US4588775A
Expired / Lapsed
US
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High toughness propylene polymer compositions
Assignee: Union Carbide Chemicals and Plastics Technology LLC
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Filing: 1984-06-22
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Granted: 1986-05-13
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Expires: 2004-06-22
Abstract
Abstract Blends of sequentially polymerized ethylene-propylene copolymers, high density ethylene homopolymers, EPM or EPDM rubber and linear low density polyethylene possess extremely good impact resistance.
Inventors
- 👤 J. Douglas McCullough, Jr.
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 02:58
CPC Classifications
C; C08; C08L; C08L23/00; C08L23/02; C08L23/10; C08L53/00; C08L2205/00; C08L2205/03; C08L2205/035; C08L23/04; C08L23/06; C08L23/08; C08L23/0807; C08L23/0815; C08L23/16; C08L2310/00; C08L2312/00; C08L2314/00; C08L2314/02
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
264 words
A composition having a melt flow between about 0.5 and about 30 dg/min (ASTM D1238-Condition L), and a high notched impact value, said composition being obtained by blending in the absence of a peroxide 50-96% by weight of an impact-improved propylene-ethylene copolymer, 2 to 45% by weight of a high density ethylene homopolymer, 2-45% by weight of a linear low density ethylene copolymer and 0 to 30% by weight of a rubber selected from the group consisting of ethylene-propylene rubber and ethylene-propylene-diene monomer rubber, wherein: (a) said impact-improved propylene-ethylene copolymer has a melt flow (ASTM D1238-Condition L) of about 0.5 to 30 dg/min and an elastomeric propylene-ethylene copolymer content of 5-50% by weight, the copolymer fraction having an ethylene content of 30-95% by weight, which propylene-ethylene copolymer is the product of sequential polymerization of propylene and a propylene-ethylene mixture over a titanium halide-containing coordination catalyst; (b) said high density ethylene homopolymer has a density in the range from 0.941 to 0.965 g/cc and a melt index (ASTM D1238 Cond. E) in the range from 0 to 20 dg/min; (c) said linear low density ethylene copolymer is the product of polymerization of ethylene with up to 15 mole percent of at least one C 3 -C 8 alpha olefin monomer over a transition metal-based coordination catalyst and which has a density in the range from 0.912 to 0.935 g/cc and a melt index (ASTM D 1238-Condition E) in the range from 0.1 to 16; and (d) the weight ratio of high density ethylene homopolymer to linear low density ethylene copolymer is between 80:20 and 20:80.
Claim 2
Dependent Claim
264 words
A composition having a melt flow between about 0.5 and about 30 dg/min (ASTM D1238-Condition L), and a high notched impact value, said composition being obtained by blending in the absence of a peroxide 50-96% by weight of an impact-improved propylene-ethylene copolymer, 2 to 45% by weight of a high density ethylene homopolymer, 2-45% by weight of a linear low density ethylene copolymer and 0 to 30% by weight of a rubber selected from the group consisting of ethylene-propylene rubber and ethylene-propylene-diene monomer rubber, wherein: (a) said impact-improved propylene-ethylene copolymer has a melt flow (ASTM D1238-Condition L) of about 0.5 to 30 dg/min and an elastomeric propylene-ethylene copolymer content of 5-50% by weight, the copolymer fraction having an ethylene content of 30-95% by weight, which propylene-ethylene copolymer is the product of sequential polymerization of propylene and a propylene-ethylene mixture over a titanium halide-containing coordination catalyst; (b) said high density ethylene homopolymer has a density in the range from 0.941 to 0.965 g/cc and a melt index (ASTM D1238 Cond. E) in the range from 0 to 20 dg/min; (c) said linear low density ethylene copolymer is the product of polymerization of ethylene with up to 15 mole percent of at least one C 3 -C 8 alpha olefin monomer over a transition metal-based coordination catalyst and which has a density in the range from 0.912 to 0.935 g/cc and a melt index (ASTM D 1238-Condition E) in the range from 0.1 to 16; and (d) the weight ratio of high density ethylene homopolymer to linear low density ethylene copolymer is between 80:20 and 20:80.
Claim 3
Dependent Claim
17 words
The composition according to claim 1 wherein said linear low density ethylene copolymer is an ethylene-1-butene copolymer.
Claim 4
Dependent Claim
25 words
The composition according to claim 1 wherein said sequential propylene-ethylene copolymer has a melt flow (ASTM D1238 Cond. L) between about 4 and 12 dg/min.
Claim 5
Dependent Claim
27 words
The composition according to claim 1 wherein said linear low density ethylene copolymer has a melt index (ASTM D1238 Cond. E) between about 1 and 7 dg/min.
Claim 6
Dependent Claim
22 words
The composition according to claim 1 wherein said linear low density ethylene copolymer has a density between about 0.917 and 0.925 g/cc.
Claim 7
Dependent Claim
25 words
The composition according to claim 1 wherein said rubber is an ethylene-propylene rubber or an ethylene-propylene-diene monomer rubber comprising 30 to 85 weight percent ethylene.
Claim 8
Dependent Claim
30 words
The composition according to claim 1 wherein the linear low density polyethylene, high density polyethylene and optionally an ethylene-propylene or ethylene-propylene-diene rubber are pre-combined by melt mixing into a masterbatch.
Claim 9
Dependent Claim
23 words
The composition according to claim 7 wherein the masterbatch is partially crosslinked with a peroxide prior to blending with said sequential propylene-ethylene copolymer.
Claim 10
Dependent Claim
28 words
The composition according to claim 8 wherein the amount of peroxide employed is between about 150 and 1500 parts by weight per million parts by weight of masterbatch.
Claim 11
Dependent Claim
11 words
The composition according to claim 8 wherein said peroxide is 2,5-dimethyl-2,5-bis(t-butylperoxy)hexane.
Claim 12
Dependent Claim
21 words
The composition according to claim 8 wherein said peroxide-contacting takes place at a temperature between about 190° C. and 260° C.
Claim 13
Dependent Claim
19 words
The composition according to claim 1 wherein said high density polyethylene has a density between about 0.955 and 0.965.
Claim 14
Dependent Claim
25 words
The composition according to claim 7 wherein the masterbatch is treated with a dimethyl-polysiloxane fluid at about 1%w based on the weight of masterbatch polyethylene.
Claim 15
Dependent Claim
23 words
The composition according to claim 1 wherein the melt index of said high density ethylene homopolymer is between about 0.1 and about 3.
Claim 16
Dependent Claim
25 words
The composition according to claim 1 wherein the elastomeric propylene-ethylene content of said impact-improved propylene-ethylene copolymer is between about 15 and about 20 weight percent.
Claim 17
Dependent Claim
22 words
The composition according to claim 15 wherein the melt flow of said impact-improved propylene-ethylene copolymer is between about 0.5 and about 12.
Claim 18
Dependent Claim
48 words
The composition according to claim 1 wherein the relative amounts of each component are: 75 to 90% by weight impact-improved ethylene-propylene copolymer; 3 to 20% by weight high density ethylene homopolymer; 5 to 20% by weight linear low density ethylene copolymer; and 2 to 8% by weight rubber.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-05-12 | 1989-11-11 | 1990-05-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-05-12 | 1993-11-11 | 1994-05-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-05-12 | 1997-11-11 | 1998-05-13 | $7700.00 | Window Closed / Lapsed |