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US4569857A Expired / Lapsed US ⏱️ 0.0 years remaining

Retroreflective sheeting

Assignee: 3M Co
•
Filing: 1984-11-16
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Granted: 1986-02-11
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Expires: 2004-11-16
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Abstract

Abstract New methods for making "embedded-lens" retroreflective sheeting, and new forms of such sheeting, are provided. The new methods involve embedding microspheres into a web by continuously presenting a mass of the microspheres against the moving web and heating the web so as to soften at least an exterior stratum of the web, and adding a spacing layer to the microsphere-covered surface of the web. The microspheres are embedded on the average to less than 50 percent of their diameter, which has been found to cause the spacing layer to conform around a greater proportion of the back surface of individual microspheres and thereby position a greater portion of the specularly reflective layer carried on the spacing layer at the approximate focal point for light passed through the microspheres. Use of a preformed spacing layer also contributes to maintaining the spacing layer at a constant thickness around the back surface of the microspheres.

Inventors

  • 👤 Chi F. Tung
  • 👤 James C. Coderre

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 06:41
CPC Classifications
G; G02; G02B; G02B5/00; G02B5/12; G02B5/126; G02B5/128

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 132 words
A method for preparing retroreflective sheeting comprising (1) continuously presenting a mass of transparent microspheres against a moving carrier web and heating the web so as to soften at least an exterior stratum of the web and partially embed a dense monolayer of microspheres in the web; (2) covering the monolayer of microspheres with a layer of transparent binder material having an exterior surface cupped around the microspheres; (3) applying a specularly reflective layer to the cupped surface of the layer of transparent binder material; (4) removing the carrier web from the assembly formed by the layer of transparent binder material and microspheres; and (5) applying transparent polymer-based material over the microsphere-covered surface left upon removal of the carrier web to form a transparent top layer in which the microspheres are embedded.
Claim 2
Independent Claim 132 words
A method for preparing retroreflective sheeting comprising (1) continuously presenting a mass of transparent microspheres against a moving carrier web and heating the web so as to soften at least an exterior stratum of the web and partially embed a dense monolayer of microspheres in the web; (2) covering the monolayer of microspheres with a layer of transparent binder material having an exterior surface cupped around the microspheres; (3) applying a specularly reflective layer to the cupped surface of the layer of transparent binder material; (4) removing the carrier web from the assembly formed by the layer of transparent binder material and microspheres; and (5) applying transparent polymer-based material over the microsphere-covered surface left upon removal of the carrier web to form a transparent top layer in which the microspheres are embedded.
Claim 3
Dependent Claim 16 words
A method of claim 1 in which the exterior stratum of the carrier web comprises polyethylene.
Claim 4
Independent Claim 144 words
A method for preparing retroreflective sheeting comprising (1) continuously presenting a mass of transparent microspheres against a moving web and heating the web so as to soften at least an exterior stratum of the web and partially embed a dense monolayer of microspheres in the web; said carrier web comprising a polymeric material against which the mass of transparent microspheres is disposed and which upon heating softens to a slippery condition such that microspheres are embedded in an amount covering at least 75 percent of the area of the surface of the web; (2) covering the monolayer of microspheres with a layer of transparent binder material having an exterior surface that is cupped around the microspheres and disposed at the approximate focal point for the microspheres; and (3) applying a specularly reflective layer to the cupped surface of the layer of transparent binder material.
Claim 5
Independent Claim 144 words
A method for preparing retroreflective sheeting comprising (1) continuously presenting a mass of transparent microspheres against a moving web and heating the web so as to soften at least an exterior stratum of the web and partially embed a dense monolayer of microspheres in the web; said carrier web comprising a polymeric material against which the mass of transparent microspheres is disposed and which upon heating softens to a slippery condition such that microspheres are embedded in an amount covering at least 75 percent of the area of the surface of the web; (2) covering the monolayer of microspheres with a layer of transparent binder material having an exterior surface that is cupped around the microspheres and disposed at the approximate focal point for the microspheres; and (3) applying a specularly reflective layer to the cupped surface of the layer of transparent binder material.
Claim 6
Dependent Claim 15 words
A method of claim 3 in which the exterior stratum of the web comprises polyethylene.
Claim 7
Dependent Claim 24 words
A method of claim 3 in which the layer of transparent binder material is preformed and laminated to the microsphere-covered surface of the web.
Claim 8
Dependent Claim 56 words
A method of claim 1 including the further steps of (1) removing the web from the assembly formed by the layer of transparent binder material and microspheres; and (2) applying transparent polymer-based material over the microsphere-covered surface left upon removal of the carrier web to form a transparent top layer in which the microspheres are embedded.
Claim 9
Dependent Claim 28 words
A method of claim 1 in which the microspheres are embedded in the web to a depth on the average of less than 50 percent of their diameter.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-02-10 1989-08-12 1990-02-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-02-10 1993-08-12 1994-02-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-02-10 1997-08-12 1998-02-11 $7700.00 Window Closed / Lapsed

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