US4571330A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Flue gas desulfurization
Assignee: Babcock and Wilcox Co
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Filing: 1983-09-29
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Granted: 1986-02-18
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Expires: 2003-09-29
Abstract
Abstract Systems for desulfurization of a flue gas containing fly ash including formation of a dry powder in a spray dryer absorber resulting from reaction of an alkaline aqueous feed and the flue gas. The dry powder is collected and a specifically selected fraction is recycled to a feed preparation subsystem for inclusion in the aqueous feed. Selective recycle is based on physical or chemical properties and, for example, large diameter and dense particles provide enhanced reagent utilization compared to smaller and less dense particles.
Inventors
- 👤 Henry V. Krigmont
- 👤 Harold H. Haaland
- 👤 Ronald J. Triscori
- 👤 Herbert W. Spencer, III
- 👤 Jay L. Stern
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 12:05
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/48; B01D53/50; B01D53/501
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
144 words
A process for desulfurization of a flue gas containing sulfur oxides, comprising: spraying an aqueous feed comprising a reagent reactive with said sulfur oxides into said flue gas in a spray dryer absorber, thereby simultaneously drying said sprayed feed and reducing the sulfur oxide content of said flue gas, and forming a dry powder; conducting said dry powder and said gas reduced in sulfur oxide content to a gas-particulate separator; collecting said powder from said separator in a plurality of chambers; determining, in each of said chambers, the value of at least one of a physical and a chemical parameter of said powder indicative of reactivity with sulfur oxides; selecting, based on said determined values, those chambers containing powder having a greater indication of reactivity with sulfur oxides; and preparing said aqueous feed from an aqueous medium and dry powder from said selected chambers.
Claim 2
Dependent Claim
144 words
A process for desulfurization of a flue gas containing sulfur oxides, comprising: spraying an aqueous feed comprising a reagent reactive with said sulfur oxides into said flue gas in a spray dryer absorber, thereby simultaneously drying said sprayed feed and reducing the sulfur oxide content of said flue gas, and forming a dry powder; conducting said dry powder and said gas reduced in sulfur oxide content to a gas-particulate separator; collecting said powder from said separator in a plurality of chambers; determining, in each of said chambers, the value of at least one of a physical and a chemical parameter of said powder indicative of reactivity with sulfur oxides; selecting, based on said determined values, those chambers containing powder having a greater indication of reactivity with sulfur oxides; and preparing said aqueous feed from an aqueous medium and dry powder from said selected chambers.
Claim 3
Dependent Claim
12 words
The process of claim 1 wherein said reagent comprises Ca(OH) 2 .
Claim 4
Dependent Claim
12 words
The process of claim 1 wherein said parameter is mass mean diameter.
Claim 5
Dependent Claim
10 words
The process of claim 1 wherein said parameter is alkalinity.
Claim 6
Dependent Claim
11 words
The process of claim 1 wherein said parameter is reactive alkalinity.
Claim 7
Dependent Claim
15 words
The process of claim 1 wherein said parameter is one of mean density and density.
Claim 8
Dependent Claim
17 words
The process of claim 1 wherein said parameter is one of mean aerodynamic diameter and aerodynamic diameter.
Claim 9
Dependent Claim
26 words
The process of claim 1 wherein said parameter is a physical property of said powder selected from the group including fluidity, specific gravity and particle size.
Claim 10
Dependent Claim
141 words
A process for desulfurization of a flue gas containing fly ash and sulfur oxides, comprising: spraying an aqueous feed comprising at least a portion of said fly ash and a reagent reactive with said sulfur oxides into said flue gas in a spray dryer absorber, thereby simultaneously drying said sprayed feed and reducing the sulfur oxide content of said flue gas, and forming a dry powder comprising conglomerates of fly ash and materials formed by said drying and sulfur oxide absorption; conducting said dry powder and said gas reduced in sulfur oxide content to an electrostatic precipitator having a plurality of serially arranged fields and corresponding serially arranged hoppers; collecting said dry powder in said hoppers; and preparing said feed from an aqueous medium and said dry powder from less than all and including the former of said serially arranged hoppers.
Claim 11
Dependent Claim
141 words
A process for desulfurization of a flue gas containing fly ash and sulfur oxides, comprising: spraying an aqueous feed comprising at least a portion of said fly ash and a reagent reactive with said sulfur oxides into said flue gas in a spray dryer absorber, thereby simultaneously drying said sprayed feed and reducing the sulfur oxide content of said flue gas, and forming a dry powder comprising conglomerates of fly ash and materials formed by said drying and sulfur oxide absorption; conducting said dry powder and said gas reduced in sulfur oxide content to an electrostatic precipitator having a plurality of serially arranged fields and corresponding serially arranged hoppers; collecting said dry powder in said hoppers; and preparing said feed from an aqueous medium and said dry powder from less than all and including the former of said serially arranged hoppers.
