Photopolymerizable recording material and the production of relief plates using this recording material

Claim 2

A photopolymerizable recording material comprising a base A, a photopolymerizable layer B which is soluble or at least dispersible in an alcohol or alcoholic solution, and a top layer C which is soluble in the alcohol or alcoholic solution and/or a cover sheet which can be striped off the photopolymerizable layer B, the photopolymerizable layer B comprising (1) a polymeric binder, (2) at least one photopolymerizable, ethylenically unsaturated, low molecular weight compound, and (3) a photopolymerization initiator, wherein the photopolymerizable layer B contains, as the binder (component B1), a substantially linear, high molecular weight, thermoplastic polyurethane which is solid at room temperature, contains acryloyl and/or methacryloyl groups as side groups, does not possess any quaternary and/or quaternizable nitrogen atoms, and is obtained by reacting a mixture of (a) from 15 to 30% by weight of a diisocyanate, (b) from 50 to 80% by weight of at least one polyether-diol, having a molecular wieght of from 250 to 4,000 and selected from the group consisting of polyethylene glycol, polypropylene glycol and ethyleneglycol/propyleneglycol co-polycondensates or mixtures of at least 50% by weight of at least one of the said polyether-diols and up to 50% by weight of at least one further compatible polydiol, (c) from 0.5 to 15% by weight of a chain-extending compound which is bifunctionally reactive towards isocyanates and possesses acryloyl and/or methacryloyl groups in side branches, and (d) from 1 to 10% by weight of another low molecular weight chain extender, each of the above percentages of the components of the reation mixture being based on the sum of the components (a), (b), (c), and (d), and the NCO/OH plus NH molar ratio provided by the reactants being from about 0.8 to 1.3.

Claim 3

A photopolymerizable recording material as set forth in claim 1, wherein the photopolymerizable layer B also contains one or more additives selected from the group consisting of thermal polymerization inhibitors, inorganic or organic pigments or dyes, inorganic or organic fillers, plasticizers, dulling agents and lubricants.

Claim 4

A photopolymerizable recording material as set forth in claim 1, wherein the polyurethane used as component (B1) has a K value of from about 25 to 75.

Claim 5

A photopolymerizable recording material as set forth in claim 1, wherein the polyurethane used as component (B1) contains from 0.01 to 2.5% by weight, based on the weight of polyurethane, of photopolymerizable double bonds in side branches.

Claim 6

The polymerizable recording material of claim 1, wherein the low molecular weight chain extender (d) is selected from the group consisting of ethylene glycol and its condensates, butanediol, propane-1,2-diol, propane-1,3-diol, neopentylglycol, hexane-1,6-diol, decane-1,10-diol, dihydroxyethoxyhydroquinone, butenediol, dimethylolnorbornene and dimethylolcyclohexene.

Claim 7

A photopolymerizable recording material as set forth in claim 1 or 2, wherein the photopolymerizable layer B contains (1) from 50 to 95% by weight, based on components B1 and B2, of the polymeric binder, (2) from 50 to 5% by weight, based on components B1 and B2, of the photopolymerizable, ethylenically unsaturated, low molecular weight compound, (3) from 0.02 to 5% by weight, based on the total layer B, of the photopolymerization initiator, and (4) from 0 to 30% by weight, based on the total layer B, of additives.

