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US4597161A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of making photoelectric conversion device

Assignee: Semiconductor Energy Laboratory Co Ltd
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Filing: 1985-04-11
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Granted: 1986-07-01
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Expires: 2005-04-11
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Abstract

Abstract A photoelectric conversion device in which a plurality n (n being an integer larger than one) of semiconductor elements U 1 to U n are sequentially formed on a substrate in a side-by-side relation and connected in series one after another. The substrate is formed by an insulating sheet-like member having an insulating film formed on a flexible metallic sheet-like member. The element U i (i=1, 2, . . . n) has a first electrode E i , a non-single-crystal semiconductor laminate member Q i formed on the first electrode E i and having formed therein at least one PN or PIN junction, and a second electrode F i formed on the semiconductor laminate member Q i . The element U i is formed by the following process: (a) a first conductive layer which will ultimately serve as the first electrode E i is formed on the substrate and then subjected to a first laser beam scanning, (b) a non-single-crystal semiconductor laminate member which will ultimately serve as the semiconductor laminate member Q i is formed to cover the first electrode E i and then subjected to a second laser beam scanning, (c) a second conductive layer which will ultimately serve as a second electrode F i is formed on the semiconductor laminate member Q i and then subjected to a third laser beam scanning.

Inventors

  • 👤 Shunpei Yamazaki

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 18:21
CPC Classifications
H; H10; H10F; H10F39/00; H10F39/10; H10F39/107; H10F19/00; H10F19/30; H10F19/31; H10F19/33; H10F39/12; H10F39/18; H10F77/00; H10F77/10; H10F77/16; H10F77/169; H10F77/1698; Y; Y02; Y02E; Y02E10/00; Y02E10/50; Y10; Y10S; Y10S438/00; Y10S438/94

