Low temperature laminatable polyurethane

Claim 2

A light transmitting article capable of transmitting at least 8% of visible light comprising (i) a layer of cured polyurethane, sandwiched between (ii) a layer of a first material and (iii) a layer of a second material, where the first and second materials can be the same or different, and are selected from the group consisting of light transmitting glass, plastic, and ceramic; the polyurethane having been cured prior to being sandwiched between the first and second materials by a curing reaction which is carried out essentially in the absence of aromatic amines, the polyurethane having a Shore A hardness of at least about 60, and being capable of laminating to the other two layers at a lamination temperature below 150° F. and a pressure below 200 psig so that the article does not delaminate at romm temperature at 2 pli.

Claim 3

The laminated article of claim 1, further comprising primer between the polyurethane layer and one of the two other layers.

Claim 4

The laminated article of claim 1 capable of transmitting at least 50% of visible light.

Claim 5

The laminated article of claim 1 capable of transmitting at least 85% of visible light.

Claim 6

The laminated article of claim 1 wherein the polyurethane layer: (a) is capable of transmitting at least about 90% of visible light; (b) has an index of refraction between about 1.4 and about 1.6; (c) a 100% modulus of from about 300 to about 800 psi; (d) a 300% modulus of from about 1,000 to about 2,000 psi; (e) a tensile strength at break of from about 3,000 to about 7,000 psi; and (f) an elongation at break of from about 400 to about 700%.

Claim 7

The article of claim 1 wherein the polyurethane is thermoplastic.

Claim 8

The article of claim 1 wherein the article delaminates at 160° F. at a rate of less than 1 inch per hour at 12 pli.

Claim 9

The laminated article of claim 1 where the coefficient of thermal expansion of the first material is at least about five times the coefficient of thermal expansion of the second material within the temperature range of from 100° F. to 200° F.

Claim 10

The laminated article of claim 8, where the first material is glass and the second material is polycarbonate.

Claim 11

The article of claim 8 wherein the article is curved.

Claim 12

The article of claim 8 wherein the article is flat and consists essentially of only the three layers.

Claim 13

The article of claim 11 no more than about 1/4 inch in thickness.

Claim 14

The laminated article of claim 1 where the polyurethane is prepared by reacting in the presence of a urethane-forming catalyst: (a) a high molecular weight polyether glycol or polyester glycol melting below 120° F., and having a molecular weight of from about 500 to about 3,000; (b) at least two diols, (i) a first diol having a molecular weight of from about 60 to about 250, the first diol being symmetrical, and (ii) a second diol having a molecular weight of from about 60 to about 250, the second diol being different from the first diol; and (c) diisocyanate in an amount substantially equivalent to the equivalents of (a)+(b); wherein from about 30 to about 60% of the functional --OH groups are provided by the glycol.

Claim 15

The article of claim 13 wherein from about 40 to about 70% of the functional --OH groups come from the with the second diol providing from about 10 to about 60% of the total --OH groups provided by the two diols.

Claim 16

The article of claim 13 where the diols are both reinforcing and differ in molecular weight by at least 14.

Claim 17

The laminated article of claim 13 the high molecular weight glycol is a polyether glycol having a molecular weight of from about 950 to about 1050, a hydroxyl number of from about 107 to about 118, an APHA color of less than 40, an alkalinity number of less than 1 meq. KOH/kg×30, an acid no. (hot) of less than 0.05 mg KOH/g, and water content of less than 0.03 wt. %, the first diol is 1,4-butanediol, the second diol is ethylene glycol, and the diisocyanate is methylene bis (4-cyclohexylisocyanate).

Claim 18

The article of claim 13 where the equivalent amounts of the glyco:first diol:second diol:diisocyanate are about 1:1:0.6:2.6.

Claim 19

A flat light transmitting article capable of transmitting at least 50% of visible light consisting essentially of three layers: a layer of cured polyurethane, sandwiched between a layer of a first material and a layer of a second material, where the first and second materials are different, and are selected from the group consisting of glass and plastic; the coefficient of thermal expansion of the first material is at least about five times the coefficient of thermal expansion of the second material within the temperature range of from 100° F. to 200° F.; the polyrethane having been cured prior to being sandwiched between the first and second materials by a curing reaction which is carried out essentially in the absence of aromatic amines, the polyurethane having a Shore A hardness of at least about 70, and being capable of laminating to the other two layers at a lamination temperature below 150° F. and a pressure below 200 psig so that the article does not delaminate at room temperature at 2 pli; the polyurethane being prepared by reacting in the presence of a urethane-forming catalyst; (a) a high molecular weight polyether glycol or polyester glycol melting below 120° F., and having a molecular weight of from about 500 to about 3,000; (b) a first symmetrical diol having a molecular weight of from about 74 to about 250; (c) a second symmetrical diol having a molecular weight of from about 60 to about 236, the molecular weight of the second diol being at least about 14 less than the molecular weight of the first diol; and (d) an aliphatic diisocyanate in an amount substantially equivalent to the equivalent of (a)+(b)+(c); the proportions of (a), (b), and (c) being such that from about 30 to about 60% of the functional --OH groups come from the polyether glycol or polyester (a), and from about 40 to about 70% from the two diols (b) and (c), with the second diol (c) providing from about 30 to about 50% of the total --OH groups provided by the two diols.

