US4582890A
Expired / Lapsed
US
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Bicyclic amide acetal/polyamine/polyisocyanate polymers
Assignee: Ashland LLC
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Filing: 1985-05-06
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Granted: 1986-04-15
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Expires: 2005-05-06
Abstract
Abstract A process is described for preparing novel polymers having good impact resistance and other desirable physical properties, said process comprising interpolymerizing a mixture of a bicyclic amide acetal, a polyamine and a polyisocyanate.
Inventors
- 👤 Timothy Tufts
- 👤 Anil Goel
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 13:24
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/65; C08G18/30; C08G18/32; C08G18/3225; C08G18/38; C08G18/3819; C08G18/3823; C08G18/3825; C08G18/3827; C08G18/67; C08G18/69; C08G18/696; C08G2120/00
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
96 words
A process for preparing a polymer having good impact resistance at a rapid rate comprising interpolymerizing a mixture of a bicyclic amide acetal, a polyamine containing two or more amine groups per molecule having at least two amino groups per molecule which have at least one hydrogen capable of reaction with isocyanates and a polyisocyanate wherein the weight ratio of amide acetal to polyamine is in the range of from 95:5 to 5:95 and the equivalent ratio of isocyanate to combined bicyclic amide acetal and polyamine is in the range of from 0.8:1 to about 3:1.
Claim 2
Dependent Claim
96 words
A process for preparing a polymer having good impact resistance at a rapid rate comprising interpolymerizing a mixture of a bicyclic amide acetal, a polyamine containing two or more amine groups per molecule having at least two amino groups per molecule which have at least one hydrogen capable of reaction with isocyanates and a polyisocyanate wherein the weight ratio of amide acetal to polyamine is in the range of from 95:5 to 5:95 and the equivalent ratio of isocyanate to combined bicyclic amide acetal and polyamine is in the range of from 0.8:1 to about 3:1.
Claim 3
Dependent Claim
104 words
The process of claim 1 wherein the bicyclic amide acetal is one having the formula ##STR2## wherein R represents hydrogen or an alkyl group having from 1 to 10 carbon atoms, R' represents hydrogen or an alkyl group having from 1 to 10 carbon atoms, R" represents an alkyl group having from 1 to 20 carbon atoms, an aryl group having from 6 to 12 carbon atoms, or an alkaryl group having from 7 to 20 carbon atoms and R"' represents hydrogen or an alkyl group having from 1 to 20 carbon atoms or an ether group having from 1 to 20 carbon atoms.
Claim 4
Dependent Claim
22 words
The process of claim 2 carried out at a temperature in the range of from about room temperature to about 200° C.
Claim 5
Dependent Claim
24 words
The process of claim 3 wherein the bicyclic amide acetal is one in which R, R' and R"' are hydrogen and R" is methyl.
Claim 6
Dependent Claim
26 words
The process of claim 4 wherein the polyamine is a mixture of triamine of a polypropyleneoxide and diethyl toluene diamine and the polyisocyanate is isophorone diisocyanate.
Claim 7
Dependent Claim
28 words
The process of claim 4 wherein the polyamine is a mixture of a triamine of a polypropyleneoxide and diethyl toluene diamine and the polyisocyanate is 4,4'-methylene bis(phenyl isocyanate).
Claim 8
Dependent Claim
20 words
The process of claim 4 wherein the polyamine is an amine terminated polypropylene oxide and the polyisocyanate is 4,4'-methylene bis(phenylisocyanate).
Claim 9
Dependent Claim
28 words
The process of claim 4 wherein the polyamine is a mixture of an amine terminated polypropyleneoxide and diethyl toluene diamine and the polyisocyanate is hydrogenated bis(4-isocyanato phenyl) methane
Claim 10
Dependent Claim
37 words
The process of claim 4 wherein the polyamine is a mixture of an amine terminated amide based on linoleic acid dimer, diethyl toluene diamine and a triamine based on poly propyleneoxide and the polyisocyanate is isophorone diisocyanate.
Claim 11
Dependent Claim
9 words
The polymer produced by the process of claim 1.
Claim 12
Dependent Claim
104 words
The polymer of claim 10 wherein the bicyclic amide acetal is one having the formula ##STR3## wherein R represents hydrogen or an alkyl group having from 1 to 10 carbon atoms, R' represents hydrogen or an alkyl group having from 1 to 10 carbon atoms, R" represents an alkyl group having from 1 to 20 carbon atoms, an aryl group having from 6 to 12 carbon atoms, or an alkaryl group having from 7 to 20 carbon atoms and R'" represents hydrogen or an alkyl group having from 1 to 20 carbon atoms or an ether group having from 1 to 20 carbon atoms.
Claim 13
Dependent Claim
21 words
The polymer of claim 11 produced at a temperature in the range of from about room temperature to about 200° C.
Claim 14
Dependent Claim
24 words
The polymer of claim 12 wherein the bicyclic amide acetal is one in which R, R' and R'" are hydrogen and R" is methyl.
Claim 15
Dependent Claim
27 words
The polymer of claim 12 wherein the polyamine is a mixture of triamine of a polypropylene oxide and diethyl toluene diamine and the polyisocyanate is isophorone diisocyanate.
Claim 16
Dependent Claim
29 words
The polymer of claim 12 wherein the polyamine is a mixture of a triamine of a polypropylene oxide and diethyl toluene diamine and the polyisocyanate is 4,4'-methylene bis(phenyl isocyanate).
Claim 17
Dependent Claim
21 words
The polymer of claim 12 wherein the polyamine is an amine terminated polypropylene oxide and the polyisocyanate is a 4,4'-methylene bis(phenylisocyanate).
Claim 18
Dependent Claim
30 words
The process of claim 12 wherein the polyamine is a mixture of an amine terminated polypropylene oxide and ocethyl diethyl toluene diamine and the polyisocyanate is hydrogenated bis(4-isocyanato phenyl) methane.
Claim 19
Dependent Claim
37 words
The process of claim 12 wherein the polyamine is a mixture of an amine terminated amide based on linoleic acid dimer, diethyl toluene diamine and a triamine based on polypropylene oxide and the polyisocyanate is isophorone diisocyanate.
References Cited (Backward Citations)
DE3235933A1
Cited
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