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US4585849A Expired / Lapsed US ⏱️ 0.0 years remaining

RTV Silicone pastes

Assignee: Bayer AG
•
Filing: 1984-09-26
•
Granted: 1986-04-29
•
Expires: 2004-09-26
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Abstract

Abstract In a polydiorganosilixane composition which is capable of storage in the absence of moisture and can be cured at ambient temperature under the action of water or moisture to give elastomers, the composition comprising a diorganosiloxane having reactive terminal groups, a diorganosilane having groups which are sensitive to hydrolysis, a cross-linking agent, and optionally fillers which have a thixotropic effect, condensation catalysts and/or other known auxiliaries, the improvement which comprises employing as the silane (a) a silane of the formula RR.sup.1 Si(NR.sup.2 R.sup.3).sub.2 plus (b) an organosilane of the formula RSi (O--N═R.sup.4).sub.3 in which R, R 1 , R 2 and R 3 each independently is alkyl, aryl, aralkyl and vinyl groups, or R 2 and R 3 together can be an alkanediyl radical having up to 8 C atoms or hydrogen, and R 4 is an R 2 R 3 C group having up to 8 C atoms. The composition cures at room temperature in the presence of moisture to elastomers of desirable physical properties.

Inventors

  • 👤 Franz Saykowski
  • 👤 Thomas Wurminghausen
  • 👤 Hans Stattlegger
  • 👤 Theo Achtenberg

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 12:01
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/54; C08G; C08G77/00; C08G77/04; C08G77/14; C08G77/16; C08G77/22; C08G77/26; Y; Y10; Y10S; Y10S528/00; Y10S528/901

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 149 words
In a polydiorganosiloxane composition which is capable of storage in the absence of moisture and can be cured at ambient temperature under the action of water or moisture to give elastomers, the composition comprising a diorganosiloxane having reactive terminal groups, a diorganosilane having groups which are sensitive to hydrolysis, a cross-linking agent, and optionally fillers which have a thixotropic effect, and condensation catalysts, the improvement which comprises employing as the silane (a) a silane of the formula RR.sup.1 Si(NR.sup.2 R.sup.3).sub.2 plus (b) an organosilane of the formula RSi(O--N═R.sup.4).sub.3 in which R, R 1 , R 2 and R 3 each independently is alkyl, aryl, aralkyl and vinyl groups, or R 2 and R 3 can be H or together can be an divalent alkyl radical radical having up to 8 C atoms, and R 4 is an R 2 R 3 --C group having up to 8 C atoms.
Claim 2
Dependent Claim 149 words
In a polydiorganosiloxane composition which is capable of storage in the absence of moisture and can be cured at ambient temperature under the action of water or moisture to give elastomers, the composition comprising a diorganosiloxane having reactive terminal groups, a diorganosilane having groups which are sensitive to hydrolysis, a cross-linking agent, and optionally fillers which have a thixotropic effect, and condensation catalysts, the improvement which comprises employing as the silane (a) a silane of the formula RR.sup.1 Si(NR.sup.2 R.sup.3).sub.2 plus (b) an organosilane of the formula RSi(O--N═R.sup.4).sub.3 in which R, R 1 , R 2 and R 3 each independently is alkyl, aryl, aralkyl and vinyl groups, or R 2 and R 3 can be H or together can be an divalent alkyl radical radical having up to 8 C atoms, and R 4 is an R 2 R 3 --C group having up to 8 C atoms.
Claim 3
Dependent Claim 15 words
A composition according to claim 1, in which R and R 1 are methyl groups.
Claim 4
Dependent Claim 23 words
A composition according to claim 1, in which the group (NR 2 R 3 ) is a cyclohexylamino radical or a butylamino radical.
Claim 5
Dependent Claim 13 words
A composition according to claim 1 in which the organosilane (b) is methyltris-(2-butanone-oxime)-silane.
Claim 6
Dependent Claim 63 words
A composition according to claim 1, comprising by weight 100 parts of α, ω-dihydroxypolydiorganosiloxane having a viscosity of 100 to 500,000 mPa.s, 3-15 parts of a dimethyldiaminosilane, 6-30 parts of an organotrioximesilane, 0 to 400 parts of a filler, 0.01-5.0 parts of a condensation catalyst, and 0 to 100 parts by weight of α, ω-bis-(trialkylsiloxy)-polydiorganosiloxane having a viscosity of 100 to 10,000 mPa.s.
Claim 7
Dependent Claim 14 words
A composition according to claim 5, wherein the α, ω-dihydroxypolydiorganosiloxane is an α, ω-dihydroxypolydimethylsiloxane.
Claim 8
Dependent Claim 12 words
A composition according to claim 5, wherein the organotrioximesilane is a methyltrioximesilane.
Claim 9
Dependent Claim 14 words
A composition according to claim 5, wherein the α, ω-bis-(trialkylsiloxy)-polydiorganosiloxane is an α, ω-bis-(trimethylsiloxy)-polydimethylsiloxane.
Claim 10
Dependent Claim 25 words
A composition according to claim 5, wherein the filler is optionally surface-treated chalk or dolomite having a mean particle size of less than 3 μm.
Claim 11
Dependent Claim 18 words
A composition according to claim 5, wherein the condensation catalyst is a metal salt of an organic acid.
Claim 12
Dependent Claim 19 words
A composition according to claim 1, wherein the reactive terminal groups of the polydiorganosiloxane are amino and/or oxime groups.
Claim 13
Dependent Claim 11 words
An elastomer produced by curing a composition according to claim 1.

References Cited (Backward Citations)

US3674738A Cited
US3758441A Cited
US4460761A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-04-28 1989-10-28 1990-04-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-04-28 1993-10-28 1994-04-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-04-28 1997-10-28 1998-04-29 $7700.00 Window Closed / Lapsed

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