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US4575432A Expired / Lapsed US ⏱️ 0.0 years remaining

Conductive thermosetting compositions and process for using same

Assignee: WR Grace and Co Conn
•
Filing: 1984-07-09
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Granted: 1986-03-11
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Expires: 2004-07-09
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Abstract

Abstract This invention is directed to a process and a novel composition for forming a conductive thermoset material which comprises admixing (a) particles of a polymeric material crosslinked to at least its gel point and swellable at its plasticization temperature, (b) at least one liquid reactive plasticizer for (a) (c) optionally and preferably a curing agent for the reactive plasticizer, and (d) heat or electrically conductive particles, and thereafter heating the admixture for a time sufficient to flux and cure same to obtain a conductive thermoset material. The crosslinking of the thermoplastic polymer can optionally be carried out in a solvent for the polymer. Upon heating, above the plasticization temperature, the liquid reactive plasticizer plasticizes the lightly crosslinked polymer particles. This results in the swelling of the polymer particle, forcing the conductive filler to pack tightly and orderly, thereby increasing the conductivity of the plasticized conductive thermoset after curing.

Inventors

  • 👤 Shiow C. Lin
  • 👤 Craig S. Barber

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 14:00
CPC Classifications
H; H01; H01B; H01B1/00; H01B1/20; H01B1/24; H01B1/22

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 82 words
A conductive, thermosettable, reactive plastisol dispersion composition comprising an admixture of (a) particles of a polymeric material crosslinked to at least its gell point and swellable at its plasticization temperature, (b) at least one liquid, reactive plasticizer for (a), and (c) particles of a heat or electrically conductive material, the weight ratio of (a):(b) being 0.0001:99.9999 to 70:30 with (c) being present in an amount in the range 1 to 80% by weight of the total conductive, thermosettable, reactive plastisol dispersion composition.
Claim 2
Dependent Claim 82 words
A conductive, thermosettable, reactive plastisol dispersion composition comprising an admixture of (a) particles of a polymeric material crosslinked to at least its gell point and swellable at its plasticization temperature, (b) at least one liquid, reactive plasticizer for (a), and (c) particles of a heat or electrically conductive material, the weight ratio of (a):(b) being 0.0001:99.9999 to 70:30 with (c) being present in an amount in the range 1 to 80% by weight of the total conductive, thermosettable, reactive plastisol dispersion composition.
Claim 3
Dependent Claim 26 words
The composition of claim 1, containing in addition a thermal curing agent for (b) in an amount ranging from 0.001 to 10% by weight of (b).
Claim 4
Independent Claim 106 words
The method of making a conductive thermoset article comprising the steps of admixing (a) particles of a polymeric material crosslinked to at least its gel point and swellable at its plasticization temperature, (b) a liquid reactive plasticizer for (a), and (c) particles of a heat or electrically conductive material to form a conductive reactive plastisol composition, the weight ratio of (a):(b) being 0.0001:99.9999 to 70:30 with (c) being present in an amount in the range 1 to 80% by weight of the conductive reactive plastisol composition, and, thereafter, heating the composition for a time sufficient to plasticize and cure same to obtain a conductive thermoset article.
Claim 5
Independent Claim 106 words
The method of making a conductive thermoset article comprising the steps of admixing (a) particles of a polymeric material crosslinked to at least its gel point and swellable at its plasticization temperature, (b) a liquid reactive plasticizer for (a), and (c) particles of a heat or electrically conductive material to form a conductive reactive plastisol composition, the weight ratio of (a):(b) being 0.0001:99.9999 to 70:30 with (c) being present in an amount in the range 1 to 80% by weight of the conductive reactive plastisol composition, and, thereafter, heating the composition for a time sufficient to plasticize and cure same to obtain a conductive thermoset article.
Claim 6
Dependent Claim 30 words
The method according to claim 3 wherein the composition contains in addition a thermal curing agent for (b) in an amount ranging from 0.001 to 10% by weight of (b).

References Cited (Backward Citations)

US30274A Cited
US3412043A Cited
US3609104A Cited
US3746662A Cited
US3968056A Cited
USRE30274E Cited
US4410457A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-03-10 1989-09-09 1990-03-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-03-10 1993-09-09 1994-03-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-03-10 1997-09-09 1998-03-11 $7700.00 Window Closed / Lapsed

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