with an aqueous dyebath containing a monosulfonated acid dyestuff or a mixture of monosulfonated acid dyestuffs, said dyestuff or mixture having (a) a build up power such that it exhausts onto wool to an extent of 90 to 98% in 60 minutes from a dyebath having a temperature of 98±1° C., a pH of 4.5, a goods: liquor ratio of 1:40 and a dyestuff concentration as required for a 2/1 standard dyeing depth, and (b) a migrating ability such that it is capable of migrating to an extent of 25 to 40% in 60 minutes from a wool sample dyed in a 1/1 standard dyeing depth to an initially undyed wool sample of equal weight in a bath having a temperature of 98±1° C., a pH of 4.5 and a goods:liquor ratio of 1:40, said 25 to 40% being the ratio after said 60 minutes, of the amount of dyestuff on the initially undyed sample to the amount of dyestuff remaining on the dyed sample, and a leveling agent which is an alkoxylation product of an amine substituted by a C 12-30 alkyl or alkenyl group or by a C 13-31 alkylcarbonyl or alkenylcarbonyl group, provided that when the substrate is a wool/synthetic polyamide fiber blend the aqueous dyebath contains a mixture of monosulfonated acid dyestuffs.
Claim 2
Dependent Claim 234 words
A process for dyeing a textile substrate comprising wool fibers, which process comprises bringing the substrate into contact with an aqueous dyebath containing a monosulfonated acid dyestuff or a mixture of monosulfonated acid dyestuffs, said dyestuff or mixture having (a) a build up power such that it exhausts onto wool to an extent of 90 to 98% in 60 minutes from a dyebath having a temperature of 98±1° C., a pH of 4.5, a goods: liquor ratio of 1:40 and a dyestuff concentration as required for a 2/1 standard dyeing depth, and (b) a migrating ability such that it is capable of migrating to an extent of 25 to 40% in 60 minutes from a wool sample dyed in a 1/1 standard dyeing depth to an initially undyed wool sample of equal weight in a bath having a temperature of 98±1° C., a pH of 4.5 and a goods:liquor ratio of 1:40, said 25 to 40% being the ratio after said 60 minutes, of the amount of dyestuff on the initially undyed sample to the amount of dyestuff remaining on the dyed sample, and a leveling agent which is an alkoxylation product of an amine substituted by a C 12-30 alkyl or alkenyl group or by a C 13-31 alkylcarbonyl or alkenylcarbonyl group, provided that when the substrate is a wool/synthetic polyamide fiber blend the aqueous dyebath contains a mixture of monosulfonated acid dyestuffs.
Claim 3
Dependent Claim 26 words
A process according to claim 1, in which the acid dyestuff or mixture of acid dyestuffs as a build-up power (a) of from 94 to 98%.
Claim 4
Dependent Claim 26 words
A process according to claim 1, in which the acid dyestuff or mixture of acid dyestuffs has a migrating ability (b) of from 30 to 35%.
Claim 5
Dependent Claim 36 words
A process according to claim 1, in which the acid dyestuff or mixture of acid dyestuffs has a build-up power (a) of from 94 to 98% and a migrating ability (b) of from 30 to 35%.
Claim 6
Dependent Claim 56 words
A process according to claim 1, in which the dyebath contains a mixture of acid dyestuffs in which at least one acid dyestuff has dyeing properties (a) and/or (b) which lie outside the ranges stated in claim 1, the resulting mixture having a build-up power (a) and a migrating ability (b) as indicated in claim 1.
Claim 7
Dependent Claim 105 words
A process according to claim 5, in which the acid dyestuff mixture contains one or more acid dyestuffs having a migrating ability (b) higher than 40% together with one or more dyestuffs having a migrating ability (b) of from 25 to 40% or with one or more acid dyestuffs having a migrating ability (b) lower than 25%, or the acid dyestuff mixture contains one or more acid dyestuffs having a migrating ability lower than 25% together with one or more acid dyestuffs having a migrating ability (b) of from 25 to 40%, the resulting mixture having a migrating ability (b) of from 25 to 40%.
