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US4620943A Expired / Lapsed US ⏱️ 0.0 years remaining

Bicarbazole-oxadiazole electroactive polymers

Assignee: Chevron USA Inc
•
Filing: 1984-10-25
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Granted: 1986-11-04
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Expires: 2004-10-25
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Abstract

Abstract Tractable doped electroactive polymers, comprising recurring units of a 3,3'-N,N'-disubstituted-6,6'-bicarbazole-1,3,4-oxadiazole-2,5-diyl ring system, and a sufficient concentration of a charge-compensating ionic dopant associated therewith.

Inventors

  • 👤 Peter Denisevich, Jr.
  • 👤 Albert H. Schroeder
  • 👤 Victor P. Kurkov
  • 👤 Shigeto Suzuki

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 06:39
CPC Classifications
H; H01; H01B; H01B1/00; H01B1/06; H01B1/12; H01B1/124; H01B1/128; C; C08; C08G; C08G73/00; C08G73/06; C08G73/08; C08L; C08L79/00; C08L79/04; C08L79/06; H01B1/127

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 60 words
A tractable electroactive polymer which comprises a charged polymer backbone of recurring units of a 3,3'-disubstituted-6,6'-bicarbazole-1,3,4-oxadiazole-2,5-diyl, wherein each carbazole nitrogen is substituted with lower alkyl of 1 to 6 carbon atoms or phenyl, and a sufficient concentration of a charge-compensating ionic dopant associated therewith, wherein the polymer backbone is capable of undergoing reversible oxidation to form the charged polymer backbone.
Claim 2
Dependent Claim 60 words
A tractable electroactive polymer which comprises a charged polymer backbone of recurring units of a 3,3'-disubstituted-6,6'-bicarbazole-1,3,4-oxadiazole-2,5-diyl, wherein each carbazole nitrogen is substituted with lower alkyl of 1 to 6 carbon atoms or phenyl, and a sufficient concentration of a charge-compensating ionic dopant associated therewith, wherein the polymer backbone is capable of undergoing reversible oxidation to form the charged polymer backbone.
Claim 3
Dependent Claim 13 words
The electroactive polymer according to claim 1, wherein the recurring unit is 3,3'-N,N'-diethyl-6,6'-bicarbazole-1,3,4-oxadiazole-2,5-diyl.
Claim 4
Dependent Claim 84 words
The electroactive polymer according to claim 1, wherein the charge-compensating ionic dopant is an anion selected from the group consisting of halogen ions, AsF 4 - , AsF 6 - , ClO 4 - , PF 6 - , SO 3 CF 3 - , BF 4 - , NO 3 - , POF 4 - , CN - , SiF 5 - , SbCl 6 - , SbF 6 - , HSO 4 - , acetate, benzoate, tosylate, or mixtures of said anions.
Claim 5
Dependent Claim 22 words
The electroactive polymer according to claim 1, wherein the polymer backbone has a molecular weight of from about 1,000 to about 250,000.
Claim 6
Dependent Claim 18 words
The electroactive polymer according to claim 4, wherein the polymer backbone has a molecular weight above about 10,000.
Claim 7
Dependent Claim 91 words
A tractable electroactive polymer which comprises a charged polymer backbone and charge-compensating ionic dopants associated therewith of the formula: ##STR2## wherein R is lower alkyl of 1 to 6 carbon atoms or phenyl; n is an integer from 2 to 1,000; d is an integer from 1 to 2,000; S is an integer from 1 to 3; and M is a charge-compensating ionic dopant of opposite electrical charge to the charge of the polymer backbone; wherein the polymer backbone is capable of undergoing reversible oxidation to form the charged polymer backbone.
Claim 8
Dependent Claim 91 words
A tractable electroactive polymer which comprises a charged polymer backbone and charge-compensating ionic dopants associated therewith of the formula: ##STR2## wherein R is lower alkyl of 1 to 6 carbon atoms or phenyl; n is an integer from 2 to 1,000; d is an integer from 1 to 2,000; S is an integer from 1 to 3; and M is a charge-compensating ionic dopant of opposite electrical charge to the charge of the polymer backbone; wherein the polymer backbone is capable of undergoing reversible oxidation to form the charged polymer backbone.
Claim 9
Dependent Claim 11 words
The electroactive polymer according to claim 6, wherein R is ethyl.
Claim 10
Dependent Claim 16 words
The electroactive polymer according to claim 6, wherein n is from about 5 to about 500.
Claim 11
Dependent Claim 16 words
The electroactive polymer according to claim 8, wherein n is from about 10 to about 300.
Claim 12
Dependent Claim 85 words
The electroactive polymer according to claim 6, wherein the charge-compensating ionic dopant M is an anion selected from the group consisting of halogen ions, AsF 4 - , AsF 6 - , ClO 4 - , PF 6 - , SO 3 CF 3 - , BF 4 - , NO 3 - , POF 4 - , CN - , SiF 5 - , SbCl 6 - , SbF 6 - , HSO 4 - , acetate, benzoate, tosylate, or mixtures of said anions.
Claim 13
Dependent Claim 28 words
A polymer of the formula: ##STR3## wherein R is lower alkyl of 1 to 6 carbon atoms or phenyl, and n is an integer from 2 to 1,000.
Claim 14
Dependent Claim 28 words
A polymer of the formula: ##STR3## wherein R is lower alkyl of 1 to 6 carbon atoms or phenyl, and n is an integer from 2 to 1,000.
Claim 15
Dependent Claim 10 words
The polymer according to claim 11, wherein R is ethyl.

References Cited (Backward Citations)

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US4360644A Cited
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US4501686A Cited
US4505840A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-11-03 1990-05-05 1990-11-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-11-03 1994-05-05 1994-11-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-11-03 1998-05-05 1998-11-04 $7700.00 Window Closed / Lapsed

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