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US4584332A Expired / Lapsed US ⏱️ 0.0 years remaining

Flame retardant polyphenylene oxide thermoplastics

Assignee: General Electric Co
•
Filing: 1984-09-17
•
Granted: 1986-04-22
•
Expires: 2004-09-17
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Abstract

Abstract Flame retardant blends of styrene and polyphenylene oxide are provided resulting from the use of a mixture of zinc oxide and a triorganothiophosphate.

Inventors

  • 👤 John J. Talley
  • 👤 Carol B. Berman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 18:23
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/49; C08K5/5398; C08K3/00; C08K3/18; C08K3/20; C08K3/22; C08L; C08L25/00; C08L25/02; C08L25/04; C08L2201/00; C08L2201/02; C08L71/00; C08L71/08; C08L71/10; C08L71/12; Y; Y10; Y10S; Y10S525/00; Y10S525/905

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 166 words
A flame retardant thermoplastic blend comprising by weight (A) 100 parts of polyphenylene oxide, (B) 20 to 300 parts of styrene resin and (C) 0.01 to 3 parts of zinc oxide per part of organothiophosphate having the formula ##STR11## which is utilized in the flame retardant thermoplastic blend in an amount of sufficient to provide from 0.5% to 5% by weight of phosphorous based on the weight of flame retardant thermoplastic blend, where R is a C.sub.(1-13) monovalent hydrocarbon radical or substituted C.sub.(1-13) monovalent hydrocarbon radical, Q is a monovalent group selected from the class consisting of ##STR12## R 1 is selected from the class consisting of divalent C.sub.(2-20) hydrocarbon radicals, halogenated divalent C.sub.(2-20) hydrocarbon radicals and divalent radicals having the formula --R.sup.2 (X).sub.a R.sup.2 -- where R 2 is a divalent C.sub.(6-13) arylene radical, X is a divalent radical selected from O, S, and C y H2 y , y is a whole number from 1 to 5 inclusive and a is 0 or 1.
Claim 2
Dependent Claim 166 words
A flame retardant thermoplastic blend comprising by weight (A) 100 parts of polyphenylene oxide, (B) 20 to 300 parts of styrene resin and (C) 0.01 to 3 parts of zinc oxide per part of organothiophosphate having the formula ##STR11## which is utilized in the flame retardant thermoplastic blend in an amount of sufficient to provide from 0.5% to 5% by weight of phosphorous based on the weight of flame retardant thermoplastic blend, where R is a C.sub.(1-13) monovalent hydrocarbon radical or substituted C.sub.(1-13) monovalent hydrocarbon radical, Q is a monovalent group selected from the class consisting of ##STR12## R 1 is selected from the class consisting of divalent C.sub.(2-20) hydrocarbon radicals, halogenated divalent C.sub.(2-20) hydrocarbon radicals and divalent radicals having the formula --R.sup.2 (X).sub.a R.sup.2 -- where R 2 is a divalent C.sub.(6-13) arylene radical, X is a divalent radical selected from O, S, and C y H2 y , y is a whole number from 1 to 5 inclusive and a is 0 or 1.
Claim 3
Dependent Claim 34 words
A flame retardant composition comprising a polyphenylene oxide-polystyrene graft copolymer, the amount of the organothiophosphate in accordance with claim 1 and from 0.01 to 3 parts of zinc oxide, per part of such organothiophosphate.
Claim 4
Dependent Claim 12 words
A composition in accordance with claim 1 where the organothiophosphate is triphenylthiophosphate.
Claim 5
Dependent Claim 12 words
A composition in accordance with claim 1 where the organothiophosphate is tri-4-methylphenylthiophosphate.
Claim 6
Dependent Claim 12 words
A composition in accordance with claim 1 where the organothiophosphate is tri-3-methylphenylthiophosphate.
Claim 7
Dependent Claim 12 words
A composition in accordance with claim 1 where the organothiophosphate is tri-2-methylphenylthiophosphate.
Claim 8
Dependent Claim 12 words
A composition in accordance with claim 1 where the organothiophosphate is tri-2,4-dimethylphenylthiophosphate.

References Cited (Backward Citations)

US3383435A Cited
US3755250A Cited
US3929931A Cited
US3943191A Cited
JPS57128731A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-04-21 1989-10-21 1990-04-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-04-21 1993-10-21 1994-04-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-04-21 1997-10-21 1998-04-22 $7700.00 Window Closed / Lapsed

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