Claim 8

A process for the production of a relief plate which comprises: exposing a photopolymerizable layer B of a photopolymerizable recording material to actinic light through an image, and layer B being soluble or at least dispersible in an alcohol or alcohol solution, said layer B comprising (1) a polymeric binder, (2) at least one photopolymerizable ethylenically unsaturated, low molecular weight compound and (3) a photopolymerization initiator, wherein the photopolymerizable layer B contains, as the binder (component B1) a substantially linear, high molecular weight, thermoplastic polyurethane which is solid at room temperature, contains acryloyl and/or methacryloyl groups as side groups, does not possess any quaternary and/or quaternizable nitrogen atoms, and is obtained by reactig a mixture of (a) from 15 to 30% by weight of a diisocyanate, (b) from 50 to 80% by weight of a polydiol consisting essentially of from 50 to 100% by weight, based on the polydiol component (b), of at least one polyether-diol, having a molecular weight of from 250 to 4,000 from the group consisting of polyethylene glycol, polypropylene glycol and ethyleneglycol/propylene glycol co-polycondensates, and from 0 to 50% by weight, based on the polydiol component (b), of at least one further compatible polydiol. (c) from 0.5 to 15% by weight of a chain-extending compound which is bifunctionally reacting towards isocyanates and possesses acryloyl and/or methacryloyl groups in side branches, and (d) from 1 to 10% by weight of another low molecular weight extender, each of the above percentages of the components of the reaction mixture being based on the sum of the components (a), (b), (c), and (d), and the NCO/OH plus NH molar ratio provided by the reactants being from about 0.8 to 1.3; washing out the unexposed, non-crosslinked areas of the photopolymerizable layer B with a developer, and thereafter drying the resulting relief plate.

Claim 9

A process for the production of a relief plate which comprises: exposing a photopolymerizable layer B of a photopolymerizable recording material to actinic light through an image, and layer B being soluble or at least dispersible in an alcohol or alcohol solution, said layer B comprising (1) a polymeric binder, (2) at least one photopolymerizable ethylenically unsaturated, low molecular weight compound and (3) a photopolymerization initiator, wherein the photopolymerizable layer B contains, as the binder (component B1) a substantially linear, high molecular weight, thermoplastic polyurethane which is solid at room temperature, contains acryloyl and/or methacryloyl groups as side groups, does not possess any quaternary and/or quaternizable nitrogen atoms, and is obtained by reactig a mixture of (a) from 15 to 30% by weight of a diisocyanate, (b) from 50 to 80% by weight of a polydiol consisting essentially of from 50 to 100% by weight, based on the polydiol component (b), of at least one polyether-diol, having a molecular weight of from 250 to 4,000 from the group consisting of polyethylene glycol, polypropylene glycol and ethyleneglycol/propylene glycol co-polycondensates, and from 0 to 50% by weight, based on the polydiol component (b), of at least one further compatible polydiol. (c) from 0.5 to 15% by weight of a chain-extending compound which is bifunctionally reacting towards isocyanates and possesses acryloyl and/or methacryloyl groups in side branches, and (d) from 1 to 10% by weight of another low molecular weight extender, each of the above percentages of the components of the reaction mixture being based on the sum of the components (a), (b), (c), and (d), and the NCO/OH plus NH molar ratio provided by the reactants being from about 0.8 to 1.3; washing out the unexposed, non-crosslinked areas of the photopolymerizable layer B with a developer, and thereafter drying the resulting relief plate.

Claim 10

A process for producing a relief plate as set forth in claim 7, wherein the polyurethane used as component (B1) has a K value of from about 25 to 75.

Claim 11

A process for producing a relief plate as set forth in claim 7, wherein the polyurethane used as component (B1) contains from 0.01 to 2.5% by weight, based on the weight of polyurethane, of photopolymerizable double bonds in side branches.

Claim 12

A process for producing a relief plate as set forth in claim 7, wherein the photopolymerizable layer B contains (1) from 50 to 95% by weight, based on components B1 and B2, of the polymeric binder, (2) from 50 to 5% by weight, based on components B1 and B2, of the photopolymerizable, ethylenically unsaturated, low molecular weight compound, (3) from 0.02 to 5% by weight, based on the total layer B, of the photopolymerization initiator, and (4) from 0 to 30% by weight, based on the total layer B, of additives.

