US4587026A
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Multifunctional lubricant additives
Assignee: Mobil Oil AS
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Filing: 1984-06-21
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Granted: 1986-05-06
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Expires: 2004-06-21
Abstract
Abstract Amine-sulfurized hydrocarbyl or hydrocarbyloxy phenol borates and alkoxylated derivatives thereof provide friction reducing and high temperature stabilizing properties to lubricating oils and greases into which they have been incorporated.
Inventors
- 👤 Andrew G. Horodysky
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 21:09
CPC Classifications
C; C07; C07F; C07F5/00; C07F5/02; C07F5/04; C10; C10M; C10M139/00; C10M2227/00; C10M2227/06; C10M2227/061; C10M2227/062
Claims Analysis
Total Claims: 27
Claim 1
Independent Claim
103 words
A lubricant composition comprising a major proportion of an oil of lubricating viscosity or a grease prepared therefrom and a minor effective proportion of a multifunctional additive having friction reducing, antioxidation and corrosion inhibition characteristics consisting of an amine or alkoxylated amine sulfurized phenol borate or mixtures thereof wherein said amine is selected from the group consisting of a hydrocarbyl monoamine or diamine, a hydrocarbyloxy hydrocarbylene monoamine or diamine, a hydrocarbyl alkoxylated monoamine or diamine, a hydrocarbyloxy hydrocarbylene alkoxylated monoamine or diamine and wherein hydrocarbyl comprises a member selected from the group consisting of alkyl, alkylene, cycloalkyl, aryl and alkaryl or mixtures thereof.
Claim 2
Dependent Claim
103 words
A lubricant composition comprising a major proportion of an oil of lubricating viscosity or a grease prepared therefrom and a minor effective proportion of a multifunctional additive having friction reducing, antioxidation and corrosion inhibition characteristics consisting of an amine or alkoxylated amine sulfurized phenol borate or mixtures thereof wherein said amine is selected from the group consisting of a hydrocarbyl monoamine or diamine, a hydrocarbyloxy hydrocarbylene monoamine or diamine, a hydrocarbyl alkoxylated monoamine or diamine, a hydrocarbyloxy hydrocarbylene alkoxylated monoamine or diamine and wherein hydrocarbyl comprises a member selected from the group consisting of alkyl, alkylene, cycloalkyl, aryl and alkaryl or mixtures thereof.
Claim 3
Dependent Claim
87 words
The composition of claim 1 wherein the amines have the following general structures: ##STR6## where R is from about C 6 to about C 30 hydrocarbyl or hydrocarbyloxy, R 2 and R 3 each separately are, H, (R 1 ) x H, R or ##STR7## R 1 is C 2 or C 3 hydrocarbyloxy, R 4 is C 2 or C 3 hydrocarbyl, R 5 and R 6 each separately are H or (R 1 ) x H and wherein x is from 1 to about 10.
Claim 4
Dependent Claim
12 words
The composition of claim 1 wherein said additive is bis(2-hydroxyethyl)cocoamine-dodecylphenol sulfide borate.
Claim 5
Dependent Claim
12 words
The composition of claim 1 wherein said additive is bis(2-hydroxyethyl)oleylamine-dodecylphenol sulfide borate.
Claim 6
Dependent Claim
12 words
The composition of claim 1 wherein said additive is N-oleyl-1,3-propylenediamine-dodecylphenol sulfude borate.
Claim 7
Dependent Claim
12 words
The composition of claim 1 wherein said additive is oleylamine-dodecylphenol sulfide borate.
Claim 8
Dependent Claim
32 words
The composition of claim 1 wherein said oil of lubricating viscosity is selected from the group consisting of mineral oils or fractions thereof, synthetic oils or mixtures of mineral and synthetic oils.
Claim 9
Dependent Claim
12 words
The composition of claim 1 wherein said oil is a mineral oil.
Claim 10
Dependent Claim
12 words
The composition of claim 3 wherein said oil is a mineral oil.
Claim 11
Dependent Claim
12 words
The composition of claim 4 wherein said oil is a mineral oil.
Claim 12
Dependent Claim
12 words
The composition of claim 5 wherein said oil is a mineral oil.
Claim 13
Dependent Claim
12 words
The composition of claim 6 wherein said oil is a mineral oil.
Claim 14
Dependent Claim
12 words
The composition of claim 1 wherein said oil is a synthetic oil.
Claim 15
Dependent Claim
12 words
The composition of claim 3 wherein said oil is a synthetic oil.
Claim 16
Dependent Claim
12 words
The composition of claim 4 wherein said oil is a synthetic oil.
Claim 17
Dependent Claim
12 words
The composition of claim 5 wherein said oil is a synthetic oil.
Claim 18
Dependent Claim
12 words
The composition of claim 6 wherein said oil is a synthetic oil.
Claim 19
Dependent Claim
12 words
The composition of claim 1 wherein said major proportion is a grease.
Claim 20
Dependent Claim
14 words
The composition of claim 18 wherein said grease is a lithium hydroxylcarboxylate soap grease.
Claim 21
Dependent Claim
17 words
The composition of claim 1 containing from about 0.1 to about 10 wt. % of said additive.
Claim 22
Dependent Claim
17 words
The composition of claim 20 containing from about 2 to about 4 wt. % of said additive.
Claim 23
Dependent Claim
125 words
A multifunctional friction-reducing additive product having the following general structure: ##STR8## where R 7 is hydrogen or from about C 3 to about C 30 hydrocarbyl, Y is from 1 to about 4, Z is 0 to about 4, and A is one or more amine of the below generalized amine structures or mixtures thereof: ##STR9## wherein R is from C 6 to about C 30 hydrocarbyl or hydrocarbyloxy, R 3 is H, (R 1 ) x H, R or ##STR10## wherein R 1 is C 2 to C 3 hydrocarbyloxy, R 4 is C 2 to C 3 hydrocarbyl and R 5 and R 6 are each separately H or (R 1 ) x H, and wherein x is from 1 to about 10.
Claim 24
Dependent Claim
125 words
A multifunctional friction-reducing additive product having the following general structure: ##STR8## where R 7 is hydrogen or from about C 3 to about C 30 hydrocarbyl, Y is from 1 to about 4, Z is 0 to about 4, and A is one or more amine of the below generalized amine structures or mixtures thereof: ##STR9## wherein R is from C 6 to about C 30 hydrocarbyl or hydrocarbyloxy, R 3 is H, (R 1 ) x H, R or ##STR10## wherein R 1 is C 2 to C 3 hydrocarbyloxy, R 4 is C 2 to C 3 hydrocarbyl and R 5 and R 6 are each separately H or (R 1 ) x H, and wherein x is from 1 to about 10.
Claim 25
Dependent Claim
174 words
A lubricant composition comprising a major proportion of an oil of lubricating viscosity or grease prepared therefrom and a minor effective proportion of a multifunctional additive having friction reducing, antioxidation and corrosion inhibiting characteristics consisting of an amine or alkoxylated amine sulfurized hydrocarbyl phenol borate or mixtures thereof derived from amines having the following general structures: ##STR11## where R is from about C 6 to about C 30 hydrocarbyl or hydrocarbyloxy, R 2 and R 3 each separately are H, (R 1 ) x H, R or ##STR12## wherein R 1 is C 2 or C 3 hydrocarbyloxy, R 4 is C 2 or C 3 hydrocarbyl, R 5 and R 6 each separately are H or (R 1 ) x H and wherein x is from 1 to about 10; sulfurized hydrocarbyl phenols having the following generalized structure: ##STR13## where R 7 is H or from about C 3 to about C 30 hydrocarbyl, Y is from 1 to about 4 and Z is from 0 to about 4; and a boronating agent.
Claim 26
Dependent Claim
174 words
A lubricant composition comprising a major proportion of an oil of lubricating viscosity or grease prepared therefrom and a minor effective proportion of a multifunctional additive having friction reducing, antioxidation and corrosion inhibiting characteristics consisting of an amine or alkoxylated amine sulfurized hydrocarbyl phenol borate or mixtures thereof derived from amines having the following general structures: ##STR11## where R is from about C 6 to about C 30 hydrocarbyl or hydrocarbyloxy, R 2 and R 3 each separately are H, (R 1 ) x H, R or ##STR12## wherein R 1 is C 2 or C 3 hydrocarbyloxy, R 4 is C 2 or C 3 hydrocarbyl, R 5 and R 6 each separately are H or (R 1 ) x H and wherein x is from 1 to about 10; sulfurized hydrocarbyl phenols having the following generalized structure: ##STR13## where R 7 is H or from about C 3 to about C 30 hydrocarbyl, Y is from 1 to about 4 and Z is from 0 to about 4; and a boronating agent.
Claim 27
Dependent Claim
18 words
The composition of claim 23 wherein the boronating agent is selected from boric acid or a trihydrocarbyl borate.
References Cited (Backward Citations)
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1989-05-05 | 1989-11-04 | 1990-05-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-05-05 | 1993-11-04 | 1994-05-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-05-05 | 1997-11-04 | 1998-05-06 | $7700.00 | Window Closed / Lapsed |