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US4579792A Expired / Lapsed US ⏱️ 0.0 years remaining

Lithium batteries with organic slurry cathodes

Assignee: Polaroid Corp
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Filing: 1984-04-30
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Granted: 1986-04-01
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Expires: 2004-04-30
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Abstract

Abstract Electrical cells and batteries having lithium anodes and cathodes comprising an organic slurry of MnO2 and carbon particles in an organic solvent in contact with a conductive plastic current collector, and a method of making the cathodes comprising the steps of heating MnO2 to remove absorbed and adsorbed water and water of crystallization, cooling the dehydrated MnO2, dispersing the cooled and dehydrated MnO2 in an anhydrous solvent to form a slurry, depositing the slurry in discrete cathode patches on cell component substrates, and sealing the slurry patches into cells having substantially gas impervious cell enveloping boundaries.

Inventors

  • 👤 Alan H. Bruder

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 16:02
CPC Classifications
H; H01; H01M; H01M4/00; H01M4/02; H01M4/06; H01M4/08; H01M6/00; H01M6/14; H01M6/16; H01M6/42; H01M6/46; H01M6/48

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 87 words
A laminar electrical cell, comprising a sheet of conductive plastic, a separator, a cathode consisting essentially of a slurry of dewatered MnO 2 and carbon particles in a solution of a lithium salt in a substantially anhydrous organic solvent between and in contact with said conductive plastic sheet and said separator with said solution permeating said separator, said slurry being free of any binder material, and a thin sheet of lithium in contact with said separator, said separator being interposed between said cathode and said lithium sheet.
Claim 2
Dependent Claim 87 words
A laminar electrical cell, comprising a sheet of conductive plastic, a separator, a cathode consisting essentially of a slurry of dewatered MnO 2 and carbon particles in a solution of a lithium salt in a substantially anhydrous organic solvent between and in contact with said conductive plastic sheet and said separator with said solution permeating said separator, said slurry being free of any binder material, and a thin sheet of lithium in contact with said separator, said separator being interposed between said cathode and said lithium sheet.
Claim 3
Dependent Claim 23 words
The cell of claim 1, in which said salt consists essentially of LiAsF 6 , and in which said solvent comprises propylene carbonate.
Claim 4
Dependent Claim 67 words
A lithium battery, comprising at least one cell including an anode, a cathode, and an electrolyte permeable separator between said anode and said cathode, said cathode consisting essentially of metallic lithium, and said cathode consisting essentially of a slurry of dewatered MnO 2 and carbon particles in a solution of a lithium salt in a substantially anhydrous organic solvent, said slurry being free of any binder material.
Claim 5
Dependent Claim 67 words
A lithium battery, comprising at least one cell including an anode, a cathode, and an electrolyte permeable separator between said anode and said cathode, said cathode consisting essentially of metallic lithium, and said cathode consisting essentially of a slurry of dewatered MnO 2 and carbon particles in a solution of a lithium salt in a substantially anhydrous organic solvent, said slurry being free of any binder material.
Claim 6
Dependent Claim 14 words
The battery of claim 3, in which said lithium salt is LiAsF 6 .
Claim 7
Dependent Claim 13 words
The battery of claim 4, in which said organic solvent comprises propylene carbonate.
Claim 8
Dependent Claim 41 words
The battery of claim 4, in which said organic solvent consists essentially of from 30 to 100 parts by weight of propylene carbonate and from 0 to 70 parts by weight of 1,2 dimethoxyethane, per 100 parts by weight of solvent.
Claim 9
Dependent Claim 121 words
A lithium battery, comprising at least one cell including an anode, a cathode, and an electrolyte permeable separator between said anode and said cathode, said anode consisting essentially of a thin flat sheet of lithium foil in contact with said separator, said cathode consisting essentially of a thin flat deposit of a slurry of dewatered MnO 2 and carbon black in a solution of a salt of lithium in an essentially anhydrous organic solvent, said slurry being free of any binder material, said slurry being in contact with said separator and said solution permeating said separator to establish ionic communication with said anode, and means forming a flexible electrolyte impermeable seal around and enclosing said anode, said cathode and said separator.
Claim 10
Dependent Claim 121 words
A lithium battery, comprising at least one cell including an anode, a cathode, and an electrolyte permeable separator between said anode and said cathode, said anode consisting essentially of a thin flat sheet of lithium foil in contact with said separator, said cathode consisting essentially of a thin flat deposit of a slurry of dewatered MnO 2 and carbon black in a solution of a salt of lithium in an essentially anhydrous organic solvent, said slurry being free of any binder material, said slurry being in contact with said separator and said solution permeating said separator to establish ionic communication with said anode, and means forming a flexible electrolyte impermeable seal around and enclosing said anode, said cathode and said separator.
Claim 11
Dependent Claim 26 words
The battery of claim 7, in which said salt is LiAsF 6 , and in which said solvent consists essentially of propylene carbonate and 1,2 dimethoxyethane.

References Cited (Backward Citations)

US4119770A Cited
US4399202A Cited
US4264689A Cited
US4328288A Cited
US4361633A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-03-31 1989-09-30 1990-04-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-03-31 1993-09-30 1994-04-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-03-31 1997-09-30 1998-04-01 $7700.00 Window Closed / Lapsed

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