US4600649A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Abrasion-resistant ultraviolet-curable coatings
Assignee: Covestro Resins BV
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Filing: 1984-10-22
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Granted: 1986-07-15
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Expires: 2004-10-22
Abstract
Abstract Ultraviolet-curable, liquid coating compositions are disclosed which are resistant to abrasion and which are strongly adherent to basic plastic surfaces. These compositions comprise one or more polyacrylates or polymethacrylates, preferably including from 70% to 85% of trimethylol propane triacrylate, from 5% to 15% of a carboxylic acid which contains acrylic or methacrylic unsaturation, preferably acrylic acid itself, and photoinitiators (which are preferably ketonic and which desirably comprise a substituted acetophenone and benzophenone) are used to render the composition sensitive to ultraviolet light. The polyacrylate component preferably includes from 1% to 12% of a diacrylate or dimethacrylate of a diglycidyl ether of a bisphenol in which the molecular weight of the diglycidyl ether is less than about 600. The above proportions are based on the total weight of polymerizable material. The composition preferably also includes 0.5% to 2.5% of a silicone dicarbinol diurethane diacrylate in which the carbinol groups are carried by an alkoxylate, preferably an ethoxylate, constituting from 30% to 70% of the silicone dicarbinol.
Inventors
- 👤 A. Frank Leo
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 14:23
CPC Classifications
C; C08; C08F; C08F222/00; C08F222/10; C08F222/1006; C08F222/103; C09; C09D; C09D4/00; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31507; Y10T428/31652; Y10T428/31663; Y10T428/31855; Y10T428/31909; Y10T428/31913; Y10T428/3192
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
63 words
A radiation curable, liquid coating composition comprising from 70% to 85% of one or more polyacrylates or methacrylates containing at least 2.4 unsaturated groups per molecule, from 5% to 15% of a carboxylic acid which contains acrylic or methacrylic unsaturation, and at least one photoinitiator rendering the composition sensitive to ultraviolet light, said proportions being based on the total weight of polymerizable material.
Claim 2
Dependent Claim
63 words
A radiation curable, liquid coating composition comprising from 70% to 85% of one or more polyacrylates or methacrylates containing at least 2.4 unsaturated groups per molecule, from 5% to 15% of a carboxylic acid which contains acrylic or methacrylic unsaturation, and at least one photoinitiator rendering the composition sensitive to ultraviolet light, said proportions being based on the total weight of polymerizable material.
Claim 3
Dependent Claim
16 words
A coating composition as recited in claim 1 in which said polyacrylate is trimethylol propane triacrylate.
Claim 4
Dependent Claim
24 words
A coating composition as recited in claim 1 in which said polyacrylate component includes from 1% to 12% of an epoxy diacrylate or dimethacrylate.
Claim 5
Dependent Claim
37 words
A coating composition as recited in claim 3 in which said epoxy diacrylate is a diacrylate of a diglycidyl ether of a bisphenol in which the molecular weight of the diglycidyl ether is less than about 600.
Claim 6
Dependent Claim
45 words
A coating composition as recited in claim 1 in which said composition includes 0.5% to 2.5% of a silicone dicarbinol diurethane diacrylate or dimethacrylate in which the carbinol groups are carried by an ethoxylate or propoxylate constituting from 30% to 70% of the silicone dicarbinol.
Claim 7
Dependent Claim
38 words
A coating composition as recited in claim 5 in which said silicone dicarbinol diurethane diacrylate is based on a methyl or phenyl-substituted polysiloxane ethoxylated to from 40% to 60% and having a molecular of from 600 to 10,000.
Claim 8
Dependent Claim
14 words
A coating composition as recited in claim 1 in which said photoinitiators are ketonic.
Claim 9
Dependent Claim
17 words
A coating composition as recited in claim 7 in which said ketonic photoinitiators comprise a substituted acetophenone.
Claim 10
Dependent Claim
17 words
A coating composition as recited in claim 8 in which said ketonic photoinitiator is 1-hydroxycyclohexyl phenyl ketone.
Claim 11
Dependent Claim
15 words
A coating composition as recited in claim 7 in which said photoinitiators further comprise benzophenone.
Claim 12
Dependent Claim
27 words
A coating composition as recited in claim 2 in which said trimethylol propane has been acrylated to provide an average of about 2.8 acrylate groups per molecule.
Claim 13
Dependent Claim
29 words
A coating composition as recited in claim 4 in which said diacrylate of a diglycidyl ether of a bisphenol is present in an amount of from 3% to 7%.
Claim 14
Dependent Claim
31 words
A coating composition as recited in claim 1 in which said composition further includes up to about 10% of the polymerizable material of a C 4 to C 8 diol diacrylate.
Claim 15
Dependent Claim
18 words
A coating composition as recited in claim 13 in which from 1% to 6%, of 1,6-hexanedioldiacrylate is employed.
Claim 16
Dependent Claim
30 words
A coating composition as recited in claim 1 in which said carboxylic acid containing acrylic unsaturation is a carboxyl-functional C 1 -C 6 alkylene ester or amide of acrylic acid.
Claim 17
Dependent Claim
19 words
A coating composition as recited in claim 15 in which said carboxylic acid containing acrylic unsaturation is acrylic acid.
Claim 18
Dependent Claim
22 words
A plastic having a basic surface coated with an ultraviolet-cured adherent abrasion resistant coating of the coating composition recited in claim 1.
Claim 19
Dependent Claim
22 words
A coated plastic as recited in claim 17 in which said basic plastic surface is selected from polycarbonate and ester-plasticized polyvinyl chloride.
Claim 20
Dependent Claim
122 words
A radiation curable, liquid coating composition comprising from 70% to 85% of trimethylol propane triacrylate containing from 2.4 to 2.8 acrylate groups per molecule, from 1% to 12% of a diacrylate of a diglycidyl ether of a bisphenol in which the molecular weight of the diglycidyl ether is less than about 600, from 0.5% to 2.5% of a silicone dicarbinol diurethane diacrylate based on a methyl or phenyl-substituted polysiloxane which has been ethoxylated to from 40% to 60% and having a molecular of from 600 to 10,000, from 5% to 15% of acrylic acid, and at least one ketonic photoinitiator comprising a substituted acetophenone rendering the composition sensitive to ultraviolet light, said proportions being based on the total weight of polymerizable material.
Claim 21
Dependent Claim
122 words
A radiation curable, liquid coating composition comprising from 70% to 85% of trimethylol propane triacrylate containing from 2.4 to 2.8 acrylate groups per molecule, from 1% to 12% of a diacrylate of a diglycidyl ether of a bisphenol in which the molecular weight of the diglycidyl ether is less than about 600, from 0.5% to 2.5% of a silicone dicarbinol diurethane diacrylate based on a methyl or phenyl-substituted polysiloxane which has been ethoxylated to from 40% to 60% and having a molecular of from 600 to 10,000, from 5% to 15% of acrylic acid, and at least one ketonic photoinitiator comprising a substituted acetophenone rendering the composition sensitive to ultraviolet light, said proportions being based on the total weight of polymerizable material.
Claim 22
Dependent Claim
23 words
A coating composition as recited in claim 19 further including from 1% to 6% of a C 4 to C 8 diol diacrylate.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-07-14 | 1990-01-13 | 1990-07-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-07-14 | 1994-01-13 | 1994-07-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-07-14 | 1998-01-13 | 1998-07-15 | $7700.00 | Window Closed / Lapsed |