US4571380A
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Spectrally sensitized inner latent image type silver halide photographic emulsions
Assignee: Fujifilm Holdings Corp
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Filing: 1983-10-27
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Granted: 1986-02-18
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Expires: 2003-10-27
Abstract
Abstract An inner latent image type silver halide photographic emulsion which is spectrally sensitized by adding at least one cyanine dye represented by general formula (II) to a direct positive inner latent image type silver halide photographic emulsion and thereafter adding additionally at least one cyanine dye represented by general formula (I) to said emulsion ##STR1## (the symbols are as defined in the appended claims). A remarkable increase of spectral sensitivity, an increase of maximum density and a decrease of minimum density can be obtained by this silver halide photographic emulsion.
Inventors
- 👤 Yasuhiro Noguchi
- 👤 Yuji Mihara
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 15:51
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/06; G03C1/08; G03C1/28; G03C1/29; G03C1/485; Y; Y10; Y10S; Y10S430/00; Y10S430/141
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
237 words
An inner latent image type silver halide photographic emulsion which is spectrally sensitized by adding at least one cyanine sensitizing dye represented by general formula (II) to a direct positive inner latent image type silver halide photographic emulsion and thereafter adding additionally at least one cyanine sensitizing dye represented by general formula (I) to said emulsion: ##STR9## wherein W and Y which may be identical or different from each other each represents an oxygen atom, a selenium atom, a sulfur atom or >N-R 5 , wherein R 5 represents a lower alkyl group which is unsubstituted or substituted with a halogen atom or a lower alkoxyl group or an allyl group, Z, Z 1 , Z 2 and Z 3 each represents an atomic group necessary to form a benzene ring or naphthalene ring, R and R 0 each represents a hydrogen atom, a lower alkyl group, a phenyl group or an aralkyl group, R 1 and R 2 each represents an alkyl group, a haloalkyl group, an alkoxyalkyl group, an aralkyl group, an aryloxyalkyl group or an allyl group, R 3 and R 4 each represents an alkyl group substituted with a carboxyl group or a sulfo group, but at least one of R 3 and R 4 represents an alkyl group substituted with a sulfo group, X 1 represents an anion, X 2 represents an anion or a cation, and n is 0 or 1.
Claim 2
Dependent Claim
237 words
An inner latent image type silver halide photographic emulsion which is spectrally sensitized by adding at least one cyanine sensitizing dye represented by general formula (II) to a direct positive inner latent image type silver halide photographic emulsion and thereafter adding additionally at least one cyanine sensitizing dye represented by general formula (I) to said emulsion: ##STR9## wherein W and Y which may be identical or different from each other each represents an oxygen atom, a selenium atom, a sulfur atom or >N-R 5 , wherein R 5 represents a lower alkyl group which is unsubstituted or substituted with a halogen atom or a lower alkoxyl group or an allyl group, Z, Z 1 , Z 2 and Z 3 each represents an atomic group necessary to form a benzene ring or naphthalene ring, R and R 0 each represents a hydrogen atom, a lower alkyl group, a phenyl group or an aralkyl group, R 1 and R 2 each represents an alkyl group, a haloalkyl group, an alkoxyalkyl group, an aralkyl group, an aryloxyalkyl group or an allyl group, R 3 and R 4 each represents an alkyl group substituted with a carboxyl group or a sulfo group, but at least one of R 3 and R 4 represents an alkyl group substituted with a sulfo group, X 1 represents an anion, X 2 represents an anion or a cation, and n is 0 or 1.
Claim 3
Dependent Claim
55 words
The silver halide photographic emulsion of claim 1, wherein Z, Z 1 , Z 2 and Z 3 in formulae (I) and (II) each forms together with W, Y and the nitrogen atom a benzimidazole nucleus, a benzoxazole nucleus, a benzothiazole nucleus, a benzoselenazole nucleus, a naphthoxazole nucleus, a naphthothiazole nucleus or a naphthoselenazole nucleus.
Claim 4
Dependent Claim
35 words
The silver halide photographic emulsion of claim 1, wherein R 3 and R 4 in formula (II) include an alkyl group connected with a carboxyl group or a sulfo group through another divalent organic group.
Claim 5
Dependent Claim
56 words
The silver halide photographic emulsion of claim 1, wherein the sensitizing dyes represented by general formula (I) are selected from the group consisting of the following formulae (Ia-1), (Ia-2) and (Ia-3): ##STR10## and the sensitizing dyes represented by formula (II) are selected from the group consisting of the following formulae (IIa-1), (IIa-2), (IIa-3) and (IIa-4): ##STR11##
Claim 6
Dependent Claim
56 words
The silver halide photographic emulsion of claim 1, wherein the sensitizing dyes represented by general formula (I) are selected from the group consisting of the following formulae (Ic-6) and (Ic-7): ##STR12## and the sensitizing dyes represented by general formula (II) are selected from the group consisting of the following formulae (IIc-8), (IIc-9), (IIc-10) and (IIc-11): ##STR13##
Claim 7
Dependent Claim
61 words
The silver halide photographic emulsion of claim 1, wherein the sensitizing dyes represented by general formula (I) are selected from the group consisting of the following formula (Id-8), (Id-9), (Id-10), (Id-11) and (Id-12): ##STR14## and the sensitizing dyes represented by general formula (II) are selected from the group consisting of the following formulae (IId-12), (IId-13), (IId-14), (IId-15), (IId-16) and (IId-17): ##STR15##
Claim 8
Dependent Claim
62 words
The silver halide photographic emulsion of claim 1, wherein the sensitizing dyes represented by general formula (I) are selected from the group consisting of the following formulae (Ig-19), (Ig-20), (Ig-21), (Ig-22), (Ig-23) and (Ig-24): ##STR16## and the sensitizing dyes represented by general formula (II) are selected from the group consisting of the following formulae (IIg-27), (IIg-28), (IIg-29), (IIg-30), (IIg-31) and (IIg-32): ##STR17##
Claim 9
Dependent Claim
39 words
The silver halide photographic emulsion of claim 1, wherein the molar ratio of the sensitizing dyes represented by general formula (I) to the sensitizing dyes represented by general formula (II) is selected from a range of 1/20 to 20/1.
Claim 10
Dependent Claim
39 words
The silver halide photographic emulsion of claim 1, wherein the amount of each of the sensitizing dyes represented by general formulae (I) and (II) is from about 1.0×10 -5 to about 1.0×10 -3 mol per mol of silver halide.
Claim 11
Dependent Claim
41 words
The silver halide photographic emulsion of claim 1, wherein the time interval from the addition of the sensitizing dyes represented by general formula (II) to the addition of the sensitizing dyes represented by general formula (I) is at least 1 minute.
Claim 12
Dependent Claim
41 words
The silver halide photographic emulsion of claim 1, wherein the time interval from the addition of the sensitizing dyes represented by general formula (II) to the addition of the sensitizing dyes represented by general formula (I) is at least 5 minutes.
Claim 13
Dependent Claim
44 words
A silver halide photographic material capable of providing direct positive images by surface development in the presence of a nucleus forming agent after imagewise exposure to light which has at least one inner latent image type silver halide emulsion layer according to claim 1.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-02-17 | 1989-08-19 | 1990-02-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-02-17 | 1993-08-19 | 1994-02-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-02-17 | 1997-08-19 | 1998-02-18 | $7700.00 | Window Closed / Lapsed |