Claim 12
Dependent Claim
43 words
The process of claim 9 further comprising continuing of said spraying, conducting, collecting and preparing steps until such point as the mass mean diameter of said powder collected in said former hoppers is larger than the mass mean diameter of said fly ash.
Claim 13
Dependent Claim
39 words
The process of claim 10 further comprising continuing said spraying, conducting, collecting and preparing steps such that the mean diameter of said powder collected in said former hoppers is larger than the mass mean diameter of said fly ash.
Claim 14
Dependent Claim
149 words
A process for desulfurization of a flue gas containing sulfur dioxide, comprising: spraying an aqueous feed comprising a reagent reactive with said sulfur dioxide into said flue gas in a spray dryer absorber, thereby simultaneously drying said sprayed feed and reducing the sulfur dioxide content of said flue gas; collecting in a plurality of chambers a dry powder comprising materials formed by the drying and sulfur dioxide absorption step; determining the relative value of at least one of a physical and a chemical parameter of said dry powder indicative of reactivity with sulfur oxides in each of said chambers relative to the value of said powder parameter in each of the other of said chambers; selecting, based on said determination, those chambers containing powder having a greater indication of reactivity with sulfur oxides; and preparing said aqueous feed from an aqueous medium and dry powder from said selected chambers.
Claim 15
Dependent Claim
149 words
A process for desulfurization of a flue gas containing sulfur dioxide, comprising: spraying an aqueous feed comprising a reagent reactive with said sulfur dioxide into said flue gas in a spray dryer absorber, thereby simultaneously drying said sprayed feed and reducing the sulfur dioxide content of said flue gas; collecting in a plurality of chambers a dry powder comprising materials formed by the drying and sulfur dioxide absorption step; determining the relative value of at least one of a physical and a chemical parameter of said dry powder indicative of reactivity with sulfur oxides in each of said chambers relative to the value of said powder parameter in each of the other of said chambers; selecting, based on said determination, those chambers containing powder having a greater indication of reactivity with sulfur oxides; and preparing said aqueous feed from an aqueous medium and dry powder from said selected chambers.
Claim 16
Dependent Claim
23 words
The process of claim 12 wherein said collecting step comprises flowing said dry powder through an electrostatic precipitator having a plurality of hoppers.
Claim 17
Dependent Claim
36 words
The process of claim 12 wherein said collecting step comprises flowing said dry powder serially through a baghouse and then through a mechanical separator having at least two outlets discharging said dry powder to two containers.
Claim 18
Dependent Claim
153 words
In a process for desulfurization of a flue gas containing sulfur oxides of the type including (a) spraying an aqueous feed comprising a reagent reactive with said sulfur oxides into said flue gas in a spray dryer absorber, thereby simultaneously drying said sprayed feed and reducing the sulfur oxide content of said flue gas and forming a dry powder, (b) conducting said dry powder and said gas reduced in sulfur oxide content to a gas-particulate separator, and (c) collecting said powder from said separator in a plurality of chambers, the improvement comprising: determining, in each of said chambers, the value of a parameter of said powder selected from the group consisting of alkalinity, reactive alkalinity, density, mean density, aerodynamic diameter, mean aerodynamic diameter and chemical composition; selecting certain of said chambers based on said determined values; and preparing said aqueous feed from an aqueous medium and dry powder from said selected certain chambers.
Claim 19
Dependent Claim
153 words
In a process for desulfurization of a flue gas containing sulfur oxides of the type including (a) spraying an aqueous feed comprising a reagent reactive with said sulfur oxides into said flue gas in a spray dryer absorber, thereby simultaneously drying said sprayed feed and reducing the sulfur oxide content of said flue gas and forming a dry powder, (b) conducting said dry powder and said gas reduced in sulfur oxide content to a gas-particulate separator, and (c) collecting said powder from said separator in a plurality of chambers, the improvement comprising: determining, in each of said chambers, the value of a parameter of said powder selected from the group consisting of alkalinity, reactive alkalinity, density, mean density, aerodynamic diameter, mean aerodynamic diameter and chemical composition; selecting certain of said chambers based on said determined values; and preparing said aqueous feed from an aqueous medium and dry powder from said selected certain chambers.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-02-17 | 1989-08-19 | 1990-02-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-02-17 | 1993-08-19 | 1994-02-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-02-17 | 1997-08-19 | 1998-02-18 | $7700.00 | Window Closed / Lapsed |