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US4608301A Expired / Lapsed US ⏱️ 0.0 years remaining

Radiographic intensifying screen

Assignee: Fujifilm Holdings Corp
•
Filing: 1984-08-01
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Granted: 1986-08-26
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Expires: 2004-08-01
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Abstract

Abstract A radiographic intensifying screen comprising a support and a phosphor layer provided thereon which comprises a binder and a phosphor dispersed therein, characterized in that said binder contains a (meth)acrylic copolymer in the amount of 5-100% by weight, having repeating units represented by the formulas (I), (II) and (III): ##STR1## in which each of R 1 , R 3 and R 5 is independently a hydrogen atom or an alkyl group; R 2 is a group selected from those consisting of an alkyl group, a cycloalkyl group, an aryl group, a heterocyclic group and an aralkyl group; R 4 is a hydrogen atom or an alkyl group, provided that R 4 is not identical to R 2 ; and x, y and z which represent molar percents are numbers satisfying the conditions of 5≦x≦99, 1≦y+z≦95 and x+y+z≧90. The (meth)acrylic copolymer is preferably employed in combination with a linear polyester having a hydroxyl value in the range of 20-70.

Inventors

  • 👤 Akio Ishizuka
  • 👤 Hisashi Yamazaki
  • 👤 Kikuo Yamazaki

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 00:09
CPC Classifications
G; G21; G21K; G21K4/00; C; C08; C08K; C08K3/00; C08K3/18; C08K3/24; C09; C09K; C09K11/00; C09K11/02; Y; Y10; Y10S; Y10S428/00; Y10S428/913; Y10T; Y10T428/00; Y10T428/25; Y10T428/256; Y10T428/258; Y10T428/31504; Y10T428/31507; Y10T428/31551; Y10T428/31565; Y10T428/31573; Y10T428/31678; Y10T428/31692; Y10T428/31699; Y10T428/31721; Y10T428/31725; Y10T428/3175; Y10T428/31786; Y10T428/31797; Y10T428/31855; Y10T428/3188; Y10T428/31895; Y10T428/31906

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 136 words
A radiographic intensifying screen comprising a plastic film support and a phosphor layer provided thereon which comprises a binder and a phosphor dispersed therein, said binder containing a (meth)acrylic copolymer in the amount of 5-100% by weight, having repeating units represented by the formulas (I), (II) and (III): ##STR6## in which each of R 1 , R 3 and R 5 is independently a hydrogen atom or an alkyl group; R 2 is a group selected from those consisting of an alkyl group, a cycloalkyl group, an aryl group, a heterocyclic group and an aralkyl group; R 4 is a hydrogn atom or an alkyl group, provided that R 4 is not identical to R 2 ; and x, y and z which represent molar percents are numbers satisfying the conditions of 5≦x≦99, 1≦y+z≦95 and x+y+z≧90.
Claim 2
Dependent Claim 136 words
A radiographic intensifying screen comprising a plastic film support and a phosphor layer provided thereon which comprises a binder and a phosphor dispersed therein, said binder containing a (meth)acrylic copolymer in the amount of 5-100% by weight, having repeating units represented by the formulas (I), (II) and (III): ##STR6## in which each of R 1 , R 3 and R 5 is independently a hydrogen atom or an alkyl group; R 2 is a group selected from those consisting of an alkyl group, a cycloalkyl group, an aryl group, a heterocyclic group and an aralkyl group; R 4 is a hydrogn atom or an alkyl group, provided that R 4 is not identical to R 2 ; and x, y and z which represent molar percents are numbers satisfying the conditions of 5≦x≦99, 1≦y+z≦95 and x+y+z≧90.
Claim 3
Dependent Claim 46 words
The radiographic intensifying screen as claimed in claim 1, in which x, y and z in the formulas (I), (II) and (III) are numbers satisfying the conditions of 50≦x≦95, 5≦y+z≦50 and x+y+z≧95, and said binder contains the (meth)acrylic copolymer in the amount of 40-90% by weight.
Claim 4
Dependent Claim 33 words
The radiographic intensifying screen as claimed in claim 2, in which x, y and z in the formulas (I), (II) and (III) are numbers satisfying the conditions of 70≦x≦95, y=0, 5≦z≦30 and x+y+z≧95.
Claim 5
Dependent Claim 29 words
The radiographic intensifying screen as claimed in claim 2, in which x, y and z in the formulas (I), (II) and (III) are numbers satisfying the conditions of x+y+z=100.
Claim 6
Dependent Claim 20 words
The radiographic intensifying screen as claimed in claim 1, in which said (meth)acrylic copolymer is crosslinked with a crosslinking agent.
Claim 7
Dependent Claim 16 words
The radiographic intensifying screen as claimed in claim 5, in which said crosslinking agent is polyisocyanate.
Claim 8
Dependent Claim 169 words
A radiographic intensifying screen comprising a plastic film support, a phosphor layer which comprises a binder and a phosphor dispersed therein, and a protective film, superposed in this order, said binder containing a mixture of a (meth)acrylic copolymer having repeating units represented by the formulas (I), (II) and (III) and a linear polyester having a hydroxyl value in the range of 20-70 whose content is not more than 40% by weight of said mixture, in the amount of 60-100% by weight: ##STR7## in which each of R 1 , R 3 and R 5 is independently a hydrogen atom or an alkyl group; R 2 is a group selected from those consisting of an alkyl group, a cycloalkyl group, an aryl group, a heterocyclic group and an aralkyl group; R 4 is a hydrogen atom or an alkyl group, provided that R 4 is not identical to R 2 ; and x, y and z which represent molar percents are numbers satisfying the conditions of 5≦x≦99, 1≦y+z≦95 and x+y+z≧90.
Claim 9
Dependent Claim 169 words
A radiographic intensifying screen comprising a plastic film support, a phosphor layer which comprises a binder and a phosphor dispersed therein, and a protective film, superposed in this order, said binder containing a mixture of a (meth)acrylic copolymer having repeating units represented by the formulas (I), (II) and (III) and a linear polyester having a hydroxyl value in the range of 20-70 whose content is not more than 40% by weight of said mixture, in the amount of 60-100% by weight: ##STR7## in which each of R 1 , R 3 and R 5 is independently a hydrogen atom or an alkyl group; R 2 is a group selected from those consisting of an alkyl group, a cycloalkyl group, an aryl group, a heterocyclic group and an aralkyl group; R 4 is a hydrogen atom or an alkyl group, provided that R 4 is not identical to R 2 ; and x, y and z which represent molar percents are numbers satisfying the conditions of 5≦x≦99, 1≦y+z≦95 and x+y+z≧90.
Claim 10
Dependent Claim 27 words
The radiographic intensifying screen as claimed in claim 7, in which said linear polyester has a molecular weight in the range of 3×10 3 -10 4 .
Claim 11
Dependent Claim 29 words
The radiographic intensifying screen as claimed in claim 7, in which said binder contains the mixture of (meth)acrylic copolymer and linear polyester in the amount of 75-95% by weight.
Claim 12
Dependent Claim 28 words
The radiographic intensifying screen as claimed in claim 7, in which the content of said linear polyester is in the range of 10-40% by weight of the mixture.

References Cited (Backward Citations)

US2676112A Cited
US4508636A Cited
US4486486A Cited
US4501796A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-08-25 1990-02-24 1990-08-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-08-25 1994-02-24 1994-08-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-08-25 1998-02-24 1998-08-26 $7700.00 Window Closed / Lapsed

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