← Back to Patent Explorer
US4582876A Expired / Lapsed US ⏱️ 0.0 years remaining

High-impact polyester/styrene-maleic anhydride copolymer blends

Assignee: Eastman Chemical Co
•
Filing: 1984-09-10
•
Granted: 1986-04-15
•
Expires: 2004-09-10
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Molding compositions having high impact at low temperatures and which are blends of copolyesters based on poly(1,4-cyclohexylenedimethylene terephthalate) and rubber-modified styrene-maleic anhydride copolymers having at least two rubbery additives that were present during the polymerization of the copolymers.

Inventors

  • 👤 Doyle A. Weemes
  • 👤 Robert W. Seymour

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 15:15
CPC Classifications
C; C08; C08L; C08L51/00; C08L51/04; C08L67/00; C08L67/02

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 283 words
Molding composition consisting of a blend of (a) 70 weight percent to 30 weight percent copolyester consisting of repeating units from terephthalic acid, repeating units from 1,4-cyclohexanedimethanol present in the amount of 25 to 90 mol % and repeating units from a second glycol having 2 to 6 carbon atoms present in the amount of 75 to 10 mol %, wherein the total mol % of glycol is equal to 100 mol %, and (b) 30 weight percent to 70 weight percent thermoplastic rubber-modified vinyl aromatic polymer composition having a notched Izod impact strength at 23° C. of at least 3.5 ft./lb./in. and a flexural modulus of no more than 325,000 psi comprising: (1) from 60 to 93% by weight of a non-equimolar copolymer of 70 to 98% by weight based on copolymer of a vinyl aromatic monomer, and from 2 to 30% by weight based on copolymer of an unsaturated dicarboxylic acid moiety copolymerizable therewith, and (2) from 7 to 40% by weight of at least two differing rubbery additives which were present during the copolymerization of the monomers of component (1) wherein said rubbery additives comprise from 5 to 20% by weight based on total composition of at least one high conjugated diene-vinyl aromatic copolymer and from 2 to 20% by weight based on total composition of at least one high vinyl aromatic conjugated diene copolymer, with the further limitations that said at least one high conjugated diene-vinyl aromatic copolymer comprises from about 60 to about 98% by weight of the conjugated diene, and that said at least one high vinyl aromatic conjugated diene copolymer is a block copolymer which comprises a greater amount of vinyl aromatic than conjugated diene monomer.
Claim 2
Dependent Claim 283 words
Molding composition consisting of a blend of (a) 70 weight percent to 30 weight percent copolyester consisting of repeating units from terephthalic acid, repeating units from 1,4-cyclohexanedimethanol present in the amount of 25 to 90 mol % and repeating units from a second glycol having 2 to 6 carbon atoms present in the amount of 75 to 10 mol %, wherein the total mol % of glycol is equal to 100 mol %, and (b) 30 weight percent to 70 weight percent thermoplastic rubber-modified vinyl aromatic polymer composition having a notched Izod impact strength at 23° C. of at least 3.5 ft./lb./in. and a flexural modulus of no more than 325,000 psi comprising: (1) from 60 to 93% by weight of a non-equimolar copolymer of 70 to 98% by weight based on copolymer of a vinyl aromatic monomer, and from 2 to 30% by weight based on copolymer of an unsaturated dicarboxylic acid moiety copolymerizable therewith, and (2) from 7 to 40% by weight of at least two differing rubbery additives which were present during the copolymerization of the monomers of component (1) wherein said rubbery additives comprise from 5 to 20% by weight based on total composition of at least one high conjugated diene-vinyl aromatic copolymer and from 2 to 20% by weight based on total composition of at least one high vinyl aromatic conjugated diene copolymer, with the further limitations that said at least one high conjugated diene-vinyl aromatic copolymer comprises from about 60 to about 98% by weight of the conjugated diene, and that said at least one high vinyl aromatic conjugated diene copolymer is a block copolymer which comprises a greater amount of vinyl aromatic than conjugated diene monomer.
Claim 3
Dependent Claim 35 words
Molding composition as defined in claim 1 wherein said blend comprises 40 weight percent to 60 weight percent said copolyester and 60 weight percent to 40 weight percent said thermoplastic rubber-modified vinyl aromatic polymer composition.
Claim 4
Dependent Claim 27 words
Molding composition as defined in claim 1 wherein said blend comprises 50 weight percent said copolyester and 50 weight percent said thermoplastic rubber-modified vinyl aromatic polymer composition.
Claim 5
Dependent Claim 33 words
Molding composition as defined in claim 1 wherein the rubbery additives in said thermoplastic rubber-modified vinyl aromatic polymer composition generally appear as widely dispersed relatively small particles in the matrix of the composition.
Claim 6
Dependent Claim 22 words
Molding composition as defined in claim 1 wherein the aromatic vinyl monomer in said thermoplastic rubber-modified vinyl aromatic polymer composition comprises styrene.
Claim 7
Dependent Claim 26 words
Molding composition as defined in claim 1 wherein the copolymer of unsaturated dicarboxylic acid moiety of said thermoplastic rubber-modified vinyl aromatic polymer composition comprises maleic acid.
Claim 8
Dependent Claim 14 words
Molding composition as defined in claim 1 wherein said second glycol comprises ethylene glycol.
Claim 9
Dependent Claim 14 words
Molding composition as defined in claim 1 wherein said second glycol comprises butylene glycol.
Claim 10
Dependent Claim 18 words
Molding composition as defined in claim 1 wherein said copolyester comprises 15 to 40 mol % ethylene glycol.
Claim 11
Dependent Claim 18 words
Molding composition as defined in claim 2 wherein said copolyester comprises 15 to 40 mol % ethylene glycol.
Claim 12
Dependent Claim 18 words
Molding composition as defined in claim 3 wherein said copolyester comprises 15 to 40 mol % ethylene glycol.
Claim 13
Dependent Claim 18 words
Molding composition as defined in claim 1 wherein said copolyester comprises 15 to 40 mol % butylene glycol.
Claim 14
Dependent Claim 18 words
Molding composition as defined in claim 2 wherein said copolyester comprises 15 to 40 mol % butylene glycol.
Claim 15
Dependent Claim 18 words
Molding composition as defined in claim 3 wherein said copolyester comprises 15 to 40 mol % butylene glycol.

References Cited (Backward Citations)

US4172859A Cited
US4117034A Cited
US4346195A Cited
US4388446A Cited
EP0081015A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-04-14 1989-10-14 1990-04-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-04-14 1993-10-14 1994-04-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-04-14 1997-10-14 1998-04-15 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag