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US4612294A Expired / Lapsed US ⏱️ 0.0 years remaining

Glass material for optical fibers used in infrared region

Assignee: Hitachi Cable Ltd
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Filing: 1984-11-26
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Granted: 1986-09-16
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Expires: 2004-11-26
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Abstract

Abstract A selenium-base chalcogenide glass for use as optical fibers suitable for transmitting with low loss infrared rays, particularly that of 10.6 μm in wavelength, is provided. The infrared optical fibers with low transmission loss, which is suitable for practical use, are obtained by incorporating 2 to 100 ppm of at least one of Al Ga, and In into a selenium-base chalcogenide glass, thereby to reduce the absorption due to the vibration of Ge--O bond formed by the contamination with oxygen. The infrared optical fibers made of such a glass material show a transmission loss of 3-4 dB/m which is less than 1/2.5 of the loss (10 dB/m) of a reference glass.

Inventors

  • 👤 Toshio Katsuyama
  • 👤 Shin Satoh
  • 👤 Hiroyoshi Matsumura

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 19:18
CPC Classifications
C; C03; C03C; C03C3/00; C03C3/32; C03C3/321; C03C13/00; C03C13/04; C03C13/041; C03C13/043; Y; Y10; Y10S; Y10S501/00; Y10S501/90; Y10S501/904; Y10S65/00; Y10S65/15

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 82 words
An infrared-transmitting glass material for use as optical fibers used in infrared region, which is a selenium-base chalcogenide glass selected from the group consisting of selenium-germanium glass, selenium-antimony-germanium glass and selenium arsenic-germanium glass in which from 2 ppm to 100 ppm of at least one of aluminum, gallium and indium is incorporated, wherein said glass exhibits a substantial decrease in absorption loss due to Ge--O bond over the same glass absent said incorporation of a least one of aluminum, gallium and indium.
Claim 2
Dependent Claim 82 words
An infrared-transmitting glass material for use as optical fibers used in infrared region, which is a selenium-base chalcogenide glass selected from the group consisting of selenium-germanium glass, selenium-antimony-germanium glass and selenium arsenic-germanium glass in which from 2 ppm to 100 ppm of at least one of aluminum, gallium and indium is incorporated, wherein said glass exhibits a substantial decrease in absorption loss due to Ge--O bond over the same glass absent said incorporation of a least one of aluminum, gallium and indium.
Claim 3
Dependent Claim 20 words
The glass material according to claim 1, wherein the composition of the selenium-base chalcogenide glass consists of selenium and germanium.
Claim 4
Dependent Claim 21 words
The glass material according to claim 1, wherein the composition of the selenium-base chalcogenide glass consists of germanium, arsenic, and selenium.
Claim 5
Dependent Claim 21 words
The glass material according to claim 1, wherein the composition of the selenium-base chalcogenide glass consists of germanium, antimony, and selenium.
Claim 6
Dependent Claim 21 words
The glass material according to claim 1, wherein the purity of each of aluminium, gallium, and indium is 99.999% or more.
Claim 7
Dependent Claim 20 words
The glass material according to claim 2, wherein the purity of each of germanium and selenium is 99.999% or more.
Claim 8
Dependent Claim 20 words
The glass material according to claim 3, wherein the purity of each of germanium and selenium is 99.999% or more.
Claim 9
Dependent Claim 20 words
The glass material according to claim 4, wherein the purity of each of germanium and selenium is 99.999% or more.
Claim 10
Dependent Claim 16 words
The glass material according to claim 3, wherein the purity of arsenic is 99.999% or more.
Claim 11
Dependent Claim 16 words
The glass material according to claim 4, wherein the purity of antimony is 99.999% or more.
Claim 12
Dependent Claim 24 words
The glass material according to claim 1, wherein the selenium-base chalcogenide glass is selenium-germanium glass in which the molar ratio of Ge:Se is 20:80.

References Cited (Backward Citations)

US3360649A Cited
US3627573A Cited
US3511992A Cited
US3615413A Cited
US3901996A Cited
US4154503A Cited
JPS5988338A Cited
JPS59182247A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-09-15 1990-03-17 1990-09-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-09-15 1994-03-17 1994-09-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-09-15 1998-03-17 1998-09-16 $7700.00 Window Closed / Lapsed

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