US4585854A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Polyester composition
Assignee: Shell USA Inc
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Filing: 1985-02-07
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Granted: 1986-04-29
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Expires: 2005-02-07
Abstract
Abstract Polyester compositions which are dispersible or soluble in water based systems can be very valuable as adhesives, coatings, paints, and the like. The use of water based solvent systems eliminates recovery and toxicity problems normally related with many organic solvents. The polyester compositions of this invention have an increased affinity for water based systems by the incorporation therein salts of organic sulfonic acid monomers and by carboxyl terminating these polyesters to a very substantial degree. The water based systems in which these modified polyesters are useful contain an alcohol in addition to water.
Inventors
- 👤 William C. T. Tung
- 👤 George A. Deisz
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 07:50
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/68; C08G63/688; C08G63/6884; A; A61; A61K; A61K8/00; A61K8/18; A61K8/72; A61K8/84; A61K8/85; A61Q; A61Q5/00; A61Q5/06; C09; C09D; C09D167/00; C09D167/02; C09J; C09J167/00; C09J167/02
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
218 words
A polyester comprised of repeat units which are derived from (A) a diacid component which is comprised of (1) from 20 to 90 mole percent of at least one member selected from the group consisting of dimethylterephthalate and terephthalic acid, (2) from 1 to 6 mole percent of at least one salt of an organic sulfonic acid monomer, and (3) from 4 to 74 mole percent of at least one member selected from the group consisting of alkyl dicarboxylic acids having from 4 to 36 carbon atoms, diesters of alkyl dicarboxylic acids having from 6 to 38 carbon atoms, aryl dicarboxylic acids having from 9 to 20 carbon atoms, diesters of aryl dicarboxylic acids having from 11 to 22 carbon atoms, alkyl substituted aryl dicarboxylic acids having from 9 to 20 carbon atoms, diesters of alkyl substituted aryl dicarboxylic acids having from 11 to 22 carbon atoms, dimethylorthophthalate, dimethylisophthalate, orthophthalic acid, and isophthalic acid: and (B) a diol component which is comprised of (1) from 20 to 100 mole percent ethylene glycol, and (2) from 0 to 80 mole percent of one or more members selected from the group consisting of glycols having from 3 to 12 carbon atoms and glycol ethers having from 4 to 12 carbon atoms: wherein said polyester is terminated with carboxyl end groups.
Claim 2
Dependent Claim
218 words
A polyester comprised of repeat units which are derived from (A) a diacid component which is comprised of (1) from 20 to 90 mole percent of at least one member selected from the group consisting of dimethylterephthalate and terephthalic acid, (2) from 1 to 6 mole percent of at least one salt of an organic sulfonic acid monomer, and (3) from 4 to 74 mole percent of at least one member selected from the group consisting of alkyl dicarboxylic acids having from 4 to 36 carbon atoms, diesters of alkyl dicarboxylic acids having from 6 to 38 carbon atoms, aryl dicarboxylic acids having from 9 to 20 carbon atoms, diesters of aryl dicarboxylic acids having from 11 to 22 carbon atoms, alkyl substituted aryl dicarboxylic acids having from 9 to 20 carbon atoms, diesters of alkyl substituted aryl dicarboxylic acids having from 11 to 22 carbon atoms, dimethylorthophthalate, dimethylisophthalate, orthophthalic acid, and isophthalic acid: and (B) a diol component which is comprised of (1) from 20 to 100 mole percent ethylene glycol, and (2) from 0 to 80 mole percent of one or more members selected from the group consisting of glycols having from 3 to 12 carbon atoms and glycol ethers having from 4 to 12 carbon atoms: wherein said polyester is terminated with carboxyl end groups.
Claim 3
Dependent Claim
34 words
A polyester as specified in claim 1 wherein said salt of an organic sulfonic acid monomer is an alkali salt of a sulfo dialkyl isophthalate or an alkali salt of a sulfo isophthalatic acid.
Claim 4
Dependent Claim
24 words
A polyester as specified in claim 2 wherein said alkali salt of a sulfo dialkyl isophthalate is a sodium salt of sulfo dimethyl isophthalate.
Claim 5
Dependent Claim
22 words
A polyester as specified in claim 2 wherein said polyester is terminated with 2 carboxyl end groups at said polyesters chain ends.
Claim 6
Dependent Claim
16 words
A polyester as specified in claim 4 wherein said polyester is carboxyl terminated with trimellitic anhydride.
Claim 7
Dependent Claim
60 words
A polyester as specified in claim 2 wherein said diol component is comprised of (1) from 50 to 100 mole percent ethylene glycol and (2) from 0 to 50 mole percent of one or more members selected from the group consisting of glycols having from 3 to 12 carbon atoms and glycol ethers having from 4 to 12 carbon atoms.
Claim 8
Dependent Claim
53 words
A polyester as specified in claim 6 wherein said members selected from the group consisting of glycols having from 3 to 12 carbon atoms and glycol ethers having from 4 to 12 carbon atoms are glycols having from 3 to 8 carbon atoms and glycol ethers having from 4 to 8 carbon atoms.
Claim 9
Dependent Claim
58 words
A polyester as specified in claim 6 wherein said members selected from the group consisting of glycols having from 3 to 12 carbon atoms and glycol ethers having from 4 to 12 carbon atoms are selected from the group consisting of 1,3-propylene glycol, 1,2-propylene glycol, 2,2-diethyl-1,3-propanediol, 2,2-dimethyl-1,3-propanediol, 2-ethyl-2-butyl-1,3-propanediol, 2-ethyl-2-isobutyl-1,3propanediol, 1,3butanediol, 1,4-butanediol, 1,5-pentanediol, 1,6-hexandeiol, 2,2,4-trimethyl-1,6-hexanediol, 1,3-cyclohexanedimethanol, 1,4-cyclohexanedimethanol, and 2,2,4,4-tetramethyl-1,3-cyclobutanediol.
Claim 10
Dependent Claim
14 words
A polyester as specified in claim 3 wherein said diol component is ethylene glycol.
Claim 11
Dependent Claim
20 words
A polyester as specified in claim 1 wherein said polyester has a molecular weight of about 1000 to about 7000.
Claim 12
Dependent Claim
20 words
A polyester as specified in claim 6 wherein said polyester has a molecular weight of about 1000 to about 7000.
Claim 13
Dependent Claim
129 words
A polyester as specified in claim 6 wherein said members selected from the group consisting of alkyl dicarboxylic acids having from 4 to 20 carbon atoms, diesters of alkyl dicarboxylic acids having from 6 to 20 carbon atoms, aryl dicarboxylic acids having from 9 to 20 carbon atoms, diesters of aryl dicarboxylic acids having 11 to 20 carbon atoms, alkyl substituted aryl dicarboxylic acids having from 9 to 20 carbon atoms, diesters of alkyl substituted aryl dicarboxylic acids having from 11 to 20 carbon atoms, dimethylorthopthalate, dimethylisophthalate, orthopthalic acid, and isophthalic acid are selected from the group consisting of isophthalic acid and azelaic acid and wherein said diol component is comprised of from 50 to 100 mole percent ethylene glycol and from 0 to 50 mole percent neopentyl glycol.
Claim 14
Dependent Claim
18 words
A polyester as specified in claim 12 wherein said polyester has a molecular weight of 2000 to 5000.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-04-28 | 1989-10-28 | 1990-04-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-04-28 | 1993-10-28 | 1994-04-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-04-28 | 1997-10-28 | 1998-04-29 | $7700.00 | Window Closed / Lapsed |