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US4613541A Expired / Lapsed US ⏱️ 0.0 years remaining

Electronic device using electron transport proteins

Assignee: Mitsubishi Electric Corp
•
Filing: 1985-12-31
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Granted: 1986-09-23
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Expires: 2005-12-31
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Abstract

Abstract An electronic device comprises a substrate (16) of glass, a plurality of elongated electrodes (17) which are provided in parallel with each other on the glass substrate, a first electron transport protein film (18) prepared by cytochrome c formed on the electrodes, a second electron transport protein film (19) of flavodoxin adhered and joined on the first electron transport protein film and a plurality of elongated electrodes (20) provided in parallel with each other on the second electron transport protein film. Cytochrome c is different in redox potential from flavodoxin, whereby rectifying characteristics are attained in the device in a molecular level by junction of the first electron transport protein film (18) and the second electron transport protein film (19).

Inventors

  • 👤 Satoru Isoda

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 04:43
CPC Classifications
B; B82; B82Y; B82Y10/00; B82Y30/00; H; H10; H10K; H10K10/00; H10K10/701; Y; Y10; Y10S; Y10S977/00; Y10S977/902; Y10S977/932; Y10S977/936; Y10T; Y10T428/00; Y10T428/24; Y10T428/24942; Y10T428/31504; Y10T428/31678; Y10T428/31681; Y10T428/31685; Y10T428/31725; Y10T428/31768

