Laminating adhesives containing polymerized surfactant

Claim 1

A pressure sensitive laminating adhesive polymer emulsion having a glass transition temperature of from -60° to -20° C., the emulsion polymer consisting essentially of: (a) at least 70% by weight of the polymer of an acrylic or methacrylic acid ester containing 4 to 12 carbon atoms or mixture of such esters; (b) from 15 to 20% of the polymer of a water miscible vinyl ester of an aliphatic carboxylic acid containing 1 to 13 carbon atoms; (c) from 2 to 10% of the polymer of a monoethylenically unsaturated mono- or di-carboxylic acid containing 2 to 5 carbon atoms or the hydroxyalkyl (C 2 -C 4 ) esters thereof; (d) from 0.75 to 10% of the polymer of a polymerizable surfactant selected from the class consisting of: (i) ring sulfonated maleate half esters of an alkoxylated alkyl arylol having the formula: ##STR5## where R 1 is selected from the group consising of ethylene, propylene, and mixtures thereof, R 2 is selected from the group consisting of hydrogen and alkyl groups each of which contains from 5 through 18 carbon atoms each, A is selected from the group consisting of phenyl nuclei or phenyl nuclei and naphthyl nuclei or naphthyl nuclei, X is selected from the group consisting of hydrogen, alkali, metals, ammonium, lower monoalkyl amines lower dialkyl amines, lower trialkyl amines, lower monoalkanol amines, lower dialkanol amines, lower trialkanol amines, heterocyclic amines, phosphates, and mixtures thereof, and n is a number of from about 2 through 50 inclusive, provided that, when R 2 is hydrogen (R 1 O) n has at least one of the following structures: --(PO) p --(EO) q --' --(PO) p --(EO) q --(PO) r --(EO) s --' and --(PO) p --(EO) q --(PO) r --(EO) s --(PO) t --(EO) u wherein p, r, and t, when present, are each an independently selected number of from about 3 through 9 inclusive; q, s, and u, when present, are each an independently selected number of from about 1 through 4 inclusive, and when the associated (EO) entity is a terminated block, q, s, and u can each be an independently selected positive number of from 1 to 20, P is propylene, and E is ethylene; (ii) compounds of the formula: ##STR6## wherein R is alkyl of 6 to 22 carbon atoms, M is H, Li, Na, K or NH 4 and n is an integer 2 to 4; and (iii) polymerizable (allyl) sulfosuccinates; (e) from 0 to 19% of the polymer of a half ester or salt of a dicarboxylic acid containing 2 to 8 carbon atoms in the ester portion thereof, wherein the total of components (c) and (e) are less than 20% by weight of the total polymer; and (f) from 0 to 20% of other copolymerizable monomers. wherein the adhesive polymer emulsion is characterized by its ability to be diluted with at least 15 parts alcohol per 100 parts wet emulsion.