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US4585824A Expired / Lapsed US ⏱️ 0.0 years remaining

Glass fiber-reinforced heat resistant resin composition

Assignee: Mitsubishi Chemical Corp
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Filing: 1984-10-05
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Granted: 1986-04-29
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Expires: 2004-10-05
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Abstract

Abstract A glass fiber-reinforced heat resistant resin composition which comprises: from 5 to 90% by weight of a pelletized polymer (A) obtained by suspension-polymerizing a vinyl aromatic monomer optionally together with an unsaturated nitrile monomer and a vinyl monomer copolymerizable therewith, in the presence of chopped glass fiber strands, and comprising from 50 to 90% by weight of the chopped glass fiber strands and from 50 to 10% by weight of a resin component consisting essentially of from 40 to 100% of residues of the vinyl aromatic monomer, from 0 to 60% of residues of the unsaturated nitrile monomer and from 0 to 30% of residues of the copolymerizable vinyl monomer; from 95 to 10% by weight of a polymer (B) comprising from 10 to 50% of residues of a maleimide monomer, from 90 to 50% of residues of a vinyl aromatic monomer, from 0 to 10% of residues of maleic anhydride and from 0 to 30% of residues of a vinyl monomer copolymerizable therewith.

Inventors

  • 👤 Minoru Uchida
  • 👤 Sadao Ikuma

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 20:50
CPC Classifications
C; C08; C08K; C08K7/00; C08K7/02; C08K7/04; C08K7/14

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 184 words
A glass fiber-reinforced heat resistant resin composition which comprises: from 5-90% by weight of a pelletized polymer (A) obtained by suspension-polymerizing a vinyl aromatic monomer, in the presence of chopped glass fiber strands, and comprising from 50 to 90% by weight of the chopped glass fiber strands and from 50 to 10% by weight of a resin component consisting essentially of from 40 to 100% of residues of the vinyl aromatic monomer; from 95 to 10% by weight of a polymer (B) comprising from 10 to 50% of residues of a maleimide monomer, and from 90 to 50% of residues of a vinyl aromatic monomer; from 15 to 50% by weight of a polymer (C) comprising from 40 to 100% of residues of a vinyl aromatic monomer; and from 0 to 50% by weight of a copolymer (D) obtained by graft-copolymerizing a vinyl aromatic monomer, to a rubber, and comprising from 5 to 70% by weight of the rubber and from 30 to 95% by weight of a resin component consisting essentially of from 40 to 100% of residues of the vinyl aromatic monomer.
Claim 2
Dependent Claim 184 words
A glass fiber-reinforced heat resistant resin composition which comprises: from 5-90% by weight of a pelletized polymer (A) obtained by suspension-polymerizing a vinyl aromatic monomer, in the presence of chopped glass fiber strands, and comprising from 50 to 90% by weight of the chopped glass fiber strands and from 50 to 10% by weight of a resin component consisting essentially of from 40 to 100% of residues of the vinyl aromatic monomer; from 95 to 10% by weight of a polymer (B) comprising from 10 to 50% of residues of a maleimide monomer, and from 90 to 50% of residues of a vinyl aromatic monomer; from 15 to 50% by weight of a polymer (C) comprising from 40 to 100% of residues of a vinyl aromatic monomer; and from 0 to 50% by weight of a copolymer (D) obtained by graft-copolymerizing a vinyl aromatic monomer, to a rubber, and comprising from 5 to 70% by weight of the rubber and from 30 to 95% by weight of a resin component consisting essentially of from 40 to 100% of residues of the vinyl aromatic monomer.
Claim 3
Dependent Claim 23 words
The composition according to claim 1, wherein the vinyl aromatic monomer is styrene, α-methylstyrene, p-methylstyrene, ter-butylstyrene, a halogenated styrene or a mixture thereof.
Claim 4
Dependent Claim 18 words
The composition according to claim 1, wherein the unsaturated nitrile monomer is acrylonitrile, methacrylonitrile or a mixture thereof.
Claim 5
Dependent Claim 17 words
The composition according to claim 1, wherein the copolymerizable vinyl monomer is an acrylate or a methacrylate.
Claim 6
Dependent Claim 19 words
The composition according to claim 1, wherein the maleimide monomer is maleimide, an N-aromatic maleimide or a mixture thereof.
Claim 7
Dependent Claim 38 words
The composition according to claim 1, wherein the resin component of said pelletized polymer (A) is obtained via suspension polymerization of, in addition to the vinyl aromatic monomer, an unsaturated nitrile monomer and a vinyl monomer copolymerizable therewith.
Claim 8
Dependent Claim 34 words
The composition according to claim 6, wherein said resin component further contains up to 60% of residues of the unsaturated nitrile monomer and up to 30% of the residues of the copolymerizable vinyl monomer.
Claim 9
Dependent Claim 31 words
The composition according to claim 1, wherein polymer (B) further comprises up to 10% of residues of maleic anhydride and up to 30% of residues of a vinyl monomer copolymerizable therewith.
Claim 10
Dependent Claim 33 words
The composition according to claim 1, wherein polymer (C) further comprises up to 60% of residues of an unsaturated nitrile monomer and up to 30% of residues of a vinyl monomer copolymerizable therewith.
Claim 11
Dependent Claim 33 words
The composition according to claim 1, wherein copolymer (D) is obtained by graft-copolymerizing, in addition to the vinyl aromatic monomer, an unsaturated nitrile monomer and a vinyl monomer copolymerizable therewith, to a rubber.
Claim 12
Dependent Claim 37 words
The composition according to claim 10, wherein the resin component of said copolymer (D) comprises up to 60% of residues of the unsaturated nitrile monomer and up to 30% of the residues of the copolymerizable vinyl monomer.
Claim 13
Dependent Claim 16 words
The composition according to claim 1, wherein said rubber of copolymer (D) is a polybutadiene rubber.

References Cited (Backward Citations)

DE1250117B Cited
GB1365329A Cited
GB1583465A Cited
JPS5536269A Cited
GB2122625A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-04-28 1989-10-28 1990-04-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-04-28 1993-10-28 1994-04-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-04-28 1997-10-28 1998-04-29 $7700.00 Window Closed / Lapsed

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