Claims Analysis

Total Claims: 26
Claim 1
Independent Claim 94 words
An electronic device comprising: a first electron transport protein film prepared by an electron transport protein having a first redox potential; a second electron transport protein film prepared by an electron transport protein having a second redox potential different from said first redox potential, said second electron transport protein film being joined to said first electron transport protein film; first electrodes connected to said first electron transport protein film; and second electrodes connected to said second electron transport protein film, difference between said first and second redox potentials being utilized to provide rectifying characteristics.
Claim 2
Dependent Claim 94 words
An electronic device comprising: a first electron transport protein film prepared by an electron transport protein having a first redox potential; a second electron transport protein film prepared by an electron transport protein having a second redox potential different from said first redox potential, said second electron transport protein film being joined to said first electron transport protein film; first electrodes connected to said first electron transport protein film; and second electrodes connected to said second electron transport protein film, difference between said first and second redox potentials being utilized to provide rectifying characteristics.
Claim 3
Dependent Claim 29 words
An electronic device in accordance with claim 1, wherein said electron transport proteins are selected from non-heme iron-sulfur protein, cytochrome c protein, cytochrome b protein, flavodoxin, plastocyanin and thioredoxin.
Claim 4
Dependent Claim 20 words
An electronic device in accordance with claim 1, wherein said first and second electron transport protein films are monomolecular films.
Claim 5
Dependent Claim 21 words
An electronic device in accordance with claim 1, wherein supply of electrons to said electron transport proteins is performed through enzyme.
Claim 6
Dependent Claim 17 words
An electronic device in accordance with claim 1, wherein said first and second electrodes are metal electrodes.
Claim 7
Dependent Claim 20 words
An electronic device in accordance with claim 5, wherein said metal electrodes are subjected to chemical modification by organic molecules.
Claim 8
Dependent Claim 82 words
An electronic device in accordance with claim 1, wherein said electron transport proteins are oriented to be in specific molecular arrangement in the same type of electron transport protein film and in different types of electron transport protein films so that electron transfer is caused in the units of electron transport protein molecules vertically to junction between said first and second electron transport protein films while no such electron transfer is caused between said electron transport protein molecules horizontal to said junction.
Claim 9
Dependent Claim 25 words
An electronic device in accordance with claim 1, wherein lipid or fatty acid is employed as a support for orientation of said electron transport proteins.
Claim 10
Dependent Claim 148 words
An electronic device having diode characteristics, comprising: an insulated substrate; a plurality of first elongated electrodes provided in parallel with each other on the upper surface of said insulated substrate; a first electron transport protein film adhered and joined to said insulated substrate and the upper surfaces of said plurality of first elongated electrodes, said first electron transport protein film being prepared by an electron transport protein having a first redox potential; a second electron transport protein film adhered and joined on the upper surface of said first electron transport protein film, said second electron transport protein film being prepared by an electron transport protein having a second redox potential different from said first redox potential; and a plurality of second elongated electrodes provided in parallel with each other on the upper surface of said second electron transport protein film perpendicularly to said plurality of first elongated electrodes.
Claim 11
Dependent Claim 148 words
An electronic device having diode characteristics, comprising: an insulated substrate; a plurality of first elongated electrodes provided in parallel with each other on the upper surface of said insulated substrate; a first electron transport protein film adhered and joined to said insulated substrate and the upper surfaces of said plurality of first elongated electrodes, said first electron transport protein film being prepared by an electron transport protein having a first redox potential; a second electron transport protein film adhered and joined on the upper surface of said first electron transport protein film, said second electron transport protein film being prepared by an electron transport protein having a second redox potential different from said first redox potential; and a plurality of second elongated electrodes provided in parallel with each other on the upper surface of said second electron transport protein film perpendicularly to said plurality of first elongated electrodes.
Claim 12
Dependent Claim 149 words
An electronic device comprising: a first electron transport protein film prepared by an electron transport protein having a first redox potential; a second electron transport protein film prepared by an electron transport protein having a second redox potential different from said first redox potential, said second electron transport protein film being joined to said first electron transport protein film; a third electron transport protein film prepared by an electron transport protein having a third redox potential different from said second redox potential, said third electron transport protein film being joined to said second electron transport protein film; first electrodes connected to said first electron transport protein film; second electrodes connected to said second electron transport protein film; and third electrodes connected to said third electron transport protein film, difference between said first, second and third redox potentials being utilized to provide at least one of transistor and switching characteristics.
Claim 13
Dependent Claim 149 words
An electronic device comprising: a first electron transport protein film prepared by an electron transport protein having a first redox potential; a second electron transport protein film prepared by an electron transport protein having a second redox potential different from said first redox potential, said second electron transport protein film being joined to said first electron transport protein film; a third electron transport protein film prepared by an electron transport protein having a third redox potential different from said second redox potential, said third electron transport protein film being joined to said second electron transport protein film; first electrodes connected to said first electron transport protein film; second electrodes connected to said second electron transport protein film; and third electrodes connected to said third electron transport protein film, difference between said first, second and third redox potentials being utilized to provide at least one of transistor and switching characteristics.
Claim 14
Dependent Claim 29 words
An electronic device in accordance with claim 10, wherein said electron transport proteins are selected from non-heme iron-sulfur protein, cytochrome c protein, cytochrome b protein, flavodoxin, plastocyanin and thioredoxin.
Claim 15
Dependent Claim 21 words
An electronic device in accordance with claim 10, wherein said first, second and third electron transport protein films are monomolecular films.
Claim 16
Dependent Claim 21 words
An electronic device in accordance with claim 10, wherein supply of electrons to said electron transport proteins is performed through enzyme.
Claim 17
Dependent Claim 18 words
An electronic device in accordance with claim 10, wherein said first, second and third electrodes are metal electrodes.
Claim 18
Dependent Claim 20 words
An electronic device in accordance with claim 14, wherein said metal electrodes are subjected to chemical modification by organic molecules.
Claim 19
Dependent Claim 80 words
An electronic device in accordance with claim 10, wherein said electron transport proteins are oriented to be in specific molecular arrangement in the same type of electron transport protein film and in different types of electron transport protein films so that electron transfer is caused in the units of electron transport protein molecules vertically to junction between respective said electron transport protein films while no such electron transfer is caused between said electron transport protein molecules horizontal to said junction.
Claim 20
Dependent Claim 25 words
An electronic device in accordance with claim 10, wherein lipid or fatty acid is employed as a support for orientation of said electron transport proteins.
Claim 21
Dependent Claim 22 words
An electronic device in accordance with claim 10, wherein said first electrodes and said second electrodes are arranged perpendicularly to each other.
Claim 22
Dependent Claim 27 words
An electronic device in accordance with claim 18, wherein said first and second electrodes are groups of elongated electrodes which are in parallel with each other respectively.
Claim 23
Dependent Claim 22 words
An electronic device in accordance with claim 10, wherein said second electrodes and said third electrodes are arranged perpendicularly to each other.
Claim 24
Dependent Claim 27 words
An electronic device in accordance with claim 20, wherein said second and third electrodes are groups of elongated electrodes which are in parallel with each other respectively.
Claim 25
Dependent Claim 237 words
An electronic device having at least one of transistor and switching characteristics, comprising: an insulated substrate; a plurality of first elongated electrodes provided in parallel with each other on the upper surface of said insulated substrate; a first electron transport protein film adhered and joined on said insulated substrate and the upper surfaces of said plurality of first elongated electrodes, said first electron transport protein film being prepared by an electron transport protein having a first redox potential; a plurality of control electrodes provided in parallel with each other on the upper surface of said first electron transport protein film perpendicularly to said plurality of first elongated electrodes; a second electron transport protein film adhered and joined to the upper surface of said first electron transport protein film as well as joined to said control electrodes, said second electron transport protein film being prepared by an electron transport protein having a second redox potential different from said first redox potential; a third electron transport protein film adhered and joined to the upper surface of said second electron transport protein film, said third electron transport protein film being prepared by an electron transport protein having a third redox potential different from said second redox potential; and a plurality of second elongated electrodes provided in parallel with each other on the upper surface of said third electron transport protein film in parallel with said plurality of first elongated electrodes.
Claim 26
Dependent Claim 237 words
An electronic device having at least one of transistor and switching characteristics, comprising: an insulated substrate; a plurality of first elongated electrodes provided in parallel with each other on the upper surface of said insulated substrate; a first electron transport protein film adhered and joined on said insulated substrate and the upper surfaces of said plurality of first elongated electrodes, said first electron transport protein film being prepared by an electron transport protein having a first redox potential; a plurality of control electrodes provided in parallel with each other on the upper surface of said first electron transport protein film perpendicularly to said plurality of first elongated electrodes; a second electron transport protein film adhered and joined to the upper surface of said first electron transport protein film as well as joined to said control electrodes, said second electron transport protein film being prepared by an electron transport protein having a second redox potential different from said first redox potential; a third electron transport protein film adhered and joined to the upper surface of said second electron transport protein film, said third electron transport protein film being prepared by an electron transport protein having a third redox potential different from said second redox potential; and a plurality of second elongated electrodes provided in parallel with each other on the upper surface of said third electron transport protein film in parallel with said plurality of first elongated electrodes.

References Cited (Backward Citations)

US3966580A Cited
US4103073A Cited
US4103064A Cited
US4541908A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-09-22 1990-03-24 1990-09-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-09-22 1994-03-24 1994-09-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-09-22 1998-03-24 1998-09-23 $7700.00 Window Closed / Lapsed

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