US4607004A
Expired / Lapsed
US
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Silver halide color photographic light-sensitive material
Assignee: Fujifilm Holdings Corp
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Filing: 1984-12-17
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Granted: 1986-08-19
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Expires: 2004-12-17
Abstract
Abstract A silver halide color photographic light-sensitive material is disclosed, comprising a support having provided thereon light-sensitive silver halide emulsion layers, wherein on the outside of the light-sensitive silver halide emulsion layer positioned farthest from the support, a layer containing silver halide fine grains of about 0.2μ or less in average grain size is provided, and in the silver halide color photographic light-sensitive material at least one compound represented by the following general formula (I) is present: ##STR1## wherein M represents a hydrogen atom, an alkali metal or a quaternary ammonium group, X represents COOM' or SO 3 M' (wherein M' represents a hydrogen atom, an alkali metal or a quaternary ammonium group), n represents 1 or 2, R 1 represents a group capable of substituting on the phenyl group, and m represents 0, 1 or 2.
Inventors
- 👤 Shinpei Ikenoue
- 👤 Haruhiko Iwano
- 👤 Hiroyuki Mifune
- 👤 Morio Yagihara
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 09:22
CPC Classifications
G; G03; G03C; G03C7/00; G03C7/30; G03C7/392; G03C7/39208; G03C7/3924; G03C7/39244; G03C7/3926; Y; Y10; Y10S; Y10S430/00; Y10S430/162
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
196 words
A silver halide color photographic light-sensitive material comprising a support having provided thereon light-sensitive silver halide emulsion layers, wherein on the outside of the light-sensitive silver halide emulsion layer positioned farthest from the support, a protective emulsion layer containing silver halide fine grains of 0.2μ or less in average grain size which are not substantially developable by development processing of the silver halide color photographic light-sensitive material and which are less sensitive than the light sensitive silver halide grains in said light sensitive silver halide emulsion layers by 0.5 or more in terms of log units is provided, and in the silver halide color photographic light-sensitive material at least one compound represented by the following general formula (I) is present in an amount sufficient to depress fog of the silver halide color photographic material after preservation: ##STR6## wherein M represents a hydrogen atom, an alkali metal or a quaternary ammonium group, X represents COOM' or SO 3 M', wherein M' represents a hydrogen atom, an alkali metal or a quaternary ammonium group, n represents 1 or 2, R 1 represents a group capable of substituting on the phenyl group, and m represents 0, 1 or 2.
Claim 2
Dependent Claim
196 words
A silver halide color photographic light-sensitive material comprising a support having provided thereon light-sensitive silver halide emulsion layers, wherein on the outside of the light-sensitive silver halide emulsion layer positioned farthest from the support, a protective emulsion layer containing silver halide fine grains of 0.2μ or less in average grain size which are not substantially developable by development processing of the silver halide color photographic light-sensitive material and which are less sensitive than the light sensitive silver halide grains in said light sensitive silver halide emulsion layers by 0.5 or more in terms of log units is provided, and in the silver halide color photographic light-sensitive material at least one compound represented by the following general formula (I) is present in an amount sufficient to depress fog of the silver halide color photographic material after preservation: ##STR6## wherein M represents a hydrogen atom, an alkali metal or a quaternary ammonium group, X represents COOM' or SO 3 M', wherein M' represents a hydrogen atom, an alkali metal or a quaternary ammonium group, n represents 1 or 2, R 1 represents a group capable of substituting on the phenyl group, and m represents 0, 1 or 2.
Claim 3
Dependent Claim
62 words
The silver halide color photographic light-sensitive material as claimed in claim 1, wherein said alkali metal is selected from the group consisting of potassium, sodium and lithium and said quaternary ammonium group is selected from the group consisting of --NH 4 , --N(CH 3 ) 4 , --N(C 2 H 5 ) 4 , and --NH(C 2 H 5 ) 3 .
Claim 4
Dependent Claim
30 words
The silver halide color photographic light-sensitive material as claimed in claim 1, wherein X represents COOM' wherein M' represents a hydrogen atom, an alkali metal or a quaternary ammonium group.
Claim 5
Dependent Claim
95 words
The silver halide color photographic light-sensitive material as claimed in claim 1, wherein R 1 is selected from the group consisting of a halogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkoxycarbonyl group, an acylamino group, a carbamoyl group, an alkylcarbamoyl group, a dialkylcarbamoyl group, an arylcarbamoyl group, an alkylsulfonyl group, an arylsulfonyl group, an alkylsulfonamido group, an arylsulfonamido group, a sulfamoyl group, an alkylsulfamoyl group, a dialkylsulfamoyl group, an alkylthio group, an arylthio group, a cyano group, a nitro group, a hydroxy group, and an amino group.
Claim 6
Dependent Claim
45 words
The silver halide color photographic light-sensitive material as claimed in claim 1, wherein said R 1 is selected from the group consisting of an alkyl group, a substituted alkyl group, an alkoxy group, and a substituted alkoxy group, each having up to 3 carbon atoms.
Claim 7
Dependent Claim
38 words
The silver halide color photographic light-sensitive material as claimed in claim 1, wherein said compound represented by formula (I) is employed in an amount of from about 10 -4 to about 10 -1 mol per mol of silver.
Claim 8
Dependent Claim
35 words
The silver halide color photographic light-sensitive material as claimed in claim 6, wherein said compound represented by formula (I) is employed in an amount of from 10 -3 to 5×10 -2 per mol of silver.
Claim 9
Dependent Claim
33 words
The silver halide color photographic light-sensitive material as claimed in claim 1, wherein the compound represented by general formula (I) is added to a light-sensitive emulsion layer, a protective layer or an interlayer.
Claim 10
Dependent Claim
40 words
The silver halide color photographic light-sensitive material as claimed in claim 1, wherein said compound represented by general formula (I) is incorporated in a layer positioned closer to the support than the protective layer which contains fine silver halide grains.
Claim 11
Dependent Claim
28 words
The silver halide color photographic light-sensitive material as claimed in claim 1, wherein said silver halide fine grains have an average grain size of 0.15 μm or less.
Claim 12
Dependent Claim
28 words
The silver halide color photographic light-sensitive material as claimed in claim 10, wherein said silver halide fine grains have an average grain size of 0.1 μm or less.
Claim 13
Dependent Claim
33 words
The silver halide color photographic light-sensitive material as claimed in claim 1, wherein said silver halide fine grains are coated in an amount of from 0.03 to 2.0 g of silver/m 2 .
Claim 14
Dependent Claim
33 words
The silver halide color photographic light-sensitive material as claimed in claim 12, wherein said silver halide fine grains are coated in an amount of from 0.05 to 1 g of silver/m 2 .
Claim 15
Dependent Claim
42 words
The silver halide color photographic light-sensitive material as claimed in claim 1, wherein said silver halide fine grains are less sensitive than light-sensitive silver halide grains in said light-sensitive silver halide emulsion layers by 1.0 or more in terms of log units.
Claim 16
Dependent Claim
43 words
The silver halide color photographic light-sensitive material as claimed in claim 1, wherein said light-sensitive material contains a hardener represented by the following general formula (II): (CH.sub.2 ═CH--SO.sub.2 --CH.sub.2).sub.2 A wherein A represents a divalent group which may or may not be present.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-08-18 | 1990-02-17 | 1990-08-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-08-18 | 1994-02-17 | 1994-08-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-08-18 | 1998-02-17 | 1998-08-19 | $7700.00 | Window Closed / Lapsed |