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US4587324A Expired / Lapsed US ⏱️ 0.0 years remaining

Polymer of phosphonylmethyl-2,4-and -2,6-diamino benzene and polyfunctional monomer

Assignee: National Aeronautics and Space Administration
•
Filing: 1984-08-16
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Granted: 1986-05-06
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Expires: 2004-08-16
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Abstract

Abstract Compounds having the general formula 1 <IMAGE> 1 wherein X and Y are functional groups, preferably amino groups, are polymerized with, for example, polyfunctional epoxides to provide heat and fire resistant polymers useful for making flame and fire resistant polymer structures such as for aircraft secondary structures. The groups R in 1 are preferably alkyl and lower halo (e.g., chloro) alkyl.

Inventors

  • 👤 John A. Mikroyannidis
  • 👤 Demetrius A. Kourtides

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 14:09
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/06; C08G73/10; C08G73/1067; C08G73/1042; C08G73/1057; C08G73/1064

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 46 words
A method of producing a phosphorus-containing polymer which comprises polymerizing a compound of the formula: ##STR23## with a polyfunctional monomer, R being an organic group attached to the oxygen atom through a carbon atom and X and Y are functional groups polymerizable with the polyfunctional monomer.
Claim 2
Independent Claim 46 words
A method of producing a phosphorus-containing polymer which comprises polymerizing a compound of the formula: ##STR23## with a polyfunctional monomer, R being an organic group attached to the oxygen atom through a carbon atom and X and Y are functional groups polymerizable with the polyfunctional monomer.
Claim 3
Dependent Claim 23 words
The method of claim 1 wherein X and Y are amino groups in the 2,4-position, 2,6-position or mixtures of the 2,4- and 2,6-positions.
Claim 4
Dependent Claim 18 words
The method of claim 2 wherein the polyfunctional monomer is a 1,2-epoxide having at least two 1,2-epoxy groups.
Claim 5
Dependent Claim 13 words
The method of claim 2 wherein R is a halogen-containing lower alkyl group.
Claim 6
Dependent Claim 13 words
The method of claim 3 wherein R is a halogen-containing lower alkyl group.
Claim 7
Dependent Claim 58 words
The method of claim 1 of producing a phosphorus-containing polymer which comprises polymerizing a compound of the formula: ##STR24## wherein R is an organic group attached to the oxygen atom through a carbon atom and is the same or different, and X and Y are both amino with a polyfunctional organic monomer wherein the monomer is a di-1,2-epoxide.
Claim 8
Dependent Claim 39 words
A polymer of a compound of the formula: ##STR25## with a polyfunctional monomer, R being an organic group attached to the oxygen atom through a carbon atom and X and Y are functional groups polymerizable with said polyfunctional monomer.
Claim 9
Dependent Claim 39 words
A polymer of a compound of the formula: ##STR25## with a polyfunctional monomer, R being an organic group attached to the oxygen atom through a carbon atom and X and Y are functional groups polymerizable with said polyfunctional monomer.
Claim 10
Dependent Claim 12 words
A polymer of claim 7 wherein R is a halo alkyl group.
Claim 11
Dependent Claim 30 words
A polymer having the repeating unit: ##STR26## wherein the R groups of the (RO) 2 are the same or different organic groups attached to the oxygen atoms by carbon atoms.
Claim 12
Dependent Claim 30 words
A polymer having the repeating unit: ##STR26## wherein the R groups of the (RO) 2 are the same or different organic groups attached to the oxygen atoms by carbon atoms.
Claim 13
Dependent Claim 10 words
A polymer of claim 9 wherein R is a haloalkyl.
Claim 14
Dependent Claim 40 words
The polymer of claim 7 wherein the compound has the formula: ##STR27## wherein R is an organic group attached to the oxygen atom through a carbon atom and is the same or different, and X and Y are each amino.

References Cited (Backward Citations)

US3376258A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-05-05 1989-11-04 1990-05-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-05-05 1993-11-04 1994-05-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-05-05 1997-11-04 1998-05-06 $7700.00 Window Closed / Lapsed

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