Claim 13

The process of claim 7, wherein the low molecular weight chain extender (d) is selected from the group consisting of ethylene glycol and its condensates, butanediol, propane-1,2-diol, propane-1,3-diol, neopentylglycol, hexane-1,6-diol, decane-1,10-diol, dihydroxyethoxyhydroquinone, butenediol, dimethylolnorbornene and dimethylolcyclohexene.

Claim 14

A photopolymerizable recording material for the production of elastomeric relief printing plates, comprising a base A wherein said base is a metal or high-polymer sheet and a photopolymerizable layer B which is soluble or at least dispersible in an alcohol or alcoholic solution and comprises (1) a polymeric binder, (2) at least one photopolymerizable ethylenically usaturated, low molecular weight compound and (3) a photopolymerization initiator, wherein the photopolymerizable layer B contains, as the binder (component B1) a substantially linear, high molecular weight, thermoplastic polyurethane which is solid at room temperature, contains acryloyl and/or methacryloyl groups as side groups, does not possess any quaternary and/or quaternizable nitrogen atoms, and is obtained by reacting a mixture of (a) from 15 to 30% by weight of a diisocyanate, (b) from 50 to 80% by weight of a polydiol consisting essentially of from 50 to 100% by weight, based on the polydiol component (b), of at least one polyether-diol, having a molecular weight of from 250 to 4,000 from the group consisting of polyethylene glycol, polypropylene glycol and ethyleneglycol/propylene glycol co-polycondensates, or mixtures of at least 50% by weight of at least one of the said polyether-diols and up to 50% by weight of at least one further compatible polydiol, (c) from 0.5 to 15% by weight of a chain-extending compound which is bifunctionally reactive towards isocyanates and possesses acryloyl and/or methacryloyl groups in side branches, and (d) from 1 to 10% by weight of another low molecular weight chain extender, each of the above percentages of the components of the reaction mixture being based on the sum of the components (a), (b), (c), and (d), and the NCO/OH plus NH molar ratio provided by the reactants being from about 0.8 to 1.3.

Claim 15

A photopolymerizable recording material for the production of elastomeric relief printing plates, comprising a base A wherein said base is a metal or high-polymer sheet and a photopolymerizable layer B which is soluble or at least dispersible in an alcohol or alcoholic solution and comprises (1) a polymeric binder, (2) at least one photopolymerizable ethylenically usaturated, low molecular weight compound and (3) a photopolymerization initiator, wherein the photopolymerizable layer B contains, as the binder (component B1) a substantially linear, high molecular weight, thermoplastic polyurethane which is solid at room temperature, contains acryloyl and/or methacryloyl groups as side groups, does not possess any quaternary and/or quaternizable nitrogen atoms, and is obtained by reacting a mixture of (a) from 15 to 30% by weight of a diisocyanate, (b) from 50 to 80% by weight of a polydiol consisting essentially of from 50 to 100% by weight, based on the polydiol component (b), of at least one polyether-diol, having a molecular weight of from 250 to 4,000 from the group consisting of polyethylene glycol, polypropylene glycol and ethyleneglycol/propylene glycol co-polycondensates, or mixtures of at least 50% by weight of at least one of the said polyether-diols and up to 50% by weight of at least one further compatible polydiol, (c) from 0.5 to 15% by weight of a chain-extending compound which is bifunctionally reactive towards isocyanates and possesses acryloyl and/or methacryloyl groups in side branches, and (d) from 1 to 10% by weight of another low molecular weight chain extender, each of the above percentages of the components of the reaction mixture being based on the sum of the components (a), (b), (c), and (d), and the NCO/OH plus NH molar ratio provided by the reactants being from about 0.8 to 1.3.

Claim 16

The photopolymerizable recording material of claim 12, wherein the low molecular weight chain extender (d) is selected from the group consisting of ethylene glycol and its condensates, butanediol, propane-1,2-diol, propane-1,3-diol, neopentylglycol, hexane-1,6-diol, decane-1,10-diol, dihydroxyethoxyhydroquinone, butenediol, dimethylolnorbornene and dimethylolcyclohexane.