Coating compositions prepared from lactone-acrylate adduct, polyol and isocyanate

Claim 2

A composition suitable for use as a radiation curable coating comprising the reaction product of a polycaprolactone polyol, a multi-functional isocyanate, and a lactone-acrylate adduct.

Claim 3

A composition as defined in claim 1 wherein the reaction product contains an hydroxyalkyl acrylate.

Claim 4

A composition as defined in claim 1 wherein the multi-functional isocyanate is selected from 2,4-tolylene diisocyanate, 2,6-tolylene diisocyanate, isophorone diisocyanate, 4,4'-diphenylmethane diisocyanate, di(2-isocyanathoethyl)-bicyclo (2.2.1) hept-5-ene-2,3-dicarboxylate, 3,5,5-tri-ethyl-1-isocyanato-3-isocynato-methylcyclohexane, 1,6-hexamethylene diisocyanate, m-and p-xylene diisocyanate, cyclohexane-1,4-diisocyanate, 4,4'-dicyclohexyl methane diisocyanate, tetramethylene diisocyanate, cyclopentylene-1,3- diisocyanate, 1,3-diisocyanate, 1,4-xylene diisocyanate, 1,5-naphthalene diisocyanate, m-phenylene diisocyanate, p-phenylene diisocyanate, hexamethylene diisocyanate, 3,3'-dimethyl -4,4'-diphenylmethane diisocyanate, 4,4'-diphenylene diisocyanate, 3,3'-dimethoxy-4,4'-dimethyl-4,4'-biphenylene diisocyanate, durene diisocyanate, 1-phenoxy-2,4-phenylene diisocyanate, 1-tert-butyl-2,4-phenylene diisocyanate, 2,2,4-trimethylhexamethylene diisocyanate, 1,3,5-benzene triisocyanate, 2,4,6-toluene triisocyanate, or mixtures thereof.

Claim 5

A composition as defined in claim 1 wherein the lactone-acrylate adduct is prepared by reacting a lactone with an hydroxyalkyl acrylate.

Claim 6

A composition as defined in claim 4 wherein the lactone is characterized by the following formula: ##STR7## wherein the R''s are independently hydrogen or alkyl of from 1 to 12 carbon atoms, and x is from 4 to 7.

Claim 7

A composition as defined in claim 5 wherein the lactone is epsilon-carprolactone.

Claim 8

A composition as defined in claim 4 wherein the hydroxyalkyl acrylate is selected from 2-hydroxyethyl acrylate, hydroxypropyl acrylate, hydroxybutyl acrylate, 2-hydroxy-3-chloropropylacrylate, 2,3-dihydroxy propyl acrylate, or mixtures thereof.

Claim 9

A composition as defined in claim 7 wherein the hydroxyalkyl acrylate is hydroxyethyl acrylate.

Claim 10

A composition as defined in claim 2 wherein the hydroxyalkyl acrylate is as defined in claim 7.

Claim 11

A composition as defined in claim 1 which contains a reactive solvent.

Claim 12

A composition as defined in claim 10 wherein the reactive solvent is of the following formula: ##STR8## wherein X is hydrogen or methyl and R 2 can be substituted or unsubstituted alkyl, cycloalkyl, alkenyl, aryl, or aralkyl, wherein the substituent can be alkoxy, hydroxy, cyano, or amino, or R 2 can be carbamoyloxy alkyl which can be N-alkyl substituted.

Claim 13

A composition as defined in claim 10 wherein the reactive solvent is a multi-functional alkyl acrylate.

Claim 14

A composition as defined in claim 12 wherein the reactive solvent is 1,6-hexanediol diacrylate, neopentyl glycol diacrylate, tetramethyleneglycol diacrylate, esterdiol-204-diacrylate, trimethylolpropane triacylate, triethyleneglycol diacrylate, the diacrylate of an alkoxylated esterdiol 204, or mixtures thereof. PG,52

Claim 15

A composition as defined in claim 10 wherein the reactive solvent is N-vinylpyrrolidone.

Claim 16

A composition as defined in claim 12 wherein the reactive solvent is a lactone-acrylate adduct reacted with a multi-functional isocyanate.

Claim 17

A composition as defined in claim 1 which contains a non-reactive solvent.

Claim 18

A composition as defined in claim 16 wherein the solvent is cyclohexanone, toluene, methyl isobutyl ketone, tetrahydrofuran, methyl amyl ketone, ethoxy ethyl acetate, and mixtures thereof.

Claim 19

A cured coating prepared from the composition of claim 1 or 10 or 16.

Claim 20

A composition suitable for use as a radiation curable coating comprising the reaction product of (a) a polycaprolactone polyol; (b) a multifunctional isocyanate; and (c) a lactone-acrylate adduct wherein in excess of 20 percent by weight of component (a), based on the total weight of components (a), (b) and (c), is reacted.

Claim 21

A composition suitable for use as a radiation curable coating comprising the reaction product of (a) a polycaprolactone polyol; (b) a multifunctional isocyanate; and (c) a lactone-acrylate adduct wherein in excess of 20 percent by weight of component (a), based on the total weight of components (a), (b) and (c), is reacted.

Claim 22

A composition suitable for use as a radiation curable coating comprising the reaction product of (a) a polycaprolactone polyol; (b) a multifunctional isocyanate; (c) a lactone-acrylate adduct; and (d) an hydroxyalkyl acrylate wherein in excess of 20 percent by weight of component (a), based on the total weight of components (a), (b), (c) and (d) is reacted.

Claim 23

A composition suitable for use as a radiation curable coating comprising the reaction product of (a) a polycaprolactone polyol; (b) a multifunctional isocyanate; (c) a lactone-acrylate adduct; and (d) an hydroxyalkyl acrylate wherein in excess of 20 percent by weight of component (a), based on the total weight of components (a), (b), (c) and (d) is reacted.

Claim 24

A composition as defined in claim 20 which contains a reactive solvent.

Claim 25

A composition as defined in claim 20 which contains a non-reactive solvent.

Claim 26

A composition as defined in claim 19 which contains a reactive solvent.

Claim 27

A composition as defined in claim 19 which contains a non-reactive solvent.

Claim 28

A composition as defined in claim 1 wherein said isocyanate is reacted with said polyol, followed by the reaction of that product with said lactone-acrylate adduct.

Claim 29

A composition as defined in claim 2 wherein said isocyanate is reacted with said polyol, followed by the reaction of that product with the lactone-acrylate adduct and said hydroxylalkyl acrylate.

Claim 30

A composition as defined in claim 19 wherein said isocyanate is reacted with said polyol, followed by the reaction of that product with said lactone-acrylate adduct.

Claim 31

A composition as defined in claim 20 wherein said isocynate is reacted with said polyol, followed by the reaction of that product with said lactone-acrylate adduct.