US4584332A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Flame retardant polyphenylene oxide thermoplastics
Assignee: General Electric Co
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Filing: 1984-09-17
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Granted: 1986-04-22
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Expires: 2004-09-17
Abstract
Abstract Flame retardant blends of styrene and polyphenylene oxide are provided resulting from the use of a mixture of zinc oxide and a triorganothiophosphate.
Inventors
- 👤 John J. Talley
- 👤 Carol B. Berman
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 18:23
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/49; C08K5/5398; C08K3/00; C08K3/18; C08K3/20; C08K3/22; C08L; C08L25/00; C08L25/02; C08L25/04; C08L2201/00; C08L2201/02; C08L71/00; C08L71/08; C08L71/10; C08L71/12; Y; Y10; Y10S; Y10S525/00; Y10S525/905
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
166 words
A flame retardant thermoplastic blend comprising by weight (A) 100 parts of polyphenylene oxide, (B) 20 to 300 parts of styrene resin and (C) 0.01 to 3 parts of zinc oxide per part of organothiophosphate having the formula ##STR11## which is utilized in the flame retardant thermoplastic blend in an amount of sufficient to provide from 0.5% to 5% by weight of phosphorous based on the weight of flame retardant thermoplastic blend, where R is a C.sub.(1-13) monovalent hydrocarbon radical or substituted C.sub.(1-13) monovalent hydrocarbon radical, Q is a monovalent group selected from the class consisting of ##STR12## R 1 is selected from the class consisting of divalent C.sub.(2-20) hydrocarbon radicals, halogenated divalent C.sub.(2-20) hydrocarbon radicals and divalent radicals having the formula --R.sup.2 (X).sub.a R.sup.2 -- where R 2 is a divalent C.sub.(6-13) arylene radical, X is a divalent radical selected from O, S, and C y H2 y , y is a whole number from 1 to 5 inclusive and a is 0 or 1.
Claim 2
Dependent Claim
166 words
A flame retardant thermoplastic blend comprising by weight (A) 100 parts of polyphenylene oxide, (B) 20 to 300 parts of styrene resin and (C) 0.01 to 3 parts of zinc oxide per part of organothiophosphate having the formula ##STR11## which is utilized in the flame retardant thermoplastic blend in an amount of sufficient to provide from 0.5% to 5% by weight of phosphorous based on the weight of flame retardant thermoplastic blend, where R is a C.sub.(1-13) monovalent hydrocarbon radical or substituted C.sub.(1-13) monovalent hydrocarbon radical, Q is a monovalent group selected from the class consisting of ##STR12## R 1 is selected from the class consisting of divalent C.sub.(2-20) hydrocarbon radicals, halogenated divalent C.sub.(2-20) hydrocarbon radicals and divalent radicals having the formula --R.sup.2 (X).sub.a R.sup.2 -- where R 2 is a divalent C.sub.(6-13) arylene radical, X is a divalent radical selected from O, S, and C y H2 y , y is a whole number from 1 to 5 inclusive and a is 0 or 1.
Claim 3
Dependent Claim
34 words
A flame retardant composition comprising a polyphenylene oxide-polystyrene graft copolymer, the amount of the organothiophosphate in accordance with claim 1 and from 0.01 to 3 parts of zinc oxide, per part of such organothiophosphate.
Claim 4
Dependent Claim
12 words
A composition in accordance with claim 1 where the organothiophosphate is triphenylthiophosphate.
Claim 5
Dependent Claim
12 words
A composition in accordance with claim 1 where the organothiophosphate is tri-4-methylphenylthiophosphate.
Claim 6
Dependent Claim
12 words
A composition in accordance with claim 1 where the organothiophosphate is tri-3-methylphenylthiophosphate.
Claim 7
Dependent Claim
12 words
A composition in accordance with claim 1 where the organothiophosphate is tri-2-methylphenylthiophosphate.
Claim 8
Dependent Claim
12 words
A composition in accordance with claim 1 where the organothiophosphate is tri-2,4-dimethylphenylthiophosphate.
References Cited (Backward Citations)
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