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US4614675A Expired / Lapsed US ⏱️ 0.0 years remaining

Antimicrobic, antistatic siloxane compositions and method for treating materials

Assignee: DuPont Toray Specialty Materials KK
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Filing: 1985-12-20
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Granted: 1986-09-30
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Expires: 2005-12-20
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Abstract

Abstract A composition for treating a solid material to give it antimicrobic, hydrophilic and antistatic properties comprises siloxane compound which has one or more alkoxysilylalkyl groups and one or more polyoxyalkylene groups and a silane having antimicrobial properties. In a preferred embodiment the composition is used to treat fibers and fiber-containing materials. The composition can further contain a curing agent for the siloxane. Emulsion compositions are particularly useful.

Inventors

  • 👤 Isao Ona
  • 👤 Masaru Ozaki

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 22:42
CPC Classifications
D; D06; D06M; D06M15/00; D06M15/19; D06M15/37; D06M15/643; D06M15/647; A; A01; A01N; A01N55/00; C; C08; C08K; C08K5/00; C08K5/54; C08K5/544; C08G; C08G77/00; C08G77/42; C08G77/46; Y; Y10; Y10S; Y10S524/00; Y10S524/91; Y10S524/911; Y10S524/912; Y10S524/913; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31652; Y10T428/31663

