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US4585826A Expired / Lapsed US ⏱️ 0.0 years remaining

Natural rubber containing compositions with increased tear strength

Assignee: Bridgestone Firestone Inc
•
Filing: 1985-01-28
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Granted: 1986-04-29
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Expires: 2005-01-28
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Abstract

Abstract Including certain carboxy-terminated butadiene-acrylonitrile copolymers in natural rubber formulations increases their tear strength, and hardness properties.

Inventors

  • 👤 Daniel F. Graves

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 17:49
CPC Classifications
C; C08; C08L; C08L7/00; C08L21/00

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 107 words
A curable but uncured elastomeric composition, said composition comprising (a) 100 parts by weight polymer consisting of (i) from about 95 to about 25 parts by weight of natural rubber, (ii) from 0 to about 65 parts by weight of synthetic rubber, (iii) from about 5 to about 25 parts by weight of liquid carboxy-terminated butadiene-acrylonitrile copolymer having a functionality ranging from about 1.5 to about 2.5, an acrylonitrile content ranging from about 10% to about 40% by weight and a Brookfield viscosity at 27° C. ranging from about 50,000 to about 200,000 centipoise, (b) from about 30 to about 120 parts by weight of reinforcing filler.
Claim 2
Dependent Claim 107 words
A curable but uncured elastomeric composition, said composition comprising (a) 100 parts by weight polymer consisting of (i) from about 95 to about 25 parts by weight of natural rubber, (ii) from 0 to about 65 parts by weight of synthetic rubber, (iii) from about 5 to about 25 parts by weight of liquid carboxy-terminated butadiene-acrylonitrile copolymer having a functionality ranging from about 1.5 to about 2.5, an acrylonitrile content ranging from about 10% to about 40% by weight and a Brookfield viscosity at 27° C. ranging from about 50,000 to about 200,000 centipoise, (b) from about 30 to about 120 parts by weight of reinforcing filler.
Claim 3
Dependent Claim 11 words
The composition of claim 1, wherein no synthetic rubber is present.
Claim 4
Dependent Claim 37 words
The composition of claim 1, wherein the carboxy-terminated butadiene-acrylonitrile copolymer has an acrylonitrile content ranging from about 15% to about 25% by weight and Brookfield viscosity at 27° C. ranging from about 125,000 to about 175,000 centipoise.
Claim 5
Dependent Claim 20 words
The composition of claim 3, wherein the reinforcing filler is selected from the group consisting of carbon black and silica.
Claim 6
Dependent Claim 26 words
The composition of claim 4, wherein the reinforcing filler is carbon black used in an amount ranging from about 30 to about 75 parts by weight.
Claim 7
Dependent Claim 28 words
The composition of claim 1, wherein the synthetic rubber is styrene-butadiene rubber and is present in an amount ranging from about 45 to about 65 parts by weight.
Claim 8
Dependent Claim 113 words
A cured elastomeric composition of improved tear strength, said composition comprising (a) 100 parts by weight polymer consisting of (i) from about 95 to about 25 parts by weight of natural rubber, (ii) from 0 to about 65 parts by weight of synthetic rubber, (iii) from about 5 to about 25 parts by weight of carboxy-terminated butadiene-acrylonitrile copolymer having a functionality ranging from about 1.5 to about 2.5, an acrylonitrile content ranging from about 10% to about 40% by weight and a Brookfield viscosity at 27° C. ranging from about 50,000 to about 200,000 centipoise, (b) from about 30 to about 120 parts by weight of reinforcing filler, and (c) a curing system.
Claim 9
Dependent Claim 113 words
A cured elastomeric composition of improved tear strength, said composition comprising (a) 100 parts by weight polymer consisting of (i) from about 95 to about 25 parts by weight of natural rubber, (ii) from 0 to about 65 parts by weight of synthetic rubber, (iii) from about 5 to about 25 parts by weight of carboxy-terminated butadiene-acrylonitrile copolymer having a functionality ranging from about 1.5 to about 2.5, an acrylonitrile content ranging from about 10% to about 40% by weight and a Brookfield viscosity at 27° C. ranging from about 50,000 to about 200,000 centipoise, (b) from about 30 to about 120 parts by weight of reinforcing filler, and (c) a curing system.
Claim 10
Dependent Claim 21 words
The cured composition of claim 7, wherein the reinforcing filler is selected from the group consisting of carbon black and silica.
Claim 11
Dependent Claim 27 words
The cured composition of claim 8, wherein the reinforcing filler is carbon black used in an amount ranging from about 30 to about 75 parts by weight.
Claim 12
Dependent Claim 39 words
The cured composition of claim 9, wherein the carboxy-terminated butadiene-acrylonitrile copolymer has an acrylonitrile content ranging from about 15% to about 25% by weight and a Brookfield viscosity at 27° C. ranging from about 125,000 to about 175,000 centipoise.
Claim 13
Dependent Claim 37 words
The cured composition of claim 10, wherein the curing system is an accelerated sulfur system comprising from about 0.5 to about 7 parts by weight sulfur and from about 0.5 to about 2.5 parts by weight accelertor.
Claim 14
Dependent Claim 12 words
The cured composition of claim 11, wherein no synthetic rubber is present.
Claim 15
Dependent Claim 29 words
The cured composition of claim 11, wherein the synthetic rubber is styrene-butadiene rubber and is present in an amount ranging from about 45 to about 65 parts by weight.

References Cited (Backward Citations)

US3837904A Cited
US4088708A Cited
US4303715A Cited
US4287928A Cited
US4204984A Cited
US4311759A Cited
US4433094A Cited
US4485198A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-04-28 1989-10-28 1990-04-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-04-28 1993-10-28 1994-04-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-04-28 1997-10-28 1998-04-29 $7700.00 Window Closed / Lapsed

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