US4598155A
Expired / Lapsed
US
⏱️ 0.0 years remaining
3(5-tetrazolyl)1,4-diaminoanthraquinones
Assignee: BASF Corp
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Filing: 1982-11-15
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Granted: 1986-07-01
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Expires: 2002-11-15
Abstract
Abstract There are described novel compounds of the formula I <IMAGE> (I) wherein the symbols R1, R2, R3, R7 and A have the meanings defined in claim 1, also processes for producing them and their use as dyes for dyeing and printing textile materials, on which are obtained brilliant, deeply colored, blue dyes, particularly on polyester materials.
Inventors
- 👤 Jean-Marie Adam
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 11:02
CPC Classifications
C; C09; C09B; C09B1/00; C09B1/16; C09B1/20
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
341 words
A 1,4-diaminoanthraquinone compound of the formula ##STR125## wherein R 1 and R 2 independently of one another are each hydrogen; C 1 -C 6 alkyl or C 1 -C 6 alkyl substituted by hydroxy, C 1 -C 4 alkoxy or hydroxy-C 1 -C 4 alkoxy; C 5 -C 8 cycloalkyl or C 5 -C 8 cycloalkyl substituted by C 1 -C 3 alkyl; or phenyl or phenyl substituted by C 1 -C 6 alkyl, C 1 -C 6 alkoxy, halogen, nitro, NHCO-C 1 -C 6 alkyl, --COO--C 1 --C 4 alkyl or --COO--C 1 --C 4 hydroxyalkyl; R 3 is hydrogen, cyano, or COOR 4 or CONR 5 R 6 , wherein R 4 is C 1 -C 10 alkyl or C 1 -C 10 alkyl substituted by hydroxy, phenoxy, alkoxy or hydroxyalkoxy or is C 5 -C 8 cycloalkyl, and R 5 and R 6 independently of one another are each hydrogen or C 1 -C 10 alkyl, R 7 is C 1 -C 10 alkyl or C 1 -C 10 alkyl substituted by hydroxy, C 1 -C 4 alkoxy, phenyl or phenyl substituted by C 1 -C 4 alkyl, halogen or nitro, phenyl-C 1 -C 3 alkoxy, phenyl-C 1 -C 3 alkylthio, phenoxy, lower alkanoyl, lower alkanoyloxy, --NR 8 R 9 or --.sup.⊕ NR 8 R 9 R 10 An.sup.⊖ wherein R 8 , R 9 and R 10 independently are C 1 -C 4 alkyl or phenyl-C 1 -C 4 alkyl and An.sup.⊖ is an anion, or COR 12 wherein R 12 is phenyl, C 1 -C 6 alkyl or C 1 -C 6 alkyl substituted by phenyl which is unsubstituted or substituted by C 1 -C 4 alkyl or halogen, and wherein the benzo radical A is not substituted or is substituted by halogen, hydroxy, C 1 -C 4 -alkoxy, hydroxy-C 1 -C 4 -alkoxy, phenoxy, C 1 -C 4 -alkylphenoxy, halophenoxy, nitro, amino, N-C 1 -C 4 -alkylamino, N,N-di-C 1 -C 4 -alkylamino, phenylamino, C 1 -C 4 -alkylphenylamino, C 1 -C 4 -alkoxyphenylamino or halophenylamino.
Claim 2
Dependent Claim
341 words
A 1,4-diaminoanthraquinone compound of the formula ##STR125## wherein R 1 and R 2 independently of one another are each hydrogen; C 1 -C 6 alkyl or C 1 -C 6 alkyl substituted by hydroxy, C 1 -C 4 alkoxy or hydroxy-C 1 -C 4 alkoxy; C 5 -C 8 cycloalkyl or C 5 -C 8 cycloalkyl substituted by C 1 -C 3 alkyl; or phenyl or phenyl substituted by C 1 -C 6 alkyl, C 1 -C 6 alkoxy, halogen, nitro, NHCO-C 1 -C 6 alkyl, --COO--C 1 --C 4 alkyl or --COO--C 1 --C 4 hydroxyalkyl; R 3 is hydrogen, cyano, or COOR 4 or CONR 5 R 6 , wherein R 4 is C 1 -C 10 alkyl or C 1 -C 10 alkyl substituted by hydroxy, phenoxy, alkoxy or hydroxyalkoxy or is C 5 -C 8 cycloalkyl, and R 5 and R 6 independently of one another are each hydrogen or C 1 -C 10 alkyl, R 7 is C 1 -C 10 alkyl or C 1 -C 10 alkyl substituted by hydroxy, C 1 -C 4 alkoxy, phenyl or phenyl substituted by C 1 -C 4 alkyl, halogen or nitro, phenyl-C 1 -C 3 alkoxy, phenyl-C 1 -C 3 alkylthio, phenoxy, lower alkanoyl, lower alkanoyloxy, --NR 8 R 9 or --.sup.⊕ NR 8 R 9 R 10 An.sup.⊖ wherein R 8 , R 9 and R 10 independently are C 1 -C 4 alkyl or phenyl-C 1 -C 4 alkyl and An.sup.⊖ is an anion, or COR 12 wherein R 12 is phenyl, C 1 -C 6 alkyl or C 1 -C 6 alkyl substituted by phenyl which is unsubstituted or substituted by C 1 -C 4 alkyl or halogen, and wherein the benzo radical A is not substituted or is substituted by halogen, hydroxy, C 1 -C 4 -alkoxy, hydroxy-C 1 -C 4 -alkoxy, phenoxy, C 1 -C 4 -alkylphenoxy, halophenoxy, nitro, amino, N-C 1 -C 4 -alkylamino, N,N-di-C 1 -C 4 -alkylamino, phenylamino, C 1 -C 4 -alkylphenylamino, C 1 -C 4 -alkoxyphenylamino or halophenylamino.
Claim 3
Dependent Claim
15 words
A 1,4-diaminoanthraquinone compound of claim 1, wherein R 1 and R 2 are each hydrogen.
Claim 4
Dependent Claim
13 words
A 1,4-diaminoanthraquinone compound of claim 1, wherein R 3 is the CN group.
Claim 5
Dependent Claim
26 words
A 1,4-diaminoanthraquinone compound of claim 1, wherein R 7 is either unsubstituted C 1 -C 4 -alkyl, or C 1 -C 4 -alkyl substituted by phenyl.
Claim 6
Dependent Claim
14 words
A 1,4-diaminoanthraquinone compound of claim 1, wherein the benzo radical A is not substituted.
Claim 7
Dependent Claim
76 words
A 1,4-diaminoanthraquinone compound of claim 1, wherein R 1 is hydrogen, R 2 is hydrogen, phenyl which is unsubstituted or substituted by C 1 -C 4 -alkyl, or it is C 1 -C 4 -alkyl, cyclohexyl or C 2 H 4 OCH 3 , R 3 is hydrogen or CN, and R 7 is C 1 -C 4 -alkyl, benzyl or CH 2 CH--CH 3 --O--COCH 3 and wherein the benzo radical A is not substituted.
Claim 8
Dependent Claim
30 words
The 1,4-diaminoanthraquinone compound of claim 1, wherein R 1 and R 2 are hydrogen, R 3 is cyano, R 7 is n-butyl, and the benzo radical A is not substituted.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-06-30 | 1989-12-30 | 1990-07-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-06-30 | 1993-12-30 | 1994-07-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-06-30 | 1997-12-30 | 1998-07-01 | $7700.00 | Window Closed / Lapsed |