Claim 8
Dependent Claim 16 words
A process according to claim 1, in which the acid dyestuff mixture is a trichromic mixture.
Claim 9
Dependent Claim 91 words
A process according to claim 1 in which the levelling agent is a compound of formula I ##STR2## in which R is C 12-30 alkyl or alkenyl, X is a direct bond or --CO--, Y is C 2 or C 3 alkylene, each of A 1 , A 2 and A 3 is, independently, a polyethylene oxide chain, the total sum of the ethylene oxide units in all three chains being from 20 to 200, and m is 0 or an integer from 1 to 6, or a quaternization product thereof.
Claim 10
Dependent Claim 46 words
A process according to claim 8 in which the levelling agent is a compound of formula I in which R is C 16-22 alkyl or alkenyl, X is a direct bond, Y is propylene, m is 0, 1 or 2 and the compound is not quaternized.
Claim 11
Dependent Claim 13 words
A process according to claim 1 in which the substrate is carbonized wool.
Claim 12
Dependent Claim 24 words
A process according to claim 1 in which the substrate is a wool/synthetic polyamide fibre blend, and a mixture of acid dyestuffs is used.
Claim 13
Dependent Claim 16 words
A process according to claim 5 in which the substrate is a wool/synthetic polyamide fibre blend.
Claim 14
Dependent Claim 29 words
A process according to claim 1 in which the dyeing is carried out by an exhaust process at a pH value corresponding to the isoelectric region of the wool.
Claim 15
Dependent Claim 36 words
A process according to claim 8 in which the acid dyestuff or mixture of acid dyestuffs has a build-up power (a) of from 94 to 98% and a migrating ability (b) of from 30 to 35%.
Claim 16
Dependent Claim 36 words
A process according to claim 9 in which the acid dyestuff or mixture of acid dyestuffs has a build-up power (a) of from 94 to 98% and a migrating ability (b) of from 30 to 35%.
Claim 17
Dependent Claim 28 words
A process according to claim 14 wherein the levelling agent is present in an amount of 0.5 to 2%, by weight, based on the weight of the substrate.
Claim 18
Dependent Claim 28 words
A process according to claim 15 wherein the levelling agent is present in an amount of 0.5 to 2%, by weight, based on the weight of the substrate.
Claim 19
Dependent Claim 27 words
A process according to claim 15 wherein the dyeing is carried out by an exhaust process at a pH corresponding to the isoelectric region of the wool.
Claim 20
Dependent Claim 28 words
A process according to claim 8 wherein the leveling agent is present in an amount of 0.5 to 2%, by weight, based on the weight of the substrate.
Claim 21
Dependent Claim 52 words
A process according to claim 8 wherein the acid dyestuff or mixture of acid dyestuffs has a build-up power (a) of from 94 to 98% or a migrating ability (b) of from 30 to 35% and the dyeing is carried out at a pH corresponding to the isoelectric region of the wool.
Claim 22
Dependent Claim 16 words
A process according to claim 18 wherein the aqueous dyebath contains a mixture of acid dyestuffs.
Claim 23
Dependent Claim 12 words
A process according to claim 18 wherein the substrate is carbonized wool.
Claim 24
Dependent Claim 27 words
A process according to claim 19 wherein the dyeing is carried out by an exhaust process at a pH corresponding to the isoelectric region of the wool.
Claim 25
Dependent Claim 12 words
A process according to claim 19 wherein the substrate is carbonized wool.
Claim 26
Dependent Claim 12 words
A process according to claim 23 wherein the substrate is carbonized wool.

References Cited (Backward Citations)

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US3658460A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-11-10 1990-05-12 1990-11-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-11-10 1994-05-12 1994-11-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-11-10 1998-05-12 1998-11-11 $7700.00 Window Closed / Lapsed

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