US4587101A
Expired / Lapsed
US
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Measuring device for determining the O2 content of a sample
Assignee: Avl AG
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Filing: 1983-11-18
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Granted: 1986-05-06
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Expires: 2003-11-18
Abstract
Abstract In a sensor element for determining the O 2 content of a sample, comprising a fluorescent indicator substance which is embedded in a polymer carrier and with which the sample may be brought into contact, a fluorescence extinction sufficiently high for yielding useful measurement results is achieved by the use of plasticizer-compatible polymers as carrier materials which contain plasticizers in addition to the indicator molecules.
Inventors
- 👤 Hermann Marsoner
- 👤 Herbert Kroneis
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 14:07
CPC Classifications
G; G01; G01N; G01N21/00; G01N21/62; G01N21/63; G01N21/64; G01N21/6428; G01N21/643; C; C09; C09K; C09K11/00; C09K11/02; C09K11/025; C09K11/06
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
115 words
A sensor element which, when placed in contact with a sample containing oxygen, is capable of indicating the oxygen content in said sample, said sensor element comprising a carrier which is composed of a linear and amorphous polymer which is compatible with plasticizers, said polymer carrier being permeable to oxygen molecules; a plasticizer compound contained within said polymer carrier; and an oxygen-sensitive fluorescent indicator substance selected from the group consisting of polycyclic aromatic molecules, homocyclic aromatic molecules and heterocyclic aromatic molecules contained within said polymer carrier, said oxygen-sensitive fluorescent indicator substance upon excitation emitting light of a certain wavelength and of varying intensity depending on the amount of oxygen from said sample in contact therewith.
Claim 2
Dependent Claim
115 words
A sensor element which, when placed in contact with a sample containing oxygen, is capable of indicating the oxygen content in said sample, said sensor element comprising a carrier which is composed of a linear and amorphous polymer which is compatible with plasticizers, said polymer carrier being permeable to oxygen molecules; a plasticizer compound contained within said polymer carrier; and an oxygen-sensitive fluorescent indicator substance selected from the group consisting of polycyclic aromatic molecules, homocyclic aromatic molecules and heterocyclic aromatic molecules contained within said polymer carrier, said oxygen-sensitive fluorescent indicator substance upon excitation emitting light of a certain wavelength and of varying intensity depending on the amount of oxygen from said sample in contact therewith.
Claim 3
Dependent Claim
46 words
A sensor element according to claim 1, wherein said carrrier is composed of hydrophilic polymers selected from the group consisting of cellulose acetate, cellulose acetate butyrate, cellulose nitrate and ethyl cellulose, and wherein said plasticizers are selected from the group consisting of glycol, glycerin and pentaerythrite.
Claim 4
Dependent Claim
68 words
A sensor element according to claim 1, wherein said carrier is composed of hydrophobic polymers selected from the group consisting of polyvinylchloride, polystrene, polyvinyllacetate, polyvinyl butyral, polyvinyl chloride acetate, polyethylene, polypropylene, polyurethane, polyester, natural rubber, isoprene rubber, chloroprene rubber and butyl rubber, and wherein said plasticizers are selected from the group consisting of high-boiling esters, mineral oils, chlorinated biphenyls, chlorinated polyphenyls, epoxidized oils, polymeric plasticizers, and polymerizable plasticizers.
Claim 5
Dependent Claim
23 words
A sensor element according to claim 3, wherein said high-boiling esters are selected from the group consisting of triarylphosphates, dialkylphthalates, dialkyladipates and dialkylsebacates.
Claim 6
Dependent Claim
23 words
A sensor element according to claim 3, wherein said polymeric plasticizers are selected from the group consisting of polyester, polyisobutane and nitride rubber.
Claim 7
Dependent Claim
25 words
A sensor element according to claim 3, wherein said polymerizable plasticizers are selected from the group consisting of alkyl ester, aryl ester and nitride ester.
Claim 8
Dependent Claim
28 words
A sensor element according to claim 1, wherein said fluorescent indicator substance comprises a polycyclic aromatic hydrocarbon which displays fluorescence decay times τ o greater than 5 ns.
Claim 9
Dependent Claim
47 words
A sensor element according to claim 1, wherein said polymer carrier defines a side which is intended to face the sample containing oxygen, and wherein said sensor element includes an additional layer of polymer of low transparency which is applied on said side of said polymer carrier.
Claim 10
Dependent Claim
26 words
A sensor element according to claim 8, wherein said additional layer has the same composition as said carrier and wherein it incorporates particles of ferrous oxide.
Claim 11
Dependent Claim
15 words
A sensor element according to claim 1, further including pigment particles in said polymer carrier.
Claim 12
Dependent Claim
15 words
A sensor element according to claim 10, wherein said pigment particles comprise ferrous oxide particles.
Claim 13
Dependent Claim
39 words
A sensor element according to claim 10, wherein said pigment particles are accumulated on the side of said polymer carrier facing said sample due to the influence of external fields of force, such as gravitational, electric or magnetic fields.
Claim 14
Dependent Claim
41 words
A sensor element according to claim 1, wherein said polymer carrier defines a side which is intended to face the sample containing oxygen, and wherein said sensor element includes a thin mesh screen embedded in said side of said polymer carrier.
Claim 15
Dependent Claim
37 words
A sensor element according to claim 1, wherein said fluorescent indicator substance includes hydrocarbon chains containing between 3 and 20 carbon atoms, such that the mobility of said fluorescent indicator substance in said polymer carrier is reduced.
Claim 16
Dependent Claim
25 words
A sensor element according to claim 1, wherein said fluorescent indicator substance is covalently bonded to said polymer carrier to immobilize it within said carrier.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-05-05 | 1989-11-04 | 1990-05-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-05-05 | 1993-11-04 | 1994-05-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-05-05 | 1997-11-04 | 1998-05-06 | $7700.00 | Window Closed / Lapsed |