Impact resistant composites with elastomeric fibers

Claim 2

An impact resistant composite consisting essentially of a polymer or polymer precursor and oriented thermoplastic elastomeric fibers: said polymer or polymer precursor being compatible with and adhesive to said thermoplastic elastomeric fibers, and forming, without said thermoplastic elastomeric fibers, a neat polymer matrix having an elongation of less than about 10%; said thermoplastic elastomeric fibers being (a) during preparation of said composite, embedded in said polymer or polymer precursor under from about 0 tension to tension only sufficient to eliminate slack, (b) capable of developing tension when embedded in said polymer or polymer precursor, and (c) present in said composite in an amount of from about 1 to about 95 percent by weight of composite; and said composite having an elongation of at least 10% greater than the elongation of the neat polymer matrix.

Claim 3

A composite of claim 1 wherein the polymer is thermoplastic.

Claim 4

A composite of claim 1 wherein the polymer is selected from the group consisting of polystyrene, polymethyl methacrylate, cross-linked polymethyl methacrylate, polybutyl methacrylate, thermoplastic and thermoset polyester, copolymer of methyl methacrylate and butyl methyl methacrylate, copolymers of styrene and methyl methacrylate and epoxy resin.

Claim 5

A composite of claim 1 wherein the polymer is selected from the group consisting of polystyrene, polymethyl methacrylate, and cross-linked polymethyl methacrylate.

Claim 6

A composite of claim 4 wherein thermoplastic elastomeric fibers are arranged in substantially parallel alignment in at least one direction.

Claim 7

A composite of claim 5 wherein the thermoplastic elastomeric fibers are embedded in the polymer or polymer precursor during the preparation of said composite under tension only sufficient to eliminate slack.

Claim 8

A composite of claim 6 wherein the oriented thermoplastic elastomeric fibers are disposed in one or more layers.

Claim 9

A composite of claim 7 wherein the thermoplastic elastomeric fibers are selected from the group consisting of polyester elastomers, polyester/polyether elastomers, polyamide/polyester/polyether elastomers, polyester/polyurethane elastomers, polytetramethylene terephthalate, and polyester/polyurethane elastomers.

Claim 10

A composite of claim 8 wherein the elastomeric fibers have a draw ratio of from about 1.2 to 4.5.

Claim 11

A composite of claim 8, wherein the composite has an elongation of at least about 60% greater than the elongation of the neat polymer matrix.

Claim 12

A composite of claim 8, wherein the composite has an elongation from about 11% to about 200%.

Claim 13

A composite of claim 11, wherein the composite has an elongation from about 60% to about 200%.

Claim 14

A composite of claim 9 wherein the polymer is polystyrene or polymethyl methacrylate.

Claim 15

A composite of claim 13 wherein the thermoplastic elastomeric fibers are polyester/polyether elastomers.

Claim 16

A composite of claim 8 wherein the thermoplastic elastomeric fibers are sheath/core fibers of two elastomers.

Claim 17

A composite of claim 8 wherein the thermoplastic elastomeric fibers are hollow.

Claim 18

A composite of claim 8 having a second layer of parallel thermoplastic elastomeric fibers oriented 90 degrees to a first layer of parallel elastomeric fibers.

Claim 19

A composite of claim 17 having 3 or more layers of thermoplastic elastomeric fibers.

Claim 20

A composite of claim 8 wherein the thermoplastic elastomeric fibers are present in the composite in an amount of from about 2 to about 30 percent by weight of composite.

Claim 21

A composite of claim 19 wherein the thermoplastic elastomeric fibers are present in the composite in an amount of from about 10 to about 30 percent by weight of composite.

Claim 22

A process for preparing an impact resistant composite consisting essentially of a polymer or polymer precursor and oriented thermoplastic elastomeric fibers comprising the steps of: (a) embedding said thermoplastic elastomeric fibers in said polymer or polymer precursor under from about 0 tension to tension only sufficient to eliminate slack; and (b) hardening said polymer or polymer precursor to form a composite; said polymer or polymer precursor being compatible with and adhesive to said thermoplastic elastomeric fibers, and forming, without said thermoplastic elastomeric fibers, a neat polymer matrix having an elongation of less than about 10%; and said thermoplastic elastomeric fibers being (a) capable of developing tension when embedded in said polymer or polymer precursor, and (b) present in said composite in an amount of from about 2 to about 95 percent by weight of composite.

Claim 23

A process for preparing an impact resistant composite consisting essentially of a polymer or polymer precursor and oriented thermoplastic elastomeric fibers comprising the steps of: (a) embedding said thermoplastic elastomeric fibers in said polymer or polymer precursor under from about 0 tension to tension only sufficient to eliminate slack; and (b) hardening said polymer or polymer precursor to form a composite; said polymer or polymer precursor being compatible with and adhesive to said thermoplastic elastomeric fibers, and forming, without said thermoplastic elastomeric fibers, a neat polymer matrix having an elongation of less than about 10%; and said thermoplastic elastomeric fibers being (a) capable of developing tension when embedded in said polymer or polymer precursor, and (b) present in said composite in an amount of from about 2 to about 95 percent by weight of composite.

Claim 24

A process as defined in claim 21, wherein the polymer is thermoplastic.

Claim 25

A process as defined in claim 21, wherein the polymer is selected from the group consisting of polystyrene, polymethyl methacrylate, cross-linked polymethyl methacrylate, polybutyl methacrylate, thermoplastic and thermoset polyester, copolymer of methyl methacrylate and butyl methyl methacrylate, copolymers of styrene and methyl methacrylate, and epoxy resin.

Claim 26

A process as defined in claim 23, wherein the polymer is selected from the group consisting of polystyrene, polymethyl methacrylate, and cross-linked polymethyl methacrylate.

Claim 27

A process as defined in claim 24, wherein the thermoplastic elastomeric fibers are embedded in the polymer or polymer precursor under tension only sufficient to eliminate slack.

Claim 28

A process as defined in claim 25, wherein the thermoplastic elastomeric fibers are selected from the group consisting of polyester elastomers, polyester/polyether elastomers, polyamide/polyester/polyether elastomers, polyester/polyurethane elastomers, polytetramethylene terephthalate, and polyester/polyurethane elastomers.