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US4602959A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for preventing multiplication of algae

Assignee: Momentive Performance Materials Japan LLC
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Filing: 1985-04-17
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Granted: 1986-07-29
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Expires: 2005-04-17
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Abstract

Abstract Disclosed is a method for preventing multiplication of algae which is characterized by coating the surfaces of solid materials with a silicone emulsion composition prepared by emulsion polymerization of: (1) 0.1 to 60% by weight of a reaction product prepared by reacting (A) 50 to 99.9% by weight of a polydiorganosilozane having more than one silanol group on the average in each molecule and having a viscosity of 5 to 10,000 cSt at 25 DEG C. with (B) 0.1 to 50% by weight of a product prepared by reacting (a) 1 mol of a compound represented by the formula: <IMAGE> wherein Q1 is a monovalent group selected from the group consisting of a hydrogen atom, -CH3, -CH2CH2NH2 and -CH2CH2NHCH2CH2NH2, R1 is a divalent hydrocarbon group having 1 to 4 carbon atoms, R2 and R3 are monovalent hydrocarbon groups each having 1 to 4 carbon atoms, and a is an integer of 0 or 1, with (b) 0.5 to 3.0 mol of a compound represented by the formula: <IMAGE> wherein Q2 is an epoxy group-containing group selected from a glycidoxy group and an epoxycyclohexyl group, R4 is a divalent hydrocarbon group having 2 to 4 carbon atoms, R5 and R6 are monovalent hydrocarbon groups each having 1 to 4 carbon atoms, and b is an integer of 0 or 1, and (2) 1 to 50% by weight of a compound represented by the formula: <IMAGE> wherein R7 and R8 are same or different substituted or unsubstituted hydrocarbon groups each having 1 to 50 carbon atoms, and n is an integer of 3 or more, in the presence of (3) 0.1 to 20% by weight of a quaternary ammonium salt surface active agent and (4) 20 to 90% by weight of water.

Inventors

  • 👤 Akitsugu Kurita
  • 👤 Shinji Kida
  • 👤 Masaaki Otsuki

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 23:09
CPC Classifications
C; C08; C08G; C08G77/00; C08G77/04; C08G77/22; C08G77/26; C09; C09D; C09D5/00; C09D5/16; C09D5/1656; C09D5/1662; C09D5/1675; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31652; Y10T428/31663

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 311 words
A method for preventing multiplication of algae comprising coating the surfaces of materials with a composition comprising silicone emulsion prepared by emulsion polymerization of: (1) 0.1 to 60% by weight of a reaction product prepared by reacting (A) 50 to 99.9% by weight of a polydiorganosiloxane having more than one silanol group on the average in each molecule and having a viscosity of 5 to 10,000 cSt at 25° C. with (B) 0.1 to 50% by weight of a product prepared by reacting (a) 1 mole of a compound represented by the formula: ##STR10## wherein Q 1 is a monovalent group selected from the group consisting of a hydrogen atom, --CH 3 , --CH 2 CH 2 NH 2 and --CH 2 CH 2 NHCH 2 CH 2 NH 2 , R 1 is a divalent hydrocarbon group having 1 to 4 carbon atoms, R 2 and R 3 are monovalent hydrocarbon groups each having 1 to 4 carbon atoms, and a is an integer of 0 or 1, with (b) 0.5 to 3.0 moles of a compound represented by the formula: ##STR11## wherein Q 2 is an epoxy group-containing group selected from a glycidoxy group and an epoxycyclohexyl group, R 4 is a divalent hydrocarbon group having 2 to 4 carbon atoms, R 5 and R 6 are monovalent hydrocarbon groups each having 1 to 4 carbon atoms, and b is an integer of 0 or 1, and (2) 1 to 50% by weight of a compound represented by the formula: ##STR12## wherein R 7 and R 8 are same or different substituted or unsubstituted hydrocarbon groups each having 1 to 50 carbon atoms, and n is an integer of 3 or more, in the presence of (3) 0.1 to 20% by weight of a quaternary ammonium salt surface active agent and (4) 20 to 90% by weight of water.
Claim 2
Independent Claim 311 words
A method for preventing multiplication of algae comprising coating the surfaces of materials with a composition comprising silicone emulsion prepared by emulsion polymerization of: (1) 0.1 to 60% by weight of a reaction product prepared by reacting (A) 50 to 99.9% by weight of a polydiorganosiloxane having more than one silanol group on the average in each molecule and having a viscosity of 5 to 10,000 cSt at 25° C. with (B) 0.1 to 50% by weight of a product prepared by reacting (a) 1 mole of a compound represented by the formula: ##STR10## wherein Q 1 is a monovalent group selected from the group consisting of a hydrogen atom, --CH 3 , --CH 2 CH 2 NH 2 and --CH 2 CH 2 NHCH 2 CH 2 NH 2 , R 1 is a divalent hydrocarbon group having 1 to 4 carbon atoms, R 2 and R 3 are monovalent hydrocarbon groups each having 1 to 4 carbon atoms, and a is an integer of 0 or 1, with (b) 0.5 to 3.0 moles of a compound represented by the formula: ##STR11## wherein Q 2 is an epoxy group-containing group selected from a glycidoxy group and an epoxycyclohexyl group, R 4 is a divalent hydrocarbon group having 2 to 4 carbon atoms, R 5 and R 6 are monovalent hydrocarbon groups each having 1 to 4 carbon atoms, and b is an integer of 0 or 1, and (2) 1 to 50% by weight of a compound represented by the formula: ##STR12## wherein R 7 and R 8 are same or different substituted or unsubstituted hydrocarbon groups each having 1 to 50 carbon atoms, and n is an integer of 3 or more, in the presence of (3) 0.1 to 20% by weight of a quaternary ammonium salt surface active agent and (4) 20 to 90% by weight of water.
Claim 3
Dependent Claim 22 words
The method for preventing multiplication of algae according to claim 1, wherein both ends of said polydiorganosiloxane are terminated with silanol groups.
Claim 4
Dependent Claim 29 words
The method for preventing multiplication of algae according to claim 1, wherein the viscosity of said polydiorganosiloxane at 25° C. is within the range of 50 to 1,000 cSt.
Claim 5
Dependent Claim 28 words
The method for preventing multiplication of algae according to claim 1, wherein said emulsion polymerization is carried out additionally in the presence of a nonionic surface active agent.
Claim 6
Dependent Claim 24 words
The method for preventing multiplication of algae according to claim 1, wherein said emulsion polymerization is carried out using potassium hydroxide as a catalyst.

References Cited (Backward Citations)

US4080190A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-07-28 1990-01-27 1990-07-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-07-28 1994-01-27 1994-07-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-07-28 1998-01-27 1998-07-29 $7700.00 Window Closed / Lapsed

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