Claim 20

A flat light transmitting article capable of transmitting at least 50% of visible light consisting essentially of three layers: a layer of cured polyurethane, sandwiched between a layer of a first material and a layer of a second material, where the first and second materials are different, and are selected from the group consisting of glass and plastic; the coefficient of thermal expansion of the first material is at least about five times the coefficient of thermal expansion of the second material within the temperature range of from 100° F. to 200° F.; the polyrethane having been cured prior to being sandwiched between the first and second materials by a curing reaction which is carried out essentially in the absence of aromatic amines, the polyurethane having a Shore A hardness of at least about 70, and being capable of laminating to the other two layers at a lamination temperature below 150° F. and a pressure below 200 psig so that the article does not delaminate at room temperature at 2 pli; the polyurethane being prepared by reacting in the presence of a urethane-forming catalyst; (a) a high molecular weight polyether glycol or polyester glycol melting below 120° F., and having a molecular weight of from about 500 to about 3,000; (b) a first symmetrical diol having a molecular weight of from about 74 to about 250; (c) a second symmetrical diol having a molecular weight of from about 60 to about 236, the molecular weight of the second diol being at least about 14 less than the molecular weight of the first diol; and (d) an aliphatic diisocyanate in an amount substantially equivalent to the equivalent of (a)+(b)+(c); the proportions of (a), (b), and (c) being such that from about 30 to about 60% of the functional --OH groups come from the polyether glycol or polyester (a), and from about 40 to about 70% from the two diols (b) and (c), with the second diol (c) providing from about 30 to about 50% of the total --OH groups provided by the two diols.

Claim 21

A process for making a light transmitting laminate capable of transmitting at least 8% of visible light comprising: (a) selecting a sheet of a first material and a sheet of a second material, where the first material and the second material can be the same or different, and are selected from the group consisting of light transmitting glass, plastic, and ceramic; (b) sandwiching a sheet of cured polyurethane between the two sheets, the polyurethane having been cured prior to being sandwiched between the two sheets by a curing reaction which is carried out essentially in the absence of aromatic amines, the polyurethane having a shore A hardness of at least 60, and being capable of laminating at a temperature of below about 150° F. and a pressure of below 200 psig so that the laminate does not delaminate at room temperature at 2 pli; and (c) maintaining the stack at a temperature of less than 150° F. and a pressure of at least 50 psig for a sufficient time to form the laminate.

Claim 22

A process for making a light transmitting laminate capable of transmitting at least 8% of visible light comprising: (a) selecting a sheet of a first material and a sheet of a second material, where the first material and the second material can be the same or different, and are selected from the group consisting of light transmitting glass, plastic, and ceramic; (b) sandwiching a sheet of cured polyurethane between the two sheets, the polyurethane having been cured prior to being sandwiched between the two sheets by a curing reaction which is carried out essentially in the absence of aromatic amines, the polyurethane having a shore A hardness of at least 60, and being capable of laminating at a temperature of below about 150° F. and a pressure of below 200 psig so that the laminate does not delaminate at room temperature at 2 pli; and (c) maintaining the stack at a temperature of less than 150° F. and a pressure of at least 50 psig for a sufficient time to form the laminate.

Claim 23

The process of claim 19 where the laminate is capable of transmitting at least 85% of visible light.

Claim 24

The process of claim 19 where the laminate is no more than about 1/4 inch in thickness.

Claim 25

The process of claim 19 where the coefficient of thermal expansion of the first material is at least about five times the coefficient of thermal expansion of the second material within the temperature range of from 100° F. to 200° F.

Claim 26

The process of claim 19 wherein the laminate delaminates at 160° F. at a rate of less than 1 inch per hour at 12 pli.

Claim 27

The process of claim 19 where the polyurethane is prepared by reacting in the presence of a urethane-forming catalyst: (a) a high molecular weight polyether glycol or polyester glycol melting below 120° F., and having a molecular weight of from about 500 to about 3,000; (b) at least two diols, (i) a first diol having a molecular weight of from about 60 to about 250, the first diol being symmetrical, and (ii) a second diol having a molecular weight of from about 60 to about 250, the second diol being different from the frist diol; and (c) diisocyanate in an amount substantially equivalent to the equivalents of (a)+(b); wherein from about 30 to about 60% of the functional --OH groups come from the glycol.

Claim 28

The process of claim 24 in from about 40 to about 70% of the functional --OH groups come from the diols and with the second providing from about 10 to about 60% of the total --OH groups provided by the two diols.

Claim 29

The process of claim 24 where the diols are both reinforcing and differ in molecular wieght by at least 14.