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US4595508A Expired / Lapsed US ⏱️ 0.0 years remaining

Reduction of sodium/ammonium alkalinity in industrial wastewater

Assignee: ExxonMobil Technology and Engineering Co
•
Filing: 1984-05-07
•
Granted: 1986-06-17
•
Expires: 2004-05-07
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Abstract

Abstract Industrial wastewater is contacted with a weak acid cation exchange resin, in the hydrogen ion form, to substantially reduce the sodium and ammonium alkalinity levels rendering the wastewater suitable, for example, as an environmentally acceptable cooling medium.

Inventors

  • 👤 Edward I. Wolfe
  • 👤 David H. Wasserstrom
  • 👤 Richard Kilpert

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 04:21
CPC Classifications
B; B01; B01J; B01J39/00; B01J39/04; B01J39/07

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 73 words
A process for reducing sodium and ammonium alkalinity of wastewater comprising the step of contracting said wastewater, possessing a sodium alkalinity/ammonium alkalinity greater than 1.0, and a hardness/alkalinity ratio less than 1.0, with a weak acid cation exchange resin, in hydrogen ion form, and continuing said contacting for a time sufficient to reduce the sum of said resulting sodium alkalinity and said ammonium alkalinity to about 10 mg./l as CaCO 3 or less.
Claim 2
Dependent Claim 73 words
A process for reducing sodium and ammonium alkalinity of wastewater comprising the step of contracting said wastewater, possessing a sodium alkalinity/ammonium alkalinity greater than 1.0, and a hardness/alkalinity ratio less than 1.0, with a weak acid cation exchange resin, in hydrogen ion form, and continuing said contacting for a time sufficient to reduce the sum of said resulting sodium alkalinity and said ammonium alkalinity to about 10 mg./l as CaCO 3 or less.
Claim 3
Dependent Claim 14 words
The process of claim 1 wherein said sodium alkalinity is reduced by about 70%.
Claim 4
Dependent Claim 14 words
The process of claim 1 wherein said ammonium alkalinity is reduced by about 80%.
Claim 5
Dependent Claim 14 words
The process of claim 1 wherein said resin is an acrylic acid-divinylbenzene crosslinked copolymer.
Claim 6
Dependent Claim 22 words
The process of claim 1 wherein said wastewater is initially biologically treated and filtered to reduce the amount of organic materials present.
Claim 7
Dependent Claim 21 words
The process of claim 1 wherein said resulting wastewater is sufficient for use as makeup cooling water in an industrial process.
Claim 8
Dependent Claim 19 words
The process of claim 1 wherein the resulting ammonium alkalinity is about 3 mg./l as CaCO 3 or less.
Claim 9
Dependent Claim 19 words
The process of claim 1 wherein said treated wastewater further contains about 1000 ppm or less total dissolved solids.
Claim 10
Dependent Claim 87 words
A process for reducing sodium and ammonium alkalinity in biologically treated and filtered wastewater comprising the step of contacting said wastewater, containing a sodium alkalinity/ammonium alkalinity ratio greater than 1.0 and a hardness/total alkalinity ratio less than 1.0, with a weak acid cation exchange resin in hydrogen ion form, and continuing said contacting for a time sufficient to reduce the combined sodium and ammonium alkalinity to about 10 mg/l as CaCO 3 , or less, and the ammonium alkalinity to about 3mg/l as CaCO 3 or less.
Claim 11
Dependent Claim 87 words
A process for reducing sodium and ammonium alkalinity in biologically treated and filtered wastewater comprising the step of contacting said wastewater, containing a sodium alkalinity/ammonium alkalinity ratio greater than 1.0 and a hardness/total alkalinity ratio less than 1.0, with a weak acid cation exchange resin in hydrogen ion form, and continuing said contacting for a time sufficient to reduce the combined sodium and ammonium alkalinity to about 10 mg/l as CaCO 3 , or less, and the ammonium alkalinity to about 3mg/l as CaCO 3 or less.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-06-16 1989-12-16 1990-06-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-06-16 1993-12-16 1994-06-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-06-16 1997-12-16 1998-06-17 $7700.00 Window Closed / Lapsed

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