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US4598020A Expired / Lapsed US ⏱️ 0.0 years remaining

Automotive paint compositions containing pearlescent pigments and dyes

Assignee: BASF Corp
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Filing: 1985-08-16
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Granted: 1986-07-01
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Expires: 2005-08-16
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Abstract

Abstract A transparent topcoat coating compositions is described comprising a thermosetting resin material containing a pigment composition and a soluble dye. The pigment composition contains about 40 weight percent to about 80 weight percent of iron oxide encapsulated mica particles. The composition also contains 0.5 weight percent to about 82.5 weight percent of a soluble 1:2 chrome or 1:2 cobalt metal organic complex dye. When used in a multi-coat coating process as a base coat overcoated with a transparent topcoat, an article is produced having improved pearlescent color effects, improved depth and clarity, and resistance to fade from ultraviolet light.

Inventors

  • 👤 Sol Panush

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 06:24
CPC Classifications
C; C09; C09D; C09D5/00; C09D5/36; C08; C08K; C08K9/00; C08K9/02; Y; Y10; Y10T; Y10T428/00; Y10T428/25; Y10T428/251; Y10T428/26; Y10T428/263; Y10T428/31504; Y10T428/31652; Y10T428/31678; Y10T428/31692; Y10T428/31971; Y10T428/31989

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 97 words
A pearlescent coating composition comprising thermoplastic or thermosetting resin containing about 1% to about 25% by weight of a pigment composition comprising about 5% to about 90% by weight of iron oxide encapsulated mica particles, wherein the improvement comprises the inclusion of about 0.5 weight percent to about 82.5 weight percent (of the pigment composition) in the coating of a metal organic complex dye selected from the group consisting of 1:2 cobalt metal organic complex dyes and 1:2 chrome metal organic complex dyes, the inclusion of such metal organic complex dyes resulting in a fade-free coating composition.
Claim 2
Dependent Claim 97 words
A pearlescent coating composition comprising thermoplastic or thermosetting resin containing about 1% to about 25% by weight of a pigment composition comprising about 5% to about 90% by weight of iron oxide encapsulated mica particles, wherein the improvement comprises the inclusion of about 0.5 weight percent to about 82.5 weight percent (of the pigment composition) in the coating of a metal organic complex dye selected from the group consisting of 1:2 cobalt metal organic complex dyes and 1:2 chrome metal organic complex dyes, the inclusion of such metal organic complex dyes resulting in a fade-free coating composition.
Claim 3
Dependent Claim 26 words
The coating composition of claim 1 wherein the pigment composition additionally comprises about 0.5 weight percent to about 18 weight percent of a metallic flake pigment.
Claim 4
Dependent Claim 52 words
The coating composition of claim 1 wherein the metal organic complex dye is selected from the group consisting of C.I. Solvent Yellow 88, C.I. Solvent Yellow 89, C.I. Solvent Yellow 25, C.I. Solvent Orange 11, C.I. Solvent Orange 59, C.I. Solvent Red 7, C.I. Solvent Violet 24, and C.I. Solvent Black 29.
Claim 5
Dependent Claim 13 words
The composition of claim 1 wherein the thermosetting resin is an acrylic resin.
Claim 6
Dependent Claim 118 words
A substrate material coated with at least two layers of polymer including a base coat comprising a pigmented thermosetting resin and a transparent topcoat on the base coat comprising a clear thermosetting or thermoplastic resin, the pigmented thermosetting resin comprising about 1% to about 25% by weight of a pigment composition comprising about 5% to about 90% by weight of iron oxide encapsulated mica particles, wherein the improvement comprises the inclusion of about 0.5 percent to about 82.5 percent by weight (of the pigment composition) of a metal organic complex dye selected from the group consisting of 1:2 chrome or 1:2 cobalt metal organic complex dye in the base coat resulting in a coating which is fade free.
Claim 7
Dependent Claim 118 words
A substrate material coated with at least two layers of polymer including a base coat comprising a pigmented thermosetting resin and a transparent topcoat on the base coat comprising a clear thermosetting or thermoplastic resin, the pigmented thermosetting resin comprising about 1% to about 25% by weight of a pigment composition comprising about 5% to about 90% by weight of iron oxide encapsulated mica particles, wherein the improvement comprises the inclusion of about 0.5 percent to about 82.5 percent by weight (of the pigment composition) of a metal organic complex dye selected from the group consisting of 1:2 chrome or 1:2 cobalt metal organic complex dye in the base coat resulting in a coating which is fade free.
Claim 8
Dependent Claim 26 words
The substrate material of claim 5 wherein the pigment composition additionally comprises about 0.5 weight percent to about 18 weight percent of a metallic flake pigment.
Claim 9
Dependent Claim 52 words
The substrate material of claim 5 wherein the metal organic complex dye is selected from the group consisting of C.I. Solvent Yellow 88, C.I. Solvent Yellow 89, C.I. Solvent Yellow 25, C.I. Solvent Orange 11, C.I. Solvent Orange 59, C.I. Solvent Red 7, C.I. Solvent Violet 24 and C.I. Solvent Black 29.
Claim 10
Independent Claim 134 words
A method of coating a substrate with multiple layers of polymer comprising applying at least one layer of a base coat of pigmented thermosetting resin to the substrate, applying at least one layer of a transparent thermosetting or thermoplastic topcoat on the base coat, and drying and curing the applied coatings, the pigmented thermosetting resin comprising about 1% to about 25% by weight of a pigment composition comprising about 5% to about 90% by weight of iron oxide encapsulated mica particles, wherein the improvement comprises the inclusion of about 0.5 weight percent to about 82.5 weight percent by weight (of the pigment composition) of a metal organic complex dye selected from the group consisting of 1:2 chrome and 1:2 cobalt metal organic complex dyes in the base coat resulting in a fade free coating.
Claim 11
Independent Claim 134 words
A method of coating a substrate with multiple layers of polymer comprising applying at least one layer of a base coat of pigmented thermosetting resin to the substrate, applying at least one layer of a transparent thermosetting or thermoplastic topcoat on the base coat, and drying and curing the applied coatings, the pigmented thermosetting resin comprising about 1% to about 25% by weight of a pigment composition comprising about 5% to about 90% by weight of iron oxide encapsulated mica particles, wherein the improvement comprises the inclusion of about 0.5 weight percent to about 82.5 weight percent by weight (of the pigment composition) of a metal organic complex dye selected from the group consisting of 1:2 chrome and 1:2 cobalt metal organic complex dyes in the base coat resulting in a fade free coating.
Claim 12
Dependent Claim 51 words
The method of claim 8 wherein the metal organic complex dye is selected from the group consisting of C.I. Solvent Yellow 88, C.I. Solvent Yellow 89, C.I. Solvent Yellow 25, C.I. Solvent Orange 11, C.I. Solvent Orange 59, C.I. Solvent Red 7, C.I. Solvent Violet 24 and C.I. Solvent Black 29.
Claim 13
Dependent Claim 25 words
The method of claim 8 wherein the pigment composition additionally comprises about 0.5 weight percent to aobut 18 weight percent of a metallic flake pigment.

References Cited (Backward Citations)

US3639147A Cited
US4146403A Cited
US4047969A Cited
US4551491A Cited
US4499143A Cited
US4487869A Cited
US4539238A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-06-30 1989-12-30 1990-07-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-06-30 1993-12-30 1994-07-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-06-30 1997-12-30 1998-07-01 $7700.00 Window Closed / Lapsed

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