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 234 words
A composition comprising (A) 100 parts by weight of a silane having the formula Z.sup.⊖ YR.sub.2 NR.sup.⊖ 'SiX.sub.g R.sub.(3-g) wherein Z.sup.⊖ denotes a halide ion, Y denotes a monovalent hydrocarbon radical containing from 10 to 20 carbon atoms, R denotes a monovalent hydrocarbon or halogenated hydrocarbon radical containing from 1 to 10 carbon atoms, R' denotes an alkylene radical having from 2 to 10 carbon atoms, X denotes an alkoxy radical or an alkoxyalkoxy radical containing from 1 to 4 carbon atoms and g has a value of 2 or 3, and (B) from 1 to 100 parts by weight of an organopolysiloxane compound which contains, in each molecule, at least one siloxane unit having the formula X.sub.a R.sub.(3-a) SiR"'SiR.sub.b O.sub.(3-b)/2 and at least one siloxane unit having the formula R"(OC.sub.3 H.sub.6).sub.c (OC.sub.2 H.sub.4).sub.d OR'SiR.sub.e O.sub.(3-e)/2 wherein R, R' and X are as noted above for component (A), R" denotes a hydrogen atom or a monovalent organic radical having from 1 to 5 carbon atoms, R'" denotes an oxygen atom or an alkylene radical having from 2 to 4 carbon atoms, a=1, 2 or 3; b=0, 1 or 2; c=0 to 50; d=0 to 50; c+d=2 to 100; and e=1 or 2, any remaining siloxane units in the organopolysiloxane compound having the formula R f SiO.sub.(4-f)/2 wherein R has the meaning denoted above for components (A) and (B) and f=0, 1, 2 or 3.
Claim 2
Dependent Claim 234 words
A composition comprising (A) 100 parts by weight of a silane having the formula Z.sup.⊖ YR.sub.2 NR.sup.⊖ 'SiX.sub.g R.sub.(3-g) wherein Z.sup.⊖ denotes a halide ion, Y denotes a monovalent hydrocarbon radical containing from 10 to 20 carbon atoms, R denotes a monovalent hydrocarbon or halogenated hydrocarbon radical containing from 1 to 10 carbon atoms, R' denotes an alkylene radical having from 2 to 10 carbon atoms, X denotes an alkoxy radical or an alkoxyalkoxy radical containing from 1 to 4 carbon atoms and g has a value of 2 or 3, and (B) from 1 to 100 parts by weight of an organopolysiloxane compound which contains, in each molecule, at least one siloxane unit having the formula X.sub.a R.sub.(3-a) SiR"'SiR.sub.b O.sub.(3-b)/2 and at least one siloxane unit having the formula R"(OC.sub.3 H.sub.6).sub.c (OC.sub.2 H.sub.4).sub.d OR'SiR.sub.e O.sub.(3-e)/2 wherein R, R' and X are as noted above for component (A), R" denotes a hydrogen atom or a monovalent organic radical having from 1 to 5 carbon atoms, R'" denotes an oxygen atom or an alkylene radical having from 2 to 4 carbon atoms, a=1, 2 or 3; b=0, 1 or 2; c=0 to 50; d=0 to 50; c+d=2 to 100; and e=1 or 2, any remaining siloxane units in the organopolysiloxane compound having the formula R f SiO.sub.(4-f)/2 wherein R has the meaning denoted above for components (A) and (B) and f=0, 1, 2 or 3.
Claim 3
Dependent Claim 107 words
A composition according to claim 1 wherein the organopolysiloxane compound has the formula A(R.sub.2 SiO).sub.x (RQSiO).sub.y (RGSiO).sub.z SiR.sub.2 A wherein Q denotes a radical having the formula --R"'SiX a R.sub.(3-a), G denotes a radical having the formula --R'O(C 2 H 4 O) d (C 3 H 6 O) c R", A denotes a radical selected from the group consisting of R, Q and G radicals, x has a value of from 1 to 500, y has a value of from 0 to 100 and z has a value of from 0 to 100, there being at least one Q radical and one G radical in the organopolysiloxane.
Claim 4
Dependent Claim 14 words
A composition according to claim 2 wherein each R radical is a methyl radical.
Claim 5
Dependent Claim 14 words
A composition according to claim 3 wherein each X radical is a methoxy radical.
Claim 6
Dependent Claim 14 words
A composition according to claim 4 wherein one A radical is a methyl radical.
Claim 7
Dependent Claim 14 words
A composition according to claim 4 wherein one A radical is a Q radical.
Claim 8
Dependent Claim 14 words
A composition according to claim 4 wherein one A radical is a G radical.
Claim 9
Dependent Claim 13 words
A composition according to claim 4 wherein both A radicals are Q radicals.
Claim 10
Dependent Claim 13 words
A composition according to claim 4 wherein both A radicals are G radicals.
Claim 11
Dependent Claim 13 words
A composition according to claim 4 wherein both A radicals are methyl radicals.
Claim 12
Dependent Claim 38 words
A composition according to claim 1 wherein the organopolysiloxane compound has the formula Me 3 SiO(Me 2 SiO) x (MeQSiO) y (MeGSiO) z SiMe 2 Q wherein x, y and z are positive integers and Me denotes methyl.
Claim 13
Dependent Claim 17 words
A composition according to claim 11 wherein Q denotes the --CH 2 CH 2 Si(OMe) 3 radical.
Claim 14
Dependent Claim 29 words
A composition according to claim 1 wherein the composition further comprises a curing amount of a curing agent comprising a curing catalyst and/or a crosslinking compound for silanol groups.
Claim 15
Dependent Claim 13 words
A composition according to claim 13 wherein the composition is an aqueous emulsion.
Claim 16
Dependent Claim 29 words
A composition according to claim 2 wherein the composition further comprises a curing amount of a curing agent comprising a curing catalyst and/or a crosslinking compound for silanol groups.
Claim 17
Dependent Claim 13 words
A composition according to claim 15 wherein the composition is an aqueous emulsion.
Claim 18
Dependent Claim 29 words
A composition according to claim 11 wherein the composition further comprises a curing amount of a curing agent comprising a curing catalyst and/or a crosslinking compound for silanol groups.
Claim 19
Dependent Claim 13 words
A composition according to claim 17 wherein the composition is an aqueous emulsion.
Claim 20
Dependent Claim 40 words
A method for treating a solid material, said method comprising applying to the solid material an amount of a composition comprising the composition of claim 1, said amount being sufficient to provide antistatic, hydrophilic, antimicrobic properties to the solid material.
Claim 21
Dependent Claim 13 words
A method according to claim 19 wherein the solid material comprises a fiber.

References Cited (Backward Citations)

US4500339A Cited
US4500338A Cited
US4500337A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-09-29 1990-03-31 1990-09-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-09-29 1994-03-31 1994-09-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-09-29 1998-03-31 1998-09-30 $7700.00 Window Closed / Lapsed

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