US4605567A
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Crosslinkable organopolysiloxanes and a method for preparing the crosslinkable organopolysiloxanes
Assignee: Wacker Chemie AG
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Filing: 1985-09-30
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Granted: 1986-08-12
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Expires: 2005-09-30
Abstract
Abstract Organopolysiloxanes having the formulas A.sub.x R.sub.3-x SiO(SiR.sub.2-x A.sub.x O).sub.n SiR.sub.3-x A.sub.x or (SiR.sub.2-x A.sub.x O).sub.y, where R is a monovalent hydrocarbon radical or a halogenated monovalent hydrocarbon radical or a monovalent aliphatic radical consisting of carbon, hydrogen, ether oxygen and fluorine atoms; A is a SiC-bonded organic radical containing a carboxyl group and a carbonyl group to which is bonded an organic radical having at least one terminal carbon-carbon double bond; n is an integer having a value of at least 1; x is 0 or 1; and y is an integer having a value of from 3 to 10, in which the organopolysiloxanes contain at least one radical represented by A per molecule. These organopolysiloxanes are preferably prepared by reacting organopolysiloxanes having the above formulas, in which the radical A is hydrogen, with, for example, allylsuccinic anhydride, and thereafter reacting the resultant organopolysiloxanes, which contain carboxylic acid anhydride groups, with, for example, a hydroxyethyl acrylate. The organopolysiloxanes can be crosslinked, for example, by ultraviolet light, and may be used in the preparation of coatings or for embedding electronic components.
Inventors
- 👤 Johann Muller
- 👤 Christa Trieschmann
- 👤 Gerhard Preiner
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 08:57
CPC Classifications
C; C08; C08G; C08G77/00; C08G77/04; C08G77/38; H; H10; H10W; H10W74/00; H10W74/40; H10W74/47; H10W74/476
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
123 words
Crosslinkable organopolysiloxanes having the formula selected from the group consisting of A.sub.x R.sub.3-x SiO(SiR.sub.2-x A.sub.x O).sub.n SiR.sub.3-x A.sub.x and (SiR.sub.2-x A.sub.x O).sub.y, where R is selected from the group consisting of a monovalent hydrocarbon radical, a halogenated monovalent hydrocarbon radical and a monovalent aliphatic radical containing carbon, hydrogen, ether oxygen and fluorine atoms; A represents a SiC-bonded organic radical containing a carboxyl group and a carbonyl group to which is bonded an organic radical having at least one terminal carbon-carbon double bond; n is an integer having a value of at least 1; x is 0 or 1; and y is an integer having a value of from 3 to 10, in which the organopolysiloxanes contain at least one radical A per molecule.
Claim 2
Dependent Claim
123 words
Crosslinkable organopolysiloxanes having the formula selected from the group consisting of A.sub.x R.sub.3-x SiO(SiR.sub.2-x A.sub.x O).sub.n SiR.sub.3-x A.sub.x and (SiR.sub.2-x A.sub.x O).sub.y, where R is selected from the group consisting of a monovalent hydrocarbon radical, a halogenated monovalent hydrocarbon radical and a monovalent aliphatic radical containing carbon, hydrogen, ether oxygen and fluorine atoms; A represents a SiC-bonded organic radical containing a carboxyl group and a carbonyl group to which is bonded an organic radical having at least one terminal carbon-carbon double bond; n is an integer having a value of at least 1; x is 0 or 1; and y is an integer having a value of from 3 to 10, in which the organopolysiloxanes contain at least one radical A per molecule.
Claim 3
Dependent Claim
166 words
The organopolysiloxane of claim 1, wherein the radical A is selected from the formula consisting of ##STR7## where R 1 is a divalent radical selected from the group consisting of a hydrocarbon radical and a halogenated hydrocarbon radical; R 2 is selected from the group consisting of hydrogen and a monovalent hydrocarbon radical which is free of aliphatic carbon-carbon multiple bonds and has from 1 to 10 carbon atoms per radical; R 3 is a hydrocarbon radical which is divalent when a is 1, trivalent when a is 2 and tetravalent when a is 3; X is selected from the group consisting of oxygen, sulfur and a radical having the formula --NR 2 --, R 2 is the same as above and Y is selected from the formula consisting of ##STR8## R 1 and R 2 are the same as above; a is 1, 2 or 3 and m is an integer having a value of from 1 to 6 and x is 0 or 1.
Claim 4
Dependent Claim
17 words
The organopolysiloxane of claim 1, wherein A is a radical selected from the group consisting of ##STR9##
Claim 5
Dependent Claim
273 words
A method for preparing the crosslinkable organopolysiloxanes of claim 1, which comprises reacting in a first stage, an organopolysiloxane selected from the group consisting of H.sub.x R.sub.3-x SiO(SiR.sub.2-x H.sub.x O).sub.n SiR.sub.3-x H.sub.x and (SiR.sub.2-x H.sub.x O).sub.y with dicarboxylic acid anhydride having the formula ##STR10## where R is selected from the group consisting of a monovalent hydrocarbon radical, a halogenated monovalent hydrocarbon radical and a monovalent aliphatic radical containing carbon, hydrogen, ether oxygen and fluorine atoms; R 2 is selected from the group consisting of hydrogen and a monovalent hydrocarbon radical which is free of aliphatic carbon-carbon multiple bonds and has from 1 to 10 carbon atoms per radical; R 5 is selected from the group consisting of a monovalent hydrocarbon radical containing an aliphatic carbon-carbon double bond and a halogenated monovalent hydrocarbon radical containing an aliphatic carbon-carbon double bond; m is an integer having a value of from 1 to 6 and x is 0 or 1 and then, in a second stage, reacting the compound obtained in the first stage with a compound having the formula (H.sub.2 C═CR.sup.2 Y.sub.x).sub.a R.sup.3 XH (II) where R 2 is the same as above; R 3 is a hydrocarbon radical which is divalent when a is 1, trivalent when a is 2 and tetravalent when a is 3; X is selected from the group consisting of oxygen, sulfur and a radical having the formula --NR 2 --, R 2 is the same as above and Y is selected from the formula consisting of ##STR11## R 1 and R 2 are the same as above; a is 1, 2 or 3 and x is 0 or 1.
Claim 6
Dependent Claim
13 words
The method of claim 4, wherein the dicarboxylic acid anhydride is allylsuccinic anhydride.
Claim 7
Dependent Claim
14 words
The method of claim 4, wherein the compound of formula II is hydroxyethyl acrylate.
Claim 8
Dependent Claim
14 words
The crosslinkable organopolysiloxanes of claim 1, wherein the organopolysiloxanes are mixed with a photosensitizer.
Claim 9
Dependent Claim
14 words
The crosslinkable organopolysiloxanes of claim 2, wherein the organopolysiloxanes are mixed with a photosensitizer.
Claim 10
Dependent Claim
14 words
The crosslinkable organopolysiloxanes of claim 3, wherein the organopolysiloxanes are mixed with a photosensitizer.
Claim 11
Dependent Claim
14 words
The crosslinkable organopolysiloxanes of claim 1, wherein the organopolysiloxanes are mixed with a peroxide.
Claim 12
Dependent Claim
14 words
The crosslinkable organopolysiloxanes of claim 2, wherein the organopolysiloxanes are mixed with a peroxide.
Claim 13
Dependent Claim
14 words
The crosslinkable organopolysiloxanes of claim 3, wherein the organopolysiloxanes are mixed with a peroxide.
Claim 14
Dependent Claim
27 words
A method for coating a substrate which comprises applying the crosslinkable organopolysiloxanes of claim 7 to the substrate and thereafter exposing the organopolysiloxanes to a radiation source.
Claim 15
Dependent Claim
24 words
The method of claim 13, wherein the crosslinkable organopolysiloxanes of claim 8 are applied to the substrate and then exposed to a radiation source.
Claim 16
Dependent Claim
24 words
The method of claim 13, wherein the crosslinkable organopolysiloxanes of claim 9 are applied to the substrate and then exposed to a radiation source.
Claim 17
Dependent Claim
32 words
A method for coating a substrate which comprises applying the crosslinkable organopolysiloxanes of claim 10 to the substrate and then heating the organopolysiloxanes to a temperature which is sufficient to promote crosslinking.
Claim 18
Dependent Claim
27 words
The method of claim 16, wherein the crosslinkable organopolysiloxanes of claim 11 are applied to the substrate and then heated to a temperature sufficient to promote crosslinking.
Claim 19
Dependent Claim
27 words
The method of claim 16, wherein the crosslinkable organopolysiloxanes of claim 12 are applied to the substrate and then heated to a temperature sufficient to promote crosslinking.
References Cited (Backward Citations)
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| 3.5 Years (Year 4) | 1989-08-11 | 1990-02-10 | 1990-08-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-08-11 | 1994-02-10 | 1994-08-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-08-11 | 1998-02-10 | 1998-08-12 | $7700.00 | Window Closed / Lapsed |