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 409 words
A method of making a photoelectric conversion device, comprising the steps of: preparing a substrate formed by an insulating sheet-like member having a metallic sheet-like member and an insulating film having a thermal conductivity less than that of glass formed on the metallic sheet-like member; forming a first conductive layer on the insulating film of the substrate; forming n-1 (where n is an integer larger than 2) sequentially arranged first grooves G 1 to G n-1 in the first conductive layer by using a first laser beam to form n sequentially arranged first electrodes E 1 to E n separated by the first grooves G 1 to G n-1 , respectively; forming on the substrate a non-single-crystal semiconductor laminate layer having formed therein at least one semiconductor junction to cover the first grooves G 1 to G n-1 and the first electrodes E 1 to E n ; forming n-1 sequentially arranged second grooves O 1 to O n-1 in the non-single-crystal semiconductor laminate layer by using a second laser beam to form n sequentially arranged non-single-crystal semiconductor laminate members Q 1 to Q n defined by the second grooves O 1 to O n-1 , respectively, thereby to expose portions of the respective first electrodes E 1 to E n-1 to the outside, where the grooves O 1 to O n-1 do not extend to the metallic sheet-like member of the substrate due to the low thermal conductivity of the insulating film; forming a second conductive layer which continuously extends on the non-single-crystal semiconductor laminate members Q 1 to Q n and extends into the grooves O 1 to O n-1 to provide coupling portions K 1 to K n-1 which are connected to the first electrodes E 1 to E n-1 through the grooves O 1 to O n-1 , respectively, and; forming n-1 sequentially arranged isolating portions H 1 to H n-1 in the second conductive layer on the non-single-crystal semiconductor laminate members Q 1 to Q n-1 , respectively, to form n sequentially arranged second electrodes F 1 to F n which are isolated by the isolating portions H 1 to H n-1 , respectively, and opposite the first electrodes E 1 to E n through the non-single-crystal semiconductor laminate members Q 1 to Q n , respectively, the second electrode F j+1 (j=1, 2, 3, . . . (n-1) being connected to the first electrode E j through the coupling portion K j .
Claim 2
Independent Claim 409 words
A method of making a photoelectric conversion device, comprising the steps of: preparing a substrate formed by an insulating sheet-like member having a metallic sheet-like member and an insulating film having a thermal conductivity less than that of glass formed on the metallic sheet-like member; forming a first conductive layer on the insulating film of the substrate; forming n-1 (where n is an integer larger than 2) sequentially arranged first grooves G 1 to G n-1 in the first conductive layer by using a first laser beam to form n sequentially arranged first electrodes E 1 to E n separated by the first grooves G 1 to G n-1 , respectively; forming on the substrate a non-single-crystal semiconductor laminate layer having formed therein at least one semiconductor junction to cover the first grooves G 1 to G n-1 and the first electrodes E 1 to E n ; forming n-1 sequentially arranged second grooves O 1 to O n-1 in the non-single-crystal semiconductor laminate layer by using a second laser beam to form n sequentially arranged non-single-crystal semiconductor laminate members Q 1 to Q n defined by the second grooves O 1 to O n-1 , respectively, thereby to expose portions of the respective first electrodes E 1 to E n-1 to the outside, where the grooves O 1 to O n-1 do not extend to the metallic sheet-like member of the substrate due to the low thermal conductivity of the insulating film; forming a second conductive layer which continuously extends on the non-single-crystal semiconductor laminate members Q 1 to Q n and extends into the grooves O 1 to O n-1 to provide coupling portions K 1 to K n-1 which are connected to the first electrodes E 1 to E n-1 through the grooves O 1 to O n-1 , respectively, and; forming n-1 sequentially arranged isolating portions H 1 to H n-1 in the second conductive layer on the non-single-crystal semiconductor laminate members Q 1 to Q n-1 , respectively, to form n sequentially arranged second electrodes F 1 to F n which are isolated by the isolating portions H 1 to H n-1 , respectively, and opposite the first electrodes E 1 to E n through the non-single-crystal semiconductor laminate members Q 1 to Q n , respectively, the second electrode F j+1 (j=1, 2, 3, . . . (n-1) being connected to the first electrode E j through the coupling portion K j .
Claim 3
Dependent Claim 29 words
A method of making a photoelectric conversion device according to claim 1, wherein the formation of the grooves G 1 to G n-1 is carried out in the air.
Claim 4
Dependent Claim 57 words
A method of making a photoelectric conversion device according to claim 1, wherein the formation of the groove G 1 to G n-1 is carried out in an atmosphere of a gas or a liquid which reacts with the material of the first conductive layer at high temperature to spatter it from the surface of the substrate.
Claim 5
Dependent Claim 37 words
A method of making a photoelectric conversion device according to claim 3, wherein the gas is hydrogen fluoride, hydrogen chloride, or a Freon gas, and wherein the liquid is hydrofluoric acid, hydrochloric acid, or a Freon liquid.
Claim 6
Dependent Claim 73 words
A method of making a photoelectric conversion device according to claim 1, wherein the second groove O j (j=1, 2, . . . (n-1)) is formed a predetermined distance apart from the first groove G j but adjacent thereto, and wherein the isolating portion H j is formed a predetermined distance apart from the first groove G j and the second groove O j and adjacent to the second groove O j .
Claim 7
Dependent Claim 63 words
A method of making a photoelectric conversion device according to claim 1, wherein the second groove O j (j=1, 2, . . . (n-1)) is formed to extend through the first electrode E j so that the coupling portion K j may be connected with the side of the first electrode E j which is exposed by the second groove O j .
Claim 8
Dependent Claim 29 words
A method of making a photoelectric conversion device according to claim 1, wherein the formation of the grooves O 1 to O n-1 is carried out in the air.
Claim 9
Dependent Claim 58 words
A method of making a photoelectric conversion device according to claim 1, wherein the formation of the grooves O 1 to O n-1 is carried out in an atmosphere of a gas or a liquid which reacts with the material of the non-single-crystal semiconductor laminate member at high temperature to spatter it from the surface of the substrate.
Claim 10
Dependent Claim 37 words
A method of making a photoelectric conversion device according to claim 8, wherein the gas is hydrogen fluoride, hydrogen chloride, or a Freon gas, and wherein the liquid is hydrofluoric acid, hydrochloric acid, or a Freon liquid.
Claim 11
Dependent Claim 30 words
A method of making a photoelectric conversion device according to claim 1, wherein the formation of the isolating portions H 1 to H n-1 is carried out in the air.
Claim 12
Dependent Claim 57 words
A method of making a photoelectric conversion device according to claim 1, wherein the formation of the isolating H 1 to H n-1 is carried out in an atmosphere of a gas or a liquid which reacts with the material of the second conductive layer at high temperature to spatter it from the surface of the substrate.
Claim 13
Dependent Claim 37 words
A method of making a photoelectric conversion device according to claim 11, wherein the gas is hydrogen fluoride, hydrogen chloride, or a Freon gas, and wherein the liquid is hydrofluoric acid, hydrochloric acid, or a Freon liquid.
Claim 14
Dependent Claim 32 words
A method of making a photoelectric conversion device according to claim 1, wherein the formation of the isolating portions H 1 to H n-1 is carried out in an atmosphere of oxygen.
Claim 15
Dependent Claim 45 words
A method of making a photoelectric conversion device according to claim 1, wherein the formation of the isolating portions H 1 to H n-1 is carried out so that the isolating portion H j may extend into the non-single-crystal semiconductor laminate member Q j .
Claim 16
Dependent Claim 24 words
A method of making a photoelectric conversion device according to claim 1 where the thickness of said insulating film is 0.1 to 5 um.
Claim 17
Dependent Claim 30 words
A method of making a photoelectric conversion device according to claim 1 wherein said insulating film comprises an organic resinous material having a melting point less than that of glass.
Claim 18
Dependent Claim 36 words
A method of making a photoelectric conversion device according to claim 16 where said organic resinous material is selected from the group consisting of polyethylene terephthalate resins, polyimide resins, polyether sulfone resins, and polyether ketone resins.
Claim 19
Dependent Claim 21 words
A method of making a photoelectric conversion device according to claim 17 where said organic resinous material is a polyimide resin.

References Cited (Backward Citations)

US4334120A Cited
US4292092A Cited
US4315096A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-06-30 1989-12-30 1990-07-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-06-30 1993-12-30 1994-07-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-06-30 1997-12-30 1998-07-01 $7700.00 Window Closed / Lapsed

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