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US4586967A Expired / Lapsed US ⏱️ 0.0 years remaining

Copper-tin alloys having improved wear properties

Assignee: Olin Corp
•
Filing: 1984-11-23
•
Granted: 1986-05-06
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Expires: 2004-11-23
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Abstract

Abstract A copper-tin alloy having improved wear performance and a process for forming the alloy is described herein. The alloy consists essentially of about 2% to about 11%, preferably about 3.5% to about 9% tin, about 0.03% to about 0.75%, preferably about 0.08% to about 0.5% phosphorous and the balance essentially copper. The processing for improving the wear performance includes a final heat treatment at a temperature in the range of about 400 DEG C. to about 650 DEG C., preferably about 500 DEG C. to about 600 DEG C. in an atmosphere having a dew point in the range of about -75 DEG C. to about +95 DEG C., preferably -57 DEG C. to +21 DEG C. and an oxygen level in the range of about 0.001 ppm to about 225 ppm.

Inventors

  • 👤 Eugene Shapiro
  • 👤 Frank N. Mandigo

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 19:53
CPC Classifications
C; C22; C22F; C22F1/00; C22F1/08; C22F1/02

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 94 words
A copper-tin alloy having a lubricating type, discontinuous film on at least one surface to improve wear performance, said alloy consisting essentially of about 2% to about 11% tin, about 0.03% to about 0.75% phosphorous and the balance essentially copper; and said film being formed by subjecting said alloy to a heat treatment at a temperature in the range of about 400° C. to about 650° C. in an atmosphere having a dew point in the range of about -75° C. to about +95° C. and an oxygen level less than about 300 ppm.
Claim 2
Dependent Claim 94 words
A copper-tin alloy having a lubricating type, discontinuous film on at least one surface to improve wear performance, said alloy consisting essentially of about 2% to about 11% tin, about 0.03% to about 0.75% phosphorous and the balance essentially copper; and said film being formed by subjecting said alloy to a heat treatment at a temperature in the range of about 400° C. to about 650° C. in an atmosphere having a dew point in the range of about -75° C. to about +95° C. and an oxygen level less than about 300 ppm.
Claim 3
Dependent Claim 67 words
The copper tin alloy of claim 1 wherein: said film being formed by subjecting said alloy to a heat treatment at a temperature in the range of about 500° C. to about 600° C. in an atmosphere having a dew point in the range of about -57° C. to about +21° C. and an oxygen level in the range of about 0.001 ppm to about 225 ppm.
Claim 4
Dependent Claim 29 words
The copper-tin alloy of claim 1 wherein: said alloy consists essentially of about 3.5% to about 9% tin, about 0.08% to about 0.5% phosphorous and the balance essentially copper.
Claim 5
Dependent Claim 22 words
The alloy of claim 1 wherein said film comprises: a plurality of discrete tin sweat nodules on said at least one surface.
Claim 6
Dependent Claim 19 words
The alloy of claim 1 wherein said film comprises: a tin-containing amorphous film on said at least one surface.

References Cited (Backward Citations)

US115220A Cited
US2237243A Cited
US2636101A Cited
DE1051517B Cited
US3505104A Cited
US3824132A Cited
US3801380A Cited
US3841921A Cited
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US4443274A Cited
US4478651A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-05-05 1989-11-04 1990-05-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-05-05 1993-11-04 1994-05-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-05-05 1997-11-04 1998-05-06 $7700.00 Window Closed